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Hexahydro-1,3,5-Trinitro-1,3,5-Triazine (Rdx) Reduction By Granular Zero-Valent Iron In Continuous Flow Reactor, Amalia Terracciano, Jie Ge, Agamemnon Koutsospyros, Xiaoguang Meng, Benjamin Smolinski, Per Arienti Oct 2018

Hexahydro-1,3,5-Trinitro-1,3,5-Triazine (Rdx) Reduction By Granular Zero-Valent Iron In Continuous Flow Reactor, Amalia Terracciano, Jie Ge, Agamemnon Koutsospyros, Xiaoguang Meng, Benjamin Smolinski, Per Arienti

Civil Engineering Faculty Publications

Wastewater streams containing hexahydro-1, 3, 5-trinitro-1, 3, 5-triazine (RDX) are subject to regulatory discharge regulations that require processing through industrial waste treatment. Thus, the development of easy-to-apply technologies for the treatment of RDX-laden wastewater streams is imperative. In the present study, the reduction of RDX by granular zero valent iron (GZVI) in batch and column experiments was investigated. Preliminary batch tests conducted under both oxic and anoxic conditions showed that after 3.0 hours of reaction with GZVI, RDX was mainly converted to formaldehyde (CH2O), nitrate (NO3 - ), and ammonium (NH4 + ). Column filtration tests …


Stabilization Of Lead (Pb) And Zinc (Zn) In Contaminated Rice Paddy Soil Using Starfish: A Preliminary Study, Deok Hyun Moon, Inseong Hwang, Agamemnon Koutsospyros, Kyung Hoon Cheong, Yong Sik Ok, Won Hyun Ji, Jeong Hun Park Feb 2018

Stabilization Of Lead (Pb) And Zinc (Zn) In Contaminated Rice Paddy Soil Using Starfish: A Preliminary Study, Deok Hyun Moon, Inseong Hwang, Agamemnon Koutsospyros, Kyung Hoon Cheong, Yong Sik Ok, Won Hyun Ji, Jeong Hun Park

Civil Engineering Faculty Publications

Lead (Pb) and zinc (Zn) contaminated rice paddy soil was stabilized using natural (NSF) and calcined starfish (CSF). Contaminated soil was treated with NSF in the range of 0-10 wt.% and CSF in the range of 0-5 wt.% and cured for 28 days. Toxicity characteristic leaching procedure (TCLP) test was used to evaluate effectiveness of starfish treatment. Scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX) analyses were conducted to investigate the mechanism responsible for effective immobilization of Pb and Zn. Experimental results suggest that NSF and CSF treatments effectively immobilize Pb and Zn in treated rice paddy soil. TCLP levels for …


Life Cycle Environmental And Economic Performance Of Biochar Compared With Activated Carbon: A Meta-Analysis, Hashim A. Alhashimi, Can B. Aktas Mar 2017

Life Cycle Environmental And Economic Performance Of Biochar Compared With Activated Carbon: A Meta-Analysis, Hashim A. Alhashimi, Can B. Aktas

Civil Engineering Faculty Publications

As the commercial production and distribution of biochar continues to grow internationally, and its applications diversifying from its early uses as soil amendment, it is important to study the environmental impacts and economic performance of biochar in comparison to activated carbon in order to assess its value. The goal of the study was to assess, through a meta-analysis, the environmental and economic performance of biochar in comparison to activated carbon under an equivalent functional unit to adsorb heavy metals. More than 80 data points on adsorption capacity of biochar and activated carbon were identified through literature, which were statistically analyzed …


Quality Improvement Of Acidic Soils By Biochar Derived From Renewable Materials, Deok Hyun Moon, Inseong Hwang, Yoon-Young Chang, Agamemnon Koutsospyros, Kyung Hoon Cheong, Won Hyun Ji, Jeong Hun Park Feb 2017

Quality Improvement Of Acidic Soils By Biochar Derived From Renewable Materials, Deok Hyun Moon, Inseong Hwang, Yoon-Young Chang, Agamemnon Koutsospyros, Kyung Hoon Cheong, Won Hyun Ji, Jeong Hun Park

Civil Engineering Faculty Publications

Biochar derived from waste plant materials and agricultural residues was used to improve the quality of an acidic soil. The acidic soil was treated for 1 month with both soy bean stover-derived biochar and oak-derived biochar in the range of 1 to 5 wt% for pH improvement and exchangeable cation enhancement. Following 1 month of treatment, the soil pH was monitored and exchangeable cations were measured. Moreover, a maize growth experiment was performed for 14 days with selected treated soil samples to confirm the effectiveness of the treatment. The results showed that the pH of the treated acidic soil increased …


Immobilization Of Lead In Contaminated Firing Range Soil Using Biochar, Deok Hyun Moon, Jae-Woo Park, Yoon-Young Chang, Yong Sik Ok, Sang Soo Lee, Mahtab Ahmad, Agamemnon Koutsospyros, Jeong Hun Park, Kitae Baek Dec 2013

Immobilization Of Lead In Contaminated Firing Range Soil Using Biochar, Deok Hyun Moon, Jae-Woo Park, Yoon-Young Chang, Yong Sik Ok, Sang Soo Lee, Mahtab Ahmad, Agamemnon Koutsospyros, Jeong Hun Park, Kitae Baek

Civil Engineering Faculty Publications

Soybean stover-derived biochar was used to immobilize lead (Pb) in military firing range soil at a mass application rate of 0 to 20 wt.% and a curing period of 7 days. The toxicity characteristic leaching procedure (TCLP) was performed to evaluate the effectiveness of the treatment. The mechanism responsible for Pb immobilization in military firing range soil was evaluated by scanning electron microscopy-energy dispersive x-ray spectroscopy (SEM-EDX) and x-ray absorption fine structure (XAFS) spectroscopy analyses. The treatment results showed that TCLP Pb leachability decreased with increasing biochar content. A reduction of over 90 % in Pb leachability was achieved upon …