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Wastewater Remediation Technologies Using Macroscopic Graphene-Based Materials: A Perspective, Rajan Arjan Kalyan Hirani, Abdul Hannan Asif, Nasir Rafique, Lei Shi, Shu Zhang, Hong Wu, Hongqi Sun May 2021

Wastewater Remediation Technologies Using Macroscopic Graphene-Based Materials: A Perspective, Rajan Arjan Kalyan Hirani, Abdul Hannan Asif, Nasir Rafique, Lei Shi, Shu Zhang, Hong Wu, Hongqi Sun

Research outputs 2014 to 2021

Three-dimensional (3D) graphene-based macrostructures are being developed to combat the issues associated with two-dimensional (2D) graphene materials in practical applications. The 3D macrostructures (3DMs), for example, membranes, fibres, sponges, beads, and mats, can be formed by the self-assembly of 2D graphene-based precursors with exceptional surface area and unique chemistry. With rational design, the 3D macrostructures can then possess outstanding properties and exclusive structures. Thanks to various advantages, these macrostructures are competing in a variety of applications with promising performances unlike the traditional activated carbons, biochars and hydrochars, which have less flexibilities for modifications towards versatile applications. However, despite having such …


A Review Of Enhancement Of Biohydrogen Productions By Chemical Addition Using A Supervised Machine Learning Method, Yiyang Liu, Jinze Liu, Hongzhen He, Shanru Yang, Yixiao Wang, Jin Hu, Huan Jin, Tianxiang Cui, Gang Yang, Yong Sun Jan 2021

A Review Of Enhancement Of Biohydrogen Productions By Chemical Addition Using A Supervised Machine Learning Method, Yiyang Liu, Jinze Liu, Hongzhen He, Shanru Yang, Yixiao Wang, Jin Hu, Huan Jin, Tianxiang Cui, Gang Yang, Yong Sun

Research outputs 2014 to 2021

In this work, the impact of chemical additions, especially nano‐particles (NPs), was quan-titatively analyzed using our constructed artificial neural networks (ANNs)‐response surface methodology (RSM) algorithm. Fe‐based and Ni‐based NPs and ions, including Mg2+, Cu2+, Na+, NH4+, and K+, behave differently towards the response of hydrogen yield (HY) and hydrogen evolution rate (HER). Manipulating the size and concentration of NPs was found to be effective in enhancing the HY for Fe‐based NPs and ions, but not for Ni‐based NPs and ions. An optimal range of particle size (86–120 nm) and Ni‐ion/NP concentration (81–120 mg L−1) existed for HER. Meanwhile, the manipulation …


Mapping Cyber-Enabled Crime: Understanding Police Investigations And Prosecutions Of Cyberstalking, Brianna Jane O'Shea, Nicole L. Asquith, Jeremy Prichard Jan 2021

Mapping Cyber-Enabled Crime: Understanding Police Investigations And Prosecutions Of Cyberstalking, Brianna Jane O'Shea, Nicole L. Asquith, Jeremy Prichard

Research outputs 2014 to 2021

Stalking is one of the main types of abusive behaviour facilitated by technology. The purpose of the current study was twofold: to identify the challenges of cyberstalking investigations and prosecutions in Australia and determine how best to investigate these types of offences. A qualitative analysis of four years of interviews, focus groups and participant observations with police departments provides an overview of the cyberstalking investigative process. The findings map out the process from the initial report of the incident to the preparation of the prosecution brief. This analysis positions cyberstalking investigations as an interesting case study in the midst of …


N Evolution And Physiochemical Structure Changes In Chars During Co-Pyrolysis: Effects Of Abundance Of Glucose In Fiberboard, Deliang Xu, Liu Yang, Ming Zhao, Yu Song, Karnowo, Hong Zhang, Xun Hu, Hongqi Sun, Shu Zhang Jan 2020

N Evolution And Physiochemical Structure Changes In Chars During Co-Pyrolysis: Effects Of Abundance Of Glucose In Fiberboard, Deliang Xu, Liu Yang, Ming Zhao, Yu Song, Karnowo, Hong Zhang, Xun Hu, Hongqi Sun, Shu Zhang

Research outputs 2014 to 2021

© 2020 by the authors. The simple incineration of wood-based panels (WBPs) waste generates a significant amount of NOx, which has led to urgency in developing a new method for treating the N-containing biomass residues. This work aims to examine the N evolution and physiochemical structural changes during the co-pyrolysis of fiberboard and glucose, where the percentage of glucose in the feedstock was varied from 0% to 70%. It was found that N retention in chars was monotonically increased with increasing use of glucose, achieving ~60% N fixation when the glucose accounted for 70% in the mixture. Pyrrole-N (N-5) and …


A Review Of Biohydrogen Productions From Lignocellulosic Precursor Via Dark Fermentation: Perspective On Hydrolysate Composition And Electron‐Equivalent Balance, Yiyang Liu, Jingluo Min, Xingyu Feng, Yue He, Jinze Liu, Yixiao Wang, Jun He, Hainam Do, Valerie Sage, Gang Yang, Yong Sun Jan 2020

A Review Of Biohydrogen Productions From Lignocellulosic Precursor Via Dark Fermentation: Perspective On Hydrolysate Composition And Electron‐Equivalent Balance, Yiyang Liu, Jingluo Min, Xingyu Feng, Yue He, Jinze Liu, Yixiao Wang, Jun He, Hainam Do, Valerie Sage, Gang Yang, Yong Sun

Research outputs 2014 to 2021

This paper reviews the current technological development of bio-hydrogen (BioH2) generation, focusing on using lignocellulosic feedstock via dark fermentation (DF). Using the collected reference reports as the training data set, supervised machine learning via the constructed artificial neuron networks (ANNs) imbedded with feed backward propagation and one cross-out validation approach was deployed to establish correlations between the carbon sources (glucose and xylose) together with the inhibitors (acetate and other inhibitors, such as furfural and aromatic compounds), hydrogen yield (HY), and hydrogen evolution rate (HER) from reported works. Through the statistical analysis, the concentrations variations of glucose (F-value = …


Application Of Biochar Derived From Pyrolysis Of Waste Fiberboard On Tetracycline Adsorption In Aqueous Solution, Deliang Xu, Yaxuan Gao, Zixiang Lin, Wenran Gao, Hong Zhang, Karnowo Karnowo, Xun Hu, Hongqi Sun, Syed S. A. Syed-Hassan, Shu Zhang Jan 2020

Application Of Biochar Derived From Pyrolysis Of Waste Fiberboard On Tetracycline Adsorption In Aqueous Solution, Deliang Xu, Yaxuan Gao, Zixiang Lin, Wenran Gao, Hong Zhang, Karnowo Karnowo, Xun Hu, Hongqi Sun, Syed S. A. Syed-Hassan, Shu Zhang

Research outputs 2014 to 2021

In this study, biochars derived from waste fiberboard biomass were applied in tetracycline (TC) removal in aqueous solution. Biochar samples were prepared by slow pyrolysis at 300, 500, and 800°C, and were characterized by ultimate analysis, Fourier transform infrared (FTIR), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Brunauer–Emmett–Teller (BET), etc. The effects of ionic strength (0–1.0 mol/L of NaCl), initial TC concentration (2.5–60 ppm), biochar dosage (1.5–2.5 g/L), and initial pH (2–10) were systemically determined. The results present that biochar prepared at 800°C (BC800) generally possesses the highest aromatization degree and surface area with abundant pyridinic N (N-6) and …


A Review Of The Enhancement Of Bio-Hydrogen Generation By Chemicals Addition, Yong Sun, Jun He, Gang Yang, Guangzhi Sun, Valérie Sage Apr 2019

A Review Of The Enhancement Of Bio-Hydrogen Generation By Chemicals Addition, Yong Sun, Jun He, Gang Yang, Guangzhi Sun, Valérie Sage

Research outputs 2014 to 2021

Bio-hydrogen production (BHP) produced from renewable bio-resources is an attractive route for green energy production, due to its compelling advantages of relative high efficiency, cost-effectiveness, and lower ecological impact. This study reviewed different BHP pathways, and the most important enzymes involved in these pathways, to identify technological gaps and effective approaches for process intensification in industrial applications. Among the various approaches reviewed in this study, a particular focus was set on the latest methods of chemicals/metal addition for improving hydrogen generation during dark fermentation (DF) processes; the up-to-date findings of different chemicals/metal addition methods have been quantitatively evaluated and thoroughly …


Fingerprinting Blue Carbon: Rationale And Tools To Determine The Source Of Organic Carbon In Marine Depositional Environments, Nathan R. Geraldi, Alejandra Ortega, Oscar Serrano, Peter I. Macreadie, Catherine E. Lovelock, Dorte Krause-Jensen, Hilary Kennedy, Paul S. Lavery, Michael L. Pace, Joeri Kaal, Carlos M. Duarte Jan 2019

Fingerprinting Blue Carbon: Rationale And Tools To Determine The Source Of Organic Carbon In Marine Depositional Environments, Nathan R. Geraldi, Alejandra Ortega, Oscar Serrano, Peter I. Macreadie, Catherine E. Lovelock, Dorte Krause-Jensen, Hilary Kennedy, Paul S. Lavery, Michael L. Pace, Joeri Kaal, Carlos M. Duarte

Research outputs 2014 to 2021

Blue carbon is the organic carbon in oceanic and coastal ecosystems that is captured on centennial to millennial timescales. Maintaining and increasing blue carbon is an integral component of strategies to mitigate global warming. Marine vegetated ecosystems (especially seagrass meadows, mangrove forests, and tidal marshes) are blue carbon hotspots and their degradation and loss worldwide have reduced organic carbon stocks and increased CO2 emissions. Carbon markets, and conservation and restoration schemes aimed at enhancing blue carbon sequestration and avoiding greenhouse gas emissions, will be aided by knowing the provenance and fate of blue carbon. We review and critique current …


Evaluation Of Bio-Asphalt Binders Modified With Biochar: A Pyrolysis By-Product Of Mesua Ferrea Seed Cover Waste, Abhinay Kumar, Rajan Choudhary, Rumi Narzari, Rupam Kataki, Sanjay K. Shukla Jan 2018

Evaluation Of Bio-Asphalt Binders Modified With Biochar: A Pyrolysis By-Product Of Mesua Ferrea Seed Cover Waste, Abhinay Kumar, Rajan Choudhary, Rumi Narzari, Rupam Kataki, Sanjay K. Shukla

Research outputs 2014 to 2021

With growing global concerns related to energy security and sustainability, interest in bio-fuels has increased significantly. Production of biofuel mostly begins with pyrolysis, a process that converts the biomass to liquid biooil, solid biochar and gases. A large amount of carbonaceous biochar is generated as a by-product during the pyrolysis. However, no major effort has been made in the past decade to utilize the biochar in pavement applications, especially as a bio-modifier to asphalt binders. In this study, an attempt was made to evaluate the carbonaceous biochar, obtained during bio-fuel production through pyrolysis of Mesua ferrea seed cover waste, as …