Arts and Humanities Commons^™

Development Of Surface Acoustic Wave Sensors Using Nanostructured Palladium For Hydrogen Detection, Amol V. Chaudhari

USF Tampa Graduate Theses and Dissertations

This thesis addresses the development of new gas sensor using surface acoustic wave (SAW) technology. SAW sensors detect the change in mass, modulus, and conductivity of a sensing layer material via absorption or adsorption of an analyte. The advantage of SAW sensor includes low cost, small size, high sensitivity.

We investigated the use of nano-crystalline palladium film for sensing hydrogen gas. We also investigated SAW fabrication for radio frequency (RF) range operation where high signal-to-noise ratios can be achieved. A test-bed consisting of a gas dilution system, a temperature-controlled test cell, a network analyzer, and computer-based measurement system was used …

The Utilization Of Enzymes In The Synthesis And Modification Of Natural And Nonnatural Compounds: A Chemo-Enzymatic Approach To Enantiomerically Pure Compounds, Jason A. Carr

USF Tampa Graduate Theses and Dissertations

The employment of enzymes and whole cells has been important in many industries for centuries. However, it is only in the last 30 years that the use of enzymes for the synthesis of high-value fine chemicals has enjoyed increasing popularity. In fact, esterases and lipases are used almost routinely these days to provide optically active building blocks for the construction of imaginative new routes to chiral target molecules. The major topic of this work describes the utilization of enzymes (namely lipases) in the synthesis and modification of natural and non-natural compounds.

Chapter 1 outlines the strengths and weaknesses of the …

Performance Analysis Of Tcp/Ip Over High Bandwidth Delay Product Networks, Subodh Kerkar

USF Tampa Graduate Theses and Dissertations

In today's Internet scenario, the current TCP has performed reasonably well. As the Internet has scaled up in load, speed, size and connectivity by the order of six over the past fifteen years, the TCP has consistently avoided severe congestion throughout this same period. Applications involving high performance computings such as bulk-data transfer, multimedia Web streaming, and computational grids demand high bandwidth. These applications usually operate over wide-area networks and, hence, performance over wide-area networks has become a critical issue. Future applications will need steady transfer rates in the order of gigabits per second to support collaborative work. TCP, which …

Characterization Of P-Type Zinc Oxide Films, Madhavi Oleti Kalki Rajan

USF Tampa Graduate Theses and Dissertations

Zinc Oxide falls under the classification of transparent conductive oxides. They typical optical transmittance of Zinc Oxide is 90% in the visible wavelength region. Though stoichiometric ZnO is an insulator, due to the presence of internal defects such as Zn interstitials and Oxygen vacancies, it exists as a n-type conductor.

The other important property of ZnO which could be used by the optical field is its widebandgap. ZnO has a wide bandgap of 3.2eV -3.3eV. The additional advantage of being a direct bandgap semiconductor has increased the probability of using ZnO for short wavelength applications. These practical applications are directly …

Characterization Of Preliminary Breast Tomosynthesis Data: Noise And Power Spectra Analysis, Madhusmita Behera

USF Tampa Graduate Theses and Dissertations

Early detection, diagnosis, and suitable treatment are known to significantly improve the chance of survival for breast cancer (BC) patients. To date, the most cost effective method for screening and early detection is screen-film mammography, which is also the only tool that has demonstrated its ability to reduce BC mortality. Full-field digital mammography (FFDM) is an extension of screen-film mammography that eliminates the need for film-processing because the images are detected electronically from their inception. Tomosynthesis is an emerging technology in digital mammography built on the FFDM framework, which offers an alternative to conventional two-dimensional mammography. Tomosynthesis produces three-dimensional (volumetric) …

On Effective And Efficient Experimental Designs For Neurobehavioral Screening Tests: The Choice Of A Testing Time For Estimating The Time Of Peak Effects, Peter A. Toyinbo

USF Tampa Graduate Theses and Dissertations

In its latest neurotoxicity guidelines released by the US EPA Office of Prevention, Pesticides and Toxic Substances (OPPTS) in 1998, it is recommended that in a neurobehavioral testing, at a minimum, for acute studies, observations and activity testing should be made before the initiation of exposure, at the estimated TOPE (time of peak effects) within 8 hrs of dosing, and at 7 and 14 days after dosing. It is recommended that estimation of TOPE be made by dosing pairs of rats across a range of doses and making regular observations of gait and arousal. However it is well known that …

The Impact Of A Goal Setting Procedure On The Work Performance Of Young Adults With Behavioral/Emotional/Learning Challenges, Robin Wagner Hogsholm

USF Tampa Graduate Theses and Dissertations

The population consisting of young people with Behavioral/Emotional/Learning challenges typically experiences poorer outcomes related to employment, in part due to lower performance levels. Effective strategies, which have a positive impact on work performance for this population, are needed. Goal setting has been used to bring about behavior change, or increase 'motivation', in many fields of study. Goal setting can be conceptualized as an establishing operation (EO), which increases the reinforcing value of goal achievement, and thereby increases the probability of the occurrence of behaviors related to reaching the goal, i.e., task completion. This study empirically examined the impact of a …

Anatomy And Function Of The Nucleus Accumbens In The Pigeon (Columba Livia), Scott Alan Husband

USF Tampa Graduate Theses and Dissertations

Relatively little is known about the existence and traits of a possible nucleus accumbens (Acc) region in non-mammals. The current project investigated a likely candidate for such a structure in pigeons, the medioventral (mvMSt) and mediodorsal (mdMSt) parts of avian medial striatum (MSt). The methods employed were threefold: 1) tract-tracing to determine anatomical connections of the MSt; 2) lesion studies to assess MSt's role in a cognitive task (reversal learning); and 3) measuring an immediate-early gene induced protein, ZENK, in striatal regions during courtship behavior in male pigeons.

The MSt was found to have many forebrain (amygdala, hippocampus, dorsal thalamus) …

Modeling Demand Uncertainty And Processing Time Variability For Multi-Product Chemical Batch Process, Rishi Darira

USF Tampa Graduate Theses and Dissertations

Most of the literature on scheduling of multi-product batch process does not consider the uncertainties in demand and variability in processing times. We develop a simulation based variable production schedule model for a multi-product batch facility assuming zero wait transfer policy and single product campaign. The model incorporates the demand uncertainties and processing time variability. The impact of demand uncertainties is evaluated in terms of total annual cost, which comprises of the backorder and inventory costs per year. The effect of variability in processing time is measured by the annual production time. We also develop a constant production schedule model …

Hydraulic Performance Of Polymer Modified Bentonite, Jessica A. Schenning

USF Tampa Graduate Theses and Dissertations

Bentonite clay is widely used in barrier systems due to its low hydraulic conductivity and it high swell capacity. Exposure to inorganic solutions can cause significant increases in hydraulic conductivity, due to changes in the surface chemistry and fabric. This phenomenon can be attributed to a reduction in the thickness of the double layer, due to the cation exchange capacity of the clay. The clay can be modified with polymers to render it less susceptible to chemical attack. The treatment process allows the clay to be engineered to enhance specific properties, such as permeability and sorption. In the present study, …

An Analysis Of Travel Trends Of The Elderly And Zero-Vehicle Households In The United States, Ravi Kiran Gorti

USF Tampa Graduate Theses and Dissertations

The elderly and persons residing in zero vehicle households require better transportation services by virtue of their need for special care and lack of mobility, respectively. An analysis of the travel trends of these population cohorts is essential to determine the best ways to improve transportation facilities to better serve them. Information about location of residence, life-cycle, differences by gender, employment status, driver status, highest level of education coupled with trip information like trip rate, travel times and distances trip purpose, modal split and percent of people immobile will facilitate understanding the factors that influence trip making among these people …

A Comparative Analysis Of Travel Time Expenditures In The United States, Lavenia Anne Toole-Holt

USF Tampa Graduate Theses and Dissertations

Literature on transportation planning and modeling is replete with the concept of a travel time budget. According to this concept, average daily travel times tend to be relatively constant. However, evidence from the 1983 Nationwide Personal Transportation Survey and the 2001 National Household Travel Survey suggest that the average daily travel time has increased by 1.9 minutes per year.

Understanding travel time expenditures is important for forecasting travel demand, especially future vehicle miles of travel. Historically, travel demand models considered vehicle availability and income as limiting factors for travel, but going forward time may be the constraint. As individuals spend …

Detection, Cloning, And Analysis Of A U32 Collagenase In Streptococcus Mutans Gs-5, Marios Ioannides

USF Tampa Graduate Theses and Dissertations

Streptococcus mutans is a recognized principal etiologic agent in coronal caries. Although S. mutans has the ability to bind collagen and degrade FALGPA, a synthetic peptide mimicking collagen substrate, its role in dental root caries has not yet been fully elucidated. Degradation of collagen fibrils in dentin was attributed to S. mutans, but a collagenase enzyme has not yet been isolated from this organism. Considering the increased incidence of dental root decay among the elderly, an understanding of the role of the pathogenic factors is necessary to the development of preventive measures. The present study has focused on the …

Analysis Of Glass Mold To Enhance Rate Of Heat Transfer, Anand Warude

USF Tampa Graduate Theses and Dissertations

Narrow Neck Press and Blow (NNPB) process is used to produce light weight bottles. The gob of molten glass is delivered to the blank mold and a specially designed narrow diameter plunger is used to form the finish or mouth and the parison as it presses upwards. Invert and final blow takes place followed by take-out and annealing. Anchor Glass Container Corp. (AGC) uses NNPB technology in their glass making plants. The problem experienced by AGC in the process is that the heat dissipation through out the mold is not uniform and hence there is a non uniform temperature distribution …

A Model For Strategic Bidding In Combined Transmission And Wholesale Energy Markets, Sanket Gupte

USF Tampa Graduate Theses and Dissertations

Motivated by deregulation in major service sectors like airlines, banking and telecommunication, the electric industry is undergoing a major transformation. However due to design inefficiencies, restructuring of the power sector, so far, has not been a major success. A lack of comprehensive quantitative models has resulted in the inability of the market designers to evaluate market performance and develop successful market designs. A comprehensive model should include market features like two-settlement system, transmission congestion, financial transmission rights (FTRs), demand elasticity, demand-side bidding and other market rules.

The contribution of this thesis includes development of an exhaustive modeling framework that includes …

Distributed Clustering For Scaling Classic Algorithms, Prodip Hore

USF Tampa Graduate Theses and Dissertations

Clustering large data sets recently has emerged as an important area of research. The ever-increasing size of data sets and poor scalability of clustering algorithms has drawn attention to distributed clustering for partitioning large data sets. Sometimes, centrally pooling the distributed data is also expensive. There might be also constraints on data sharing between different distributed locations due to privacy, security, or proprietary nature of the data. In this work we propose an algorithm to cluster large-scale data sets without centrally pooling the data. Data at distributed sites are clustered independently i.e. without any communication among them. After partitioning the …

Re-Constructing The Image Of The Voluntarily Childfree: An Ethnographic Exploration Of Media Representation And The Childless By Choice, Eddy Sass

USF Tampa Graduate Theses and Dissertations

In the United States, like most other parts of the world, there is a commonly held belief that all capable couples should have children. This belief has contributed to the development of a pro-natalist ideology or concept that having children is good. This pronatalist belief tends to spill over into the media, as well. Yet, there are those individuals who do not subscribe to the parenthood belief structure and to the manner in which the media frame the parenthood debate. These people are known as the voluntarily childfree or the childless by choice. This thesis is an exploratory ethnographic examination …

Robust Dock Assignments At Less-Than-Truckload Terminals, Mesut Korhan Acar

USF Tampa Graduate Theses and Dissertations

Less-than-truckload industry has a valuable potential for applications of operations research in two areas, network design and efficiency improvement within existing networks. This thesis focuses on the latter, specifically the less-than-truckload terminals where cross docking operations occur.

The assignment of incoming trailers to inbound docks is one of the critical decisions that affect the performance of less-than-truckload terminals. This research reviews existing models in literature and introduces an optimal mixed integer quadratic model with the objective of generating assignments that are robust against variability in system parameters such as truck arrival and service times, terminal characteristics and trailer load content. …

Effects Of Aspirin And Its Derivatives In Combination With Electroporation For Drug Delivery In Cultured Cells, Jennifer Langham

USF Tampa Graduate Theses and Dissertations

The purpose of this research was to investigate the effects that aspirin (ASA) and its metabolites, salicylic acid (SA) and acetic acid (AA), have on the delivery of drugs across biological barriers when used in conjunction with electroporation. Electroporation is a technique used to enhance drug delivery across bio-membranes in which a transmembrane potential is induced into cellular membranes, resulting in the creation of aqueous pores that allow molecules to pass through the otherwise impermeable barrier. Aspirin is a widely used drug that has been used for over a century and has been proven relatively safe at normal doses as …

Involution Codes With Application To Dna Strand Design, Kalpana Mahalingam

USF Tampa Graduate Theses and Dissertations

The set of all sequences that are generated by a bio-molecular protocol forms a language over the four letter alphabet Delta = [A,G,C,T]. This alphabet is associated with natural involution mapping Theta, A maps to T and G maps to C which is an antimorphism of Delta* In order to avoid undesirable Watson-Crick bonds between the words the language has to satisfy certain coding properties. Hence for an involution Theta we consider involution codes: Theta-infix, Theta-comma-free, Theta-k-codes and Theta-subword-k-codes which avoid certain undesirable hybridization. We investigate the closure properties of these codes and also the conditions under which both X …

A Decision Support Tool For Accepting Or Rejecting Donations In Humanitarian Relief Organizations, Francisco Javier Ruiz-Brand

USF Tampa Graduate Theses and Dissertations

With the increase in the occurrence of disasters (natural and man-made) that leave people injured, handicapped or dead, the disaster management theory is gaining more importance. As a consequence, human assistance and disaster relief organizations are managing increasingly more inventories anticipated to help people in need. Donations are the common means used by humanitarian relief organizations for procuring commodities to support some of their programs. Previous experiences have indicated that donations become a burden instead of offering relief when they do not match actual victims' needs. Accepting or rejecting donations is a key issue that can produce not only economic …

Characterization Of Hfo2 Films For Flash Memory Applications, Surendra Gaddipati

USF Tampa Graduate Theses and Dissertations

The scaling of integrated circuits requires the use of alternative dielectric materials as the replacement for silicon dioxide in the submicron devices. The scaling limit for silicon dioxide used in MOSFETs is 1.2nm and the Oxide Nitride Oxide (ONO) stack used in flash memory applications is 13.0nm. The use of alternative dielectrics with high- κ value will alleviate the problem of charge retention and also would help to decrease the programming voltage in case of flash memory cells.

Many alternative high- κ dielectric materials such as TaO₂, TiO₂, Al₂O₃ etc., have been examined …

Cadmium Zinc Telluride Solar Cells By Close Spaced Sublimation, Madhan Raj Ramalingam

USF Tampa Graduate Theses and Dissertations

Cadmium Zinc Telluride (Cd_xZn_1-xTe or CZT) is a ternary semiconductor with a tunable bandgap of 1.44-2.26 eV. Solar cells with efficiencies of 20% or higher can be achieved by using a tandem solar cell structure which consists of a top cell and a bottom cell connected in series. In this kind of a structure, the light passes through the top cell first which has a wider bandgap to absorb light of shorter wavelengths and the remaining light passes through the bottom cell with a lower bandgap to absorb light of higher wavelengths. For a tandem cell …

The Perceived Impact Of The Individuals With Disabilities Education Act (Idea), 1997 Disciplinary Mandates On The School Board Policies In Three Urban, K-12 Public School Districts, Nancy S. Zambito

USF Tampa Graduate Theses and Dissertations

In 1990 the Individuals with Disabilities Education Act (IDEA) required that states provide a free and appropriate education to all children and youth with disabilities, no matter how severe the disabilities. This obligation was tied to federal funding and outlined in detail parental rights with regard to identifying and educating their child with disabilities. The 1997 reauthorization of IDEA stepped into school discipline, creating a complex process for addressing school misconduct of such students.

This study determines how the 1997 IDEA disciplinary mandates, as they existed until May 2003, were interpreted and implemented in three similar, urban, public school districts …

Tutor Attitudes Toward Tutoring Creative Writers In Writing Centers, Leah F. Cassorla

USF Tampa Graduate Theses and Dissertations

This study concerns itself with tutor attitudes toward tutoring creative writers in writing centers. In it, I look at these attitudes and compare tutor definitions of creative writing, tutor comfort with tutoring writers, and tutor training. Tutors attitudes toward their training and their beliefs about what training to tutor creative writers should entail tell a great deal about the privileging of creative writing and creative writers in writing centers. This study is an important first step in considering that privileging, its source, and its effects.

For the study, tutors completed an online survey. They were not asked for any identifying …

Improved 1/F Noise Measurements For Microwave Transistors, Clemente Toro Jr.

USF Tampa Graduate Theses and Dissertations

Minimizing electrical noise is an increasingly important topic. New systems and modulation techniques require a lower noise threshold. Therefore, the design of RF and microwave systems using low noise devices is a consideration that the circuit design engineer must take into account. Properly measuring noise for a given device is also vital for proper characterization and modeling of device noise. In the case of an oscillator, a vital part of a wireless receiver, the phase noise that it produces affects the overall noise of the system. Factors such as biasing, selectivity of the input and output networks, and selectivity of …

Accuracy And Bias Of Tdr Measurements In Compacted Sands, Newel Kimball White

USF Tampa Graduate Theses and Dissertations

It is essential to properly monitor in-situ soil compaction properties during most earthwork construction projects. Traditional in-situ soil compaction monitoring methods are often limited in their application. As a result, new methods are being developed to more accurately measure in-situ compaction parameters. Time domain reflectometry (TDR) is one such method. Relying on the propagation of an electromagnetic wave through the soil sample, TDR can be used to measure both in-situ moisture content as well as soil dry density. Although TDR is relatively new to the field of geotechnical engineering, it has previously been implemented in other fields with success. Researchers …

The Impact Of Technology On Community College Students’ Success In Remedial/Developmental Mathematics, Mary M. Bendickson

USF Tampa Graduate Theses and Dissertations

Increased institutional accountability and fiscal constraints coupled with most community college students being required to take at least one remedial/developmental course indicates a need to find the best way to deliver these classes. Institutions are expanding alternate delivery formats to meet student expectations. Is using technology best for students in remedial/developmental courses?

This study investigated effectiveness of technology-assisted instruction for remedial/developmental math in Florida community colleges. Technology has emerged as potentially enhancing student success; however, it is expensive. If research shows that students benefit from technology in remedial/developmental courses, then funds spent to provide instruction through technology are validated. However, …

Recycled Materials Relational Database: Design And Implementation Aspects, Rory Morgan Mcdonald

USF Tampa Graduate Theses and Dissertations

Although there has been a rise in the use of recycled materials in highway and geotechnical systems, many tons of potentially useful industrial and domestic by-products are still being discarded in the United States each year. While extensive research has been conducted to investigate the use of recycled materials in engineering applications, the dissemination of the findings is often limited. The problem is compounded by the lack of a single resource containing relevant engineering and environmental characteristics of each material; the tendency of the researchers to publish their findings in technical reports rather than archived publications; and the wide discrepancies …

Characterization Of Cadmium Zinc Telluride Solar Cells By Rf Sputtering, Senthilnathan Subramanian

USF Tampa Graduate Theses and Dissertations

High efficiency solar cells can be attained by the development of two junctions one stacked on top of each other into tandem structures. So that, if a photon is not able to excite an electron-hole pair in the top cell can create a pair in the bottom cell, which has a smaller bandgap. For a two junction tandem device structure, the bandgap of the top cell should be 1.6-1.8eV and for the bottom cell should be 1eV to attain efficiencies in the range of 25%. Cadmium Zinc Telluride which has a tunable bandgap of 1.45- 2.2eV is a candidate for …