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Full-Text Articles in Education
Potential Driven Polyelectrolyte Adsorption Onto Monolayer Modified Electrodes, Mark Anderson, Weslie Sanders
Potential Driven Polyelectrolyte Adsorption Onto Monolayer Modified Electrodes, Mark Anderson, Weslie Sanders
Mark R. Anderson
Preparation of interfacial structures by molecular self-assembly has been actively studied for many years. Well-defined modified interfaces can be used to study fundamental interfacial properties, or they can be used in different practical applications. To broaden the utility of interfaces prepared by molecular self-assembly, monolayers containing terminal functionality are frequently used. These interfaces have structural and physical properties that can be controlled by both the identity of the functionalization as well as the ensemble structure of the modified interface. This suggests that the chemical and physical properties of an interface can be designed and/or controlled to some extent by altering …
Selective Formation Of A Symmetric Sc3n@C78 Bisadduct: Adduct Docking Controlled By An Internal Trimetallic Nitride Cluster, Ting Cai, Liaosa Xu, Chunying Shu, Hunter Champion, Jonathan Reid, Clemins Anklin, Mark Anderson, Harry Gibson, Harry Dorn
Selective Formation Of A Symmetric Sc3n@C78 Bisadduct: Adduct Docking Controlled By An Internal Trimetallic Nitride Cluster, Ting Cai, Liaosa Xu, Chunying Shu, Hunter Champion, Jonathan Reid, Clemins Anklin, Mark Anderson, Harry Gibson, Harry Dorn
Mark R. Anderson
In this paper we report a regioselective Bingel−Hirsch reaction of Sc3N@C78 yielding a single mono- and a dominate bis-ethyl malonate derivative for the first time. The Cs-symmetric monoadduct 1 and C2v-symmetric bisadduct 2 were isolated by HPLC and characterized by MS, UV−vis, and NMR spectroscopy. The symmetric bisadduct 2 clearly demonstrate the remarkable regioselectivity control exerted by the encapsulated Sc3N cluster. We have employed a LUMO electron density surface computational approach to predict multiadduct docking sites on the ellipsoidal fullerene cage surface.
Rust, Glue, And Molecules -- Understanding The Role Of Molecular Structure On Macroscopic Interfacial Properties, Mark Anderson
Rust, Glue, And Molecules -- Understanding The Role Of Molecular Structure On Macroscopic Interfacial Properties, Mark Anderson
Mark R. Anderson
No abstract is available at this time.
Application Of Steaming Video And Flash Animation For Teaching Analytical Chemistry, Mark Anderson
Application Of Steaming Video And Flash Animation For Teaching Analytical Chemistry, Mark Anderson
Mark R. Anderson
No abstract is currently available.
Teaching Analytical Chemistry To The Masses: How We Went From 2 Courses To 7 Courses In 10 Years, Gary Long, Mark Anderson, Brian Tissue, John Morris
Teaching Analytical Chemistry To The Masses: How We Went From 2 Courses To 7 Courses In 10 Years, Gary Long, Mark Anderson, Brian Tissue, John Morris
Mark R. Anderson
No abstract is currently available.
Interactive Multimedia Over The Internet For Teaching Analytical Chemistry, Mark Anderson
Interactive Multimedia Over The Internet For Teaching Analytical Chemistry, Mark Anderson
Mark R. Anderson
No abstract is currently available.
Using Flash Animation And Streaming Video For Laboratory/Lecture Demonstrations In Large Enrollment Courses, Mark Anderson
Using Flash Animation And Streaming Video For Laboratory/Lecture Demonstrations In Large Enrollment Courses, Mark Anderson
Mark R. Anderson
No abstract is currently available.
Development And Student Use Of Web-Based Prelabs In Analytical Chemistry Courses, Mark Anderson, Brian Tissue
Development And Student Use Of Web-Based Prelabs In Analytical Chemistry Courses, Mark Anderson, Brian Tissue
Mark R. Anderson
No abstract is currently available.
The Voltammetry Of C84 Isomers, Mark Anderson, Harry Dorn, Steven Stevenson, Susanne Dana
The Voltammetry Of C84 Isomers, Mark Anderson, Harry Dorn, Steven Stevenson, Susanne Dana
Mark R. Anderson
The square-wave voltammetry of isolated isomers of C84 is reported. Based on their relative abundance, the isomers are assumed to have D2 and D2d symmetry. The D2 isomer has four reversible reductions at −0.65, −0.98, −1.34, and −1.75 V versus Fc/Fc+ prior to electrolyte decomposition. This behavior is consistent with previous reports, and is similar to the voltammetry of C60 and C70 (e.g. sequential reductions spaced at slightly increasing intervals). The D2d isomer has five reversible reductions at −0.46, −0.77, −1.58, −1.98, and −2.27 V versus Fc/Fc+ prior to the onset of electrolyte decomposition. The large potential difference separating the …
The Voltammetry Of Sc3@C82, Mark Anderson, Harry Dorn, Paul Burbank, Steven Stevenson, James Gibson
The Voltammetry Of Sc3@C82, Mark Anderson, Harry Dorn, Paul Burbank, Steven Stevenson, James Gibson
Mark R. Anderson
Many endohedral metallofullerenes have a C82 cage surrounding the metals, even though the normal arc-vaporization method of fullerene preparation does not generate C82 in significant abundance.1-10Manolopous et al.11-13attribute the low abundance of empty-cage C82 to the unfavorable electron configuration of this species. Consequently, the prevalence of C82 in metallofullerenes may be the result of an electron transfer from the encapsulated metal atoms to the fullerene cage.10-13 The extent of this charge transfer also contributes to the properties (e.g. catalytic, superconductive, nonlinear optical, and ferromagnetic) that are attributed to the endohedral metallofullerenes.14,15Because of the importance of the charge transfer reaction, characterization …
Voltammetric Studies Of Mn@C82, Mark Anderson, Harry Dorn, Paul Burbank, James Gibson
Voltammetric Studies Of Mn@C82, Mark Anderson, Harry Dorn, Paul Burbank, James Gibson
Mark R. Anderson
The voltammetry for a series of related endohedral metallofullerenes is reported. It is found that as additional metal atoms are inserted into the fullerene cage, the first reduction of the metallofullerenes shifts to more negative potentials. This is consistent with more charge being transferred to the fullerene cage from the additional metal atom; however, the magnitude of the shift is much smaller than expected.
Development And Evaluation Of Internet-Based Hypermedia Chemistry Tutorials, Brian Tissue, Ronald Earp, Ching-Wan Yip, Mark Anderson
Development And Evaluation Of Internet-Based Hypermedia Chemistry Tutorials, Brian Tissue, Ronald Earp, Ching-Wan Yip, Mark Anderson
Mark R. Anderson
This progress report describes the development and student use of World-Wide-Web-based prelaboratory exercises in senior-level Instrumental Analysis during the 1995 Fall semester. The laboratory preparation exercises contained hypermedia tutorials and multiple-choice questions that were intended to familiarize the students with the experiments and instrumentation before their laboratory session. The overall goal of our work is to explore ways in which computer and network technology can be applied in education to improve the cost-effectiveness and efficacy of teaching. The course material can be accessed at http://www.chem.vt.edu/chem-ed/4114/Fall1995.html.
Designing Chemical Education Hypermedia For The World-Wide Web, Brian Tissue, Ching-Wan Yip, Yue-Ling Wong, Mark Anderson
Designing Chemical Education Hypermedia For The World-Wide Web, Brian Tissue, Ching-Wan Yip, Yue-Ling Wong, Mark Anderson
Mark R. Anderson
No abstract is currently available.
Characterization Of Surface Structure And Interactions By Polarization Modulation Fitr And The Quartz Crystal Microbalance, Mark Anderson, Minhui Zhang
Characterization Of Surface Structure And Interactions By Polarization Modulation Fitr And The Quartz Crystal Microbalance, Mark Anderson, Minhui Zhang
Mark R. Anderson
No abstract is currently available.
Effect Of Applied Potential Upon The In Situ Structure Of Self-Assembled Monolayers On Gold Electrodes, Mark Anderson, Marilyn Gatin
Effect Of Applied Potential Upon The In Situ Structure Of Self-Assembled Monolayers On Gold Electrodes, Mark Anderson, Marilyn Gatin
Mark R. Anderson
Polarization modulation Fourier transform infrared reflection absorption spectroscopy (PM-FTIRRAS) has been utilized to study the in situ structure of octadecanethiol when adsorbed to gold electrode surfaces and with the application of potential to the substrate. It is found that applied potential has little effect upon the spectrum of the monolayer in the presence of D2O solutions containing 0.10 M NaClO4. The presence of an acetonitrile solution contacting the monolayer leads to small changes in the infrared spectrum relative to that seen in D2O solutions, suggestive of some small disordering of the monolayer caused by the presence of the acetonitrile. With …
Application Of Polarization Modulation Infrared Relection Absorption Spectroscopy To Study The In Situ Structure Of Monolayers Prepared By Spontaneous Adsorption, Mark Anderson, Mark Evaniak, Minhui Zhang
Application Of Polarization Modulation Infrared Relection Absorption Spectroscopy To Study The In Situ Structure Of Monolayers Prepared By Spontaneous Adsorption, Mark Anderson, Mark Evaniak, Minhui Zhang
Mark R. Anderson
No abstract is currently available.
Charge Transport Properties Of Electrodes Modified By The Spontaneous Adsorption Of Asymmetric Dialkysulfides, Mark Anderson, Minhui Zhang
Charge Transport Properties Of Electrodes Modified By The Spontaneous Adsorption Of Asymmetric Dialkysulfides, Mark Anderson, Minhui Zhang
Mark R. Anderson
No abstract is currently available.
Application Of Potential And Polarization Modulation Infrared Reflection Absorption Spectroscopy To Study The Physical And Structural Properties Of The Electrochemical Interface, Mark Anderson, Susanne Feltovich, Minhui Zhang, Mark Evaniak
Application Of Potential And Polarization Modulation Infrared Reflection Absorption Spectroscopy To Study The Physical And Structural Properties Of The Electrochemical Interface, Mark Anderson, Susanne Feltovich, Minhui Zhang, Mark Evaniak
Mark R. Anderson
No abstract is currently available.
Selectivity In Detection Of Analytes In Flowing Streams Using Piezoelectric Quartz, Mark Anderson, John Roush, David Thacker
Selectivity In Detection Of Analytes In Flowing Streams Using Piezoelectric Quartz, Mark Anderson, John Roush, David Thacker
Mark R. Anderson
No abstract is currently available.
Characterization Of Electrochemical Double Layer From The Infrared Spectroscopic Behavior Of Adsorbed Carbon Monoxide, Mark Anderson
Characterization Of Electrochemical Double Layer From The Infrared Spectroscopic Behavior Of Adsorbed Carbon Monoxide, Mark Anderson
Mark R. Anderson
No abstract is currently available.
Spectroelectrochemical Analysis Of Spontaneously Adsorbed Monolayers, Marilyn O'Grady, Mark Anderson
Spectroelectrochemical Analysis Of Spontaneously Adsorbed Monolayers, Marilyn O'Grady, Mark Anderson
Mark R. Anderson
No abstract is currently available.
Spectroelectrochemical Analysis Of Metal Surfaces Modified With Thin Organic Films, Marilyn O'Grady, Mark Anderson
Spectroelectrochemical Analysis Of Metal Surfaces Modified With Thin Organic Films, Marilyn O'Grady, Mark Anderson
Mark R. Anderson
No abstract is currently available.
The Influence Of Cation Size Upon The Infrared Spectrum Of Carbon Monoxide Adsorbed On Platinum Electrodes, Mark Anderson, Jimin Huang
The Influence Of Cation Size Upon The Infrared Spectrum Of Carbon Monoxide Adsorbed On Platinum Electrodes, Mark Anderson, Jimin Huang
Mark R. Anderson
No abstract is currently available.
The Influence Of Cation Size Upon The Infrared Spectrum Of Carbon Monoxide Adsorbed On Platinum Electrodes, Mark Anderson, Jimin Huang
The Influence Of Cation Size Upon The Infrared Spectrum Of Carbon Monoxide Adsorbed On Platinum Electrodes, Mark Anderson, Jimin Huang
Mark R. Anderson
No abstract is currently available.
Spectroelectrochemical Investigation Of The Double Layer Structure And Properties, Mark Anderson
Spectroelectrochemical Investigation Of The Double Layer Structure And Properties, Mark Anderson
Mark R. Anderson
No abtract is currently available.
Quantitative Determination Of Adsorption Using A Semi-Integral Method, Mark Anderson
Quantitative Determination Of Adsorption Using A Semi-Integral Method, Mark Anderson
Mark R. Anderson
No abstract is currently available.
The Electrochemical And Sniftirs Behavior Of Copper(I)Tetrakisbenzonitrile, Mark Anderson, Daniel Blackwood, Thomas Richmond, Stanley Pons
The Electrochemical And Sniftirs Behavior Of Copper(I)Tetrakisbenzonitrile, Mark Anderson, Daniel Blackwood, Thomas Richmond, Stanley Pons
Mark R. Anderson
No abstract is currently available.
The Effect Of Solvent Type On The Infrared Spectrum Of Carbon Monoxide Adsorbed On A Platinum Electrode, Stanley Pons, Mark Anderson, Daniel Blackwood
The Effect Of Solvent Type On The Infrared Spectrum Of Carbon Monoxide Adsorbed On A Platinum Electrode, Stanley Pons, Mark Anderson, Daniel Blackwood
Mark R. Anderson
No abstract is currently available.
Surface-Enhanced Raman Study Of The Effect Of Ph And Electrode Potential On The Surface Concentrations Of The Electroactive Forms Of Pyridinecarboxaldehydes, Dennis Evans, Mark Anderson
Surface-Enhanced Raman Study Of The Effect Of Ph And Electrode Potential On The Surface Concentrations Of The Electroactive Forms Of Pyridinecarboxaldehydes, Dennis Evans, Mark Anderson
Mark R. Anderson
No abstract is currently available.
Evaluation Of Electrochemical Kinetic Parameters Using The Bond-Henderson-Oldham Global Analysis, Dennis Evans, Mark Anderson
Evaluation Of Electrochemical Kinetic Parameters Using The Bond-Henderson-Oldham Global Analysis, Dennis Evans, Mark Anderson
Mark R. Anderson
No abstract is currently available.