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2022

Physics

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Carrier Transport Engineering In Wide Bandgap Semiconductors For Photonic And Memory Device Applications, Ravi Teja Velpula Dec 2022

Carrier Transport Engineering In Wide Bandgap Semiconductors For Photonic And Memory Device Applications, Ravi Teja Velpula

Dissertations

Wide bandgap (WBG) semiconductors play a crucial role in the current solid-state lighting technology. The AlGaN compound semiconductor is widely used for ultraviolet (UV) light-emitting diodes (LEDs), however, the efficiency of these LEDs is largely in a single-digit percentage range due to several factors. Until recently, AlInN alloy has been relatively unexplored, though it holds potential for light-emitters operating in the visible and UV regions. In this dissertation, the first axial AlInN core-shell nanowire UV LEDs operating in the UV-A and UV-B regions with an internal quantum efficiency (IQE) of 52% are demonstrated. Moreover, the light extraction efficiency of this …


Photonic Monitoring Of Atmospheric Fauna, Adrien P. Genoud Dec 2022

Photonic Monitoring Of Atmospheric Fauna, Adrien P. Genoud

Dissertations

Insects play a quintessential role in the Earth’s ecosystems and their recent decline in abundance and diversity is alarming. Monitoring their population is paramount to understand the causes of their decline, as well as to guide and evaluate the efficiency of conservation policies. Monitoring populations of flying insects is generally done using physical traps, but this method requires long and expensive laboratory analysis where each insect must be identified by qualified personnel. Lack of reliable data on insect populations is now considered a significant issue in the field of entomology, often referred to as a “data crisis” in the field. …


Helioseismic Diagnostics Of Active Regions And Their Magnetic Fields, John T. Stefan Dec 2022

Helioseismic Diagnostics Of Active Regions And Their Magnetic Fields, John T. Stefan

Dissertations

While two and a half decades of nearly constant observation by the Solar and Heliospheric Observatory (SOHO) and the Solar Dynamics Observatory (SDO) spacecraft have yielded key insights into the structure and dynamics of active regions, it is still unclear if active regions can be identified before emerging on the solar surface and, once emerged, whether the subsurface structure of an active region’s magnetic field can be measured. Regarding the dynamical processes associated with active regions, the height and mechanism of sunquake excitation remains poorly understood. To answer these questions, a comprehensive survey of active region magnetic fields and their …


Hydrodynamic Investigation Of The Discharge Of Complex Fluids From Dispensing Bottles Using Experimental And Computational Approaches, Baran Teoman Dec 2022

Hydrodynamic Investigation Of The Discharge Of Complex Fluids From Dispensing Bottles Using Experimental And Computational Approaches, Baran Teoman

Dissertations

The discharge of non-Newtonian, complex fluids through orifices of industrial tanks, pipes, dispensers, or packaging containers is a ubiquitous but often problematic process because of the complex rheology of such fluids and the geometry of the containers. This, in turn, reduces the discharge rate and results in residual fluid left in the container, often referred to as heel. Heel formation is undesired in general, since it causes loss of valuable material, container fouling, and cross-contamination between batches. Heel may be of significant concern not only in industrial vessels but also in consumer packaging. Despite its relevance, the research in this …


Interactions Of Amyloid Peptides With Lipid Membranes, Yanxing Yang Dec 2022

Interactions Of Amyloid Peptides With Lipid Membranes, Yanxing Yang

Dissertations

The aggregation of amyloid proteins into fibrils is a hallmark of several diseases including Alzheimer’s (AD), Parkinson’s, and Type II diabetes. This aggregation process involves the formation of small size oligomers preceding the formation of insoluble fibrils. Recent studies have shown that these oligomers are more likely to be responsible for cell toxicity than fibrils. A possible mechanism of toxicity involves the interaction of oligomers with the cell membrane compromising its integrity. In particular, oligomers may form pore-like structures in the cell membrane affecting its permeability or they may induce lipid loss via a detergent-like effect. This dissertation aims to …


Observation Of Novel Phases Of Quantum Matter Beyond Topological Insulator, Sabin Regmi Dec 2022

Observation Of Novel Phases Of Quantum Matter Beyond Topological Insulator, Sabin Regmi

Electronic Theses and Dissertations, 2020-

Because of the unique electronic properties, intriguing novel phenomena, and potentiality in quantum device applications, the quantum materials with non-trivial band structures have enticed a bulk of research works over the last two decades. The experimental discovery of the three-dimensional topological insulators (TIs) - bulk insulators with surface conduction via spin-polarized electrons - kicked off the flurry of research interests towards such materials, which resulted in the experimental discovery of new topological phases of matter beyond TIs. The topological semimetallic phase in Dirac, Weyl, and nodal-line semimetals is an example, where the classification depends on the dimensionality, degeneracy, and symmetry …


Systems Level Analysis Of Organelle Biogenesis In Saccharomyces Cerevisiae, Kiandokht Panjtan Amiri Dec 2022

Systems Level Analysis Of Organelle Biogenesis In Saccharomyces Cerevisiae, Kiandokht Panjtan Amiri

Arts & Sciences Electronic Theses and Dissertations

Eukaryotic cells contain hundreds of subcellular structures that serve different functions to maintain cellular homeostasis. A hallmark of Eukaryotic cells is its compartmentalization into membrane-bound organelles. One of the grand challenges in quantitative cell biology is understanding the precision with which cells assemble and maintain subcellular organelles. Despite identification of numerous molecular factors that regulate organelle sizes we lack insight into the quantitative principles underlying organelle size control. We examine organelle sizes from Saccharomyces cerevisiae and human iPS cells with mathematical theory to show that cells can robustly control average fluctuations in organelle size. By demonstrating that organelle sizes obey …


The Physics Of Associative Polymers And Applications To Biomolecular Condensates, Furqan Dar Dec 2022

The Physics Of Associative Polymers And Applications To Biomolecular Condensates, Furqan Dar

Arts & Sciences Electronic Theses and Dissertations

Biomolecular condensates represent a new and ubiquitous class of membraneless organelles (MLOs) that are essential for healthy cellular functioning. The constituent molecules of such condensates span a vast bio-macromolecular gamut from intrinsically disordered regions and proteins (IDPs/IDRs), to RNA and RNA-binding proteins (RNPs), to polymerases and DNA etc. Apart from being part of the regular healthy cell cycle, these condensates are also implicated in many diseases, most notably progressive neurodegenerative diseases like Amyotropic Lateral Sclerosis (ALS) and Huntingtin's Disease (HD). Since the constituent molecules of these condensates span a broad range of length scales and modes of interaction, uncovering a …


Quasiparticle And Excitonic Effects In Two-Dimensional Van Der Waals Materials, Linghan Zhu Dec 2022

Quasiparticle And Excitonic Effects In Two-Dimensional Van Der Waals Materials, Linghan Zhu

Arts & Sciences Electronic Theses and Dissertations

Since their discovery, low dimensional van der Waals materials have attracted increasing research interests. They serve as ideal platforms to study novel physics in reduced-dimensional systems, and are critical in nowadays’ nanotechnology applications. Due to the reduced dielectric screening in low dimensions, strong excited state properties dictate their electronic, transport and optical properties, the study of which calls for a description of the many-particle interactions beyond the traditional density functional theory. This is where the many-body perturbation theory comes into play. In this thesis, I will present a comprehensive study of the quasiparticle and excitonic properties of a variety of …


The Effect Of Ionization Density In Applications Of Radiation Detection, Dosimetry, And Therapy, Daniel Mulrow Dec 2022

The Effect Of Ionization Density In Applications Of Radiation Detection, Dosimetry, And Therapy, Daniel Mulrow

Arts & Sciences Electronic Theses and Dissertations

This dissertation covers a wide range of topics but is linked by the common theme of radiation interacting with materials and studying the result of those interactions. The introduction describes the fundamentals of how radiation interacts with material and how we are able to detect that radiation and the application of how we use those interactions in radiation oncology. The thesis starts with a chapter detailing the temperature dependence of the photophysics in two organic scintillators. This chapter is the foundation for a future study that will look the degree to which these scintillators can distinguish between gammas and neutrons …


Observation Of The Ξ_B^-→Λ_B^0 Π^- Decay And Measurement Of B(Ξ_B^-→Λ_B^0 Π^-), Zhuoming Li Dec 2022

Observation Of The Ξ_B^-→Λ_B^0 Π^- Decay And Measurement Of B(Ξ_B^-→Λ_B^0 Π^-), Zhuoming Li

Dissertations - ALL

We present the first observation of the weak decay Ξ−b → Λ0b π−, which is mediated by an s → u ̄ud transitionwithin the Ξ_b^- baryon. The analysis uses a pp collision data sample at a center-of-mass energy of 13 TeV corresponding to 5.5 fb^(−1) of integrated luminosity. The sample of Λb0 baryons used in this analysis are reconstructed through their decays to Λ+c π− and Λ+c π−π+π−. From a fit to the Ξ−b → Λ0b π− mass spectrum, the Ξ−b → Λ0b π− decay is observed with a significance of 11.3 standard deviations, thus establishing observation of this decay. …


Precise Measurement Of The Nuclear Dependence Of The Emc Effect In Light Nuclei, Abishek Karki, Abishek Karki Dec 2022

Precise Measurement Of The Nuclear Dependence Of The Emc Effect In Light Nuclei, Abishek Karki, Abishek Karki

Theses and Dissertations

Measurements of inclusive electron scattering cross-section ratios from light nuclei over a wide range of the Björken �� (0.3 < �� < 1) up to �� 2 = 8.3 GeV2 were made as part of experiment E10-10-008, which was conducted in Hall C at the Thomas Jefferson National Accelerator Facility. The measurements were performed using a beam energy of 10.602 GeV and an average beam current of 45 ��A. This dissertation provides a thorough description of the experiment as well as the extracted ratios of inclusive nuclear cross-sections with respect to the deuterium cross-sections (the EMC effect) for the targets 9 Be, 12 C, 10 B, and 11 B. The …


Molecular Insights Into The Redox Of Atmospheric Mercury Through Laser Spectroscopy, Rongrong Wu Cohen Dec 2022

Molecular Insights Into The Redox Of Atmospheric Mercury Through Laser Spectroscopy, Rongrong Wu Cohen

Theses and Dissertations

The widespread pollution of mercury motivates research into its atmospheric chemistry and transport. Gaseous elemental mercury (Hg(0)) dominates mercury emission to the atmosphere, but the rate of its oxidation to mercury compound (Hg(II)) plays a significant role in controlling where and when mercury deposits to ecosystems. Atomic bromine is regarded as the main oxidant for Hg(0) oxidation, known to initiate the oxidation via a two-step process in the atmosphere – formation of BrHg (R1) and subsequent reactions of BrHg with abundant free radicals Y, i.e., NO2, HOO, etc. (R2), where the reaction of BrHg +Y could also lead to the …


Evaluation Of Yttrium Stabilized Zirconium Thin Films With Secondary Ion Mass Spectrometry, Jeff Serfass Dec 2022

Evaluation Of Yttrium Stabilized Zirconium Thin Films With Secondary Ion Mass Spectrometry, Jeff Serfass

Seton Hall University Dissertations and Theses (ETDs)

Fuel Cells using solid oxides for the electrolyte material, or Solid Oxide Fuel Cells (SOFCs), can operate at high temperatures and have many benefits when compared to other electrolyte material-based fuel cells. SOFCs can, however still have problems when operating at these high temperatures. (~1,000 degrees Celsius) At high temperatures, the SOFC electrolyte resistivity goes up making the ionic conductivity decrease and therefore a loss of performance. The inclusion of low level Yttria to Zirconium Oxide (the electrolyte material) has been known to help reduce the resistivity at high operating temperatures. In this study, a series of Yttria stabilized Zirconium …


Possibilities For Inertial Electrostatic Confinement Fusion, Jeffrey Edward Black Dec 2022

Possibilities For Inertial Electrostatic Confinement Fusion, Jeffrey Edward Black

Dissertations and Theses

While most of the fusion energy research is focused on magnetic confinement, there have been several alternative confinement methods aimed at the development of smaller and less expensive reactors. A number of these devices utilize a spherically convergent beam of recirculating ions, a technique known as inertial electrostatic confinement (IEC). This study looks at several aspects of IEC devices, including measurements of the fusion rate of an IEC device with a wire mesh electrode cathode, and a solid titanium cathode. In addition, several computational studies were performed to explore the possibilities for IEC fusion. These include development of a 1D-1P …


Behaviors For Which Deinonychosaurs Used Their Feet, Alexander King Dec 2022

Behaviors For Which Deinonychosaurs Used Their Feet, Alexander King

Honors Projects

This paper seeks to show for what purpose deinonychosaurs used their feet. Fowler et al., (2011) showed that D. antirrhopus’s feet were closest in function to accipitrids, as they found it was more built for grasping prey than running.

I answered this question by using 2D images of the feet of three modern birds (Buteo jamaicensis, Phasianus colchicus, and Gallus gallus domesticus), one eudromaeosaur (Deinonychus antirrhopus), and one troodontid (Borogovia gracilicrus). I used ImageJ to apply 73 landmarks to each foot, capturing the variation between species in the metatarsals and pedal phalanges. These data were then uploaded to the software …


Core-Collapse Supernova Simulations With Spectral Two-Moment Neutrino Transport, Ran Chu Dec 2022

Core-Collapse Supernova Simulations With Spectral Two-Moment Neutrino Transport, Ran Chu

Doctoral Dissertations

The primary focus of this dissertation is to develop a next-generation, state-of-the-art neutrino kinetics capability that will be used in the context of the next-generation, state-of-the-art core-collapse supernova (CCSN) simulation frameworks \thornado\ and \FLASH.\index{CCSN} \thornado\ is a \textbf{t}oolkit for \textbf{h}igh-\textbf{or}der \textbf{n}eutrino-r\textbf{ad}iation hydr\textbf{o}dynamics, which is a collection of modules that can be incorporated into a simulation code/framework, such as \FLASH, together with a nuclear equation of state (EOS)\index{EOS} library, such as the \WeakLib\ EOS tables. The first part of this work extends the \WeakLib\ code to compute neutrino interaction rates from~\cite{Bruenn_1985} and produce corresponding opacity tables.\index{Bruenn 1985} The processes of emission, …


Development Of A New High-Resolution Neutron Detector And Beta-Delayed Neutron Spectroscopy Of 24o., Shree K. Neupane Dec 2022

Development Of A New High-Resolution Neutron Detector And Beta-Delayed Neutron Spectroscopy Of 24o., Shree K. Neupane

Doctoral Dissertations

An efficient neutron detection system with good energy resolution is needed to correctly characterize the decays of neutron-rich nuclei where beta-delayed neutron emission is a dominant decay mode. Precision neutron spectroscopy probes nuclear structure effects in neutron-rich nuclei and is essential to exploit the opportunities in new-generation radioactive beam facilities. A new high-resolution neutron detector, Neutron dEtector with Xn Tracking (NEXT), has been constructed, characterized, and tested in decay and reaction experiments. Its essential capability is the neutron interaction position localization, which enables improvement in energy resolution without compromising detection efficiency in the time-of-flight measurements. Neutron-gamma discrimination capability of NEXT …


Chasing Transients: Constructing Local Galaxy Catalogs For Electromagnetic Follow-Up Of Gravitational Wave Events, Chaoran Zhang Dec 2022

Chasing Transients: Constructing Local Galaxy Catalogs For Electromagnetic Follow-Up Of Gravitational Wave Events, Chaoran Zhang

Theses and Dissertations

Gravitational waves (GWs) provide a new window for observing the universe which is not possible using traditional electromagnetic (EM) wave astronomy. The coalescence of compact object binaries, such as black holes (BHs) and neutron stars (NSs) generates “loud" GW signals that are detectable by the LIGO-Virgo-KAGRA (LVK) GW Observa- tory. If the binary contains at least one NS, there is a possibility that an observable EM counterpart will be launched during and/or after the merger. The first joint detection of GW radiation (GW170817) and its EM counterpart (AT 2017gfo) greatly extended our understanding of the universe in many fields, such …


Classification Of Nuclear Pastas Through Alpha Shapes Model, Daniela Ramirez Chavez Dec 2022

Classification Of Nuclear Pastas Through Alpha Shapes Model, Daniela Ramirez Chavez

Open Access Theses & Dissertations

The nuclear pasta is important because is an astromaterial with incredible strength that may be a source for gravitational waves, which observe from the rotation of neutron stars. The characterization of the pasta is vital because the nuclear phases have transport properties - compressibility, neutrino opacity, thermal conductivity, and electrical conductivity - associated with their shape for which neutron stars may be sensitive. These properties could interpret observations of supernova neutrinos, magnetic field decay, and crust cooling of accreting neutron stars. Here, we study the nuclear pasta using alpha shapes to achieve a phase characterization with the Minkowski functionals (area, …


Towards The Electronic Response Of Carbon-Based Van Der Waals Heterostructures In A Diamond Anvil Cell, George Thomas Foskaris Dec 2022

Towards The Electronic Response Of Carbon-Based Van Der Waals Heterostructures In A Diamond Anvil Cell, George Thomas Foskaris

UNLV Theses, Dissertations, Professional Papers, and Capstones

The nanoscale regime of materials has been at the forefront of research and interest in condensed matter physics for many years. In a merger of the fields of two-dimensional (2D) materials and high pressure physics, we present an investigation of the electronic response of carbon-based, van der Waals (vdW) heterostructures in a diamond anvil cell (DAC). Combining these fields presents us with the ability to study the characteristics of such systems both optically, and through electrical transport. Properties such as conductance, band structure, and layer number are considered. The samples in this study are assembled using exfoliation and stacking techniques …


Day ‘N’ Nite: Habitability Of Tidally Locked Planets With Sporadic Rotation, Cody James Shakespeare Dec 2022

Day ‘N’ Nite: Habitability Of Tidally Locked Planets With Sporadic Rotation, Cody James Shakespeare

UNLV Theses, Dissertations, Professional Papers, and Capstones

Tidally locked worlds provide a unique opportunity for constraining the climates of detected exoplanets. They are unique in that few exoplanet spin and obliquity states are known or will be determined in the near future. The TRAPPIST-1 exoplanet system has multiple habitable zone planets that, in the past, have been presumed to be tidally locked. However, a recent study shows the dynamical conditions present in the TRAPPIST-1 system make rotation and large librations possible spin states for these planets. I confirm the tendency for these planets to sporadically transition from tidally locked libration to slow rotation using N-body simulations independent …


Display Applications For Grating Angle Magnification Accelerated Angular Scanners, Daniel Jesus Valdes Dec 2022

Display Applications For Grating Angle Magnification Accelerated Angular Scanners, Daniel Jesus Valdes

UNLV Theses, Dissertations, Professional Papers, and Capstones

This work includes experimental demonstrations of grating angle magnification accelerated optical beam scanners. Diffraction grating scanners governed by the grating equation can have scan speed advantages over the flat mirror bound by Snell's law of reflection. Scan speed enhancement of 750% was achieved with a 635nm laser and 1800 groove/mm diffraction grating configuration thanks to the grating angle magnification. A three-color diffraction grating scanner shows identical results at larger scan angles. Tunable acceleration speed is a feature enabled by the diffraction grating scanner to operate in a high-speed scanning region and/or high-resolution scanning region depending on the demands of the …


Denoising And Deconvolving Sperm Whale Data In The Northern Gulf Of Mexico Using Fourier And Wavelet Techniques, Kendal Mccain Leftwich Dec 2022

Denoising And Deconvolving Sperm Whale Data In The Northern Gulf Of Mexico Using Fourier And Wavelet Techniques, Kendal Mccain Leftwich

University of New Orleans Theses and Dissertations

The use of underwater acoustics can be an important component in obtaining information from the oceans of the world. It is desirable (but difficult) to compile an acoustic catalog of sounds emitted by various underwater objects to complement optical catalogs. For example, the current visual catalog for whale tail flukes of large marine mammals (whales) can identify even individual whales from their individual fluke characteristics. However, since sperm whales, Physeter microcephalus, do not fluke up when they dive, they cannot be identified in this manner. A corresponding acoustic catalog for sperm whale clicks could be compiled to identify individual …


Building Structures From Mycelium, Noah M. Brown Dec 2022

Building Structures From Mycelium, Noah M. Brown

Physics

The purpose of this project was to develop a method for creating bricks from mycelium and agricultural waste. The bulk of the research happened in two parts, the first part being a period in which different substrates, strains, and methods were used build the bricks. This research took place in San Luis Obispo and was aided by a group of students in PSC392 under Dr. Pete Schwartz in early 2022. After developing a method for constructing these bricks, the research was moved to St. Thomas, Jamaica, in collaboration with an ecovillage called The Source Farm from July to September. The …


Constraining The 30p(P,Γ)31s Reaction Using 30p(D,Pγ)31p With Goddess, Rajesh Ghimire Dec 2022

Constraining The 30p(P,Γ)31s Reaction Using 30p(D,Pγ)31p With Goddess, Rajesh Ghimire

Doctoral Dissertations

The 30P(p,γ)31S reaction acts as a bottleneck for classical nova nucleosynthesis beyond A=30 in ONe novae, due in part to the long lifetime of 30P (∼2.5 minutes) with respect to the timescale of a nova outburst. Also, the 30P(p,γ)31S reaction rate directly affects the isotopic ratio of 30Si/28Si, which is an important nova identifier in the analysis of pre-solar grains. O/S, S/Al, O/P, and P/Al elemental abundance ratios can be used as nuclear thermometers for classical novae by constraining the 30P(p,γ)31S reaction rate.

However, direct measurement of …


Quantifying The Magnitude Of Total Dose Deviation Caused By Various Sources Of Error Among Iroc Phantom Irradiation Results, Sharbacha S. Edward Dec 2022

Quantifying The Magnitude Of Total Dose Deviation Caused By Various Sources Of Error Among Iroc Phantom Irradiation Results, Sharbacha S. Edward

Dissertations & Theses (Open Access)

The Imaging and Radiation Oncology Core (IROC) phantoms are used as an end-to-end test of an institution’s radiotherapy processes, and for clinical trial credentialing. Phantoms are treated like patients, and evaluation of the doses received by the thermoluminescent dosimeters (TLDs) inside the phantom, reflects the accuracy with which an institution can image, plan and irradiate a phantom or patient. Recent phantom results show that among the hundreds of various IROC phantoms irradiated annually, 8-17% of institutions fail this test. The purpose of this work was to investigate the various types of errors that may occur during the treatment process and …


Application Of Flo-Sic To F-Electron Systems: Sixth Row Elements And Ligated Molecules, Alexander Irun Johnson Dec 2022

Application Of Flo-Sic To F-Electron Systems: Sixth Row Elements And Ligated Molecules, Alexander Irun Johnson

Open Access Theses & Dissertations

Density functional theory - the most widely used theoretical method to study atoms,molecules, and solids - suffers from the well-known self-interaction error. A solution to the problem was suggested by Perdew and Zunger [1], who showed the self-interaction error can be removed with self-interaction correction. In 2014, Pederson showed a unitary transformation can be performed on the Kohn-Sham orbitals to generate Fermi-Löwdin orbitals which improve atomization energies, and avoid the computational costs of solving the localization equations.[2] This method is known as the Fermi-Löwdin Orbital Self-Interaction Correction (FLO-SIC). Until now, the FLO-SIC methodology has been used for atoms not containing …


Modulation Of Non-Diffracting Hermite Gaussian Beams And Nonlinear Optical Microscopy For Nanoscale Sulfur Imaging, Gilberto Navarro Dec 2022

Modulation Of Non-Diffracting Hermite Gaussian Beams And Nonlinear Optical Microscopy For Nanoscale Sulfur Imaging, Gilberto Navarro

Open Access Theses & Dissertations

Hermite Gaussian beams are the solutions of the scalar paraxial wave equation in Cartesian coordinates. A method was developed to modulate the intensity profile of non-diffracting Hermite Gaussian (HG) beams. The original HG beamâ??s intensity profile consists of high intense corner lobes and low intense central lobes which is not ideal for structured illumination in light-field microscopy. The modulated HG beams were generated by multiplying the original HGâ??s beam envelope by a super-Gaussian envelope to modify the intensity profile to attain equal intensity lobes. The propagation of the original HG beam and modulated HG beam were compared to determine that …


Magnetic Structures Of Sawtooth Olivines Mn2six 4 (X = S, Se) Determined Through Neutron Powder Diffraction, Melaku Sisay Tafere Dec 2022

Magnetic Structures Of Sawtooth Olivines Mn2six 4 (X = S, Se) Determined Through Neutron Powder Diffraction, Melaku Sisay Tafere

Open Access Theses & Dissertations

In olivine chalcogenide Mn2SiX 4 (X = S, Se) compounds, the Mn lattice produces a sawtooth, which is of critical significance in magnetism due to the potential for manifesting at bands in the magnon spectrum, a crucial component in magnonics. The compounds Mn2SiS4 and Mn2SiSe4 in Mn2SiX 4 family undergo antiferromagnetic phase transitions at T â?? 85 K and â?? 66 K, respectively, as determined from the specific heat, Cp(T). The average and local crystal structuresare determined using synchrotron X-ray, neutron diffraction, and X-ray total scattering data followed by Rietveld and pair distribution function (PDF) analysis. It is found from …