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Part I. Thermodynamic Acidities Of Substituted Phenylacetylenes. Part Ii. Mercury Accumulation In Trout Of Southern Missouri, Eric T. Lloyd
Part I. Thermodynamic Acidities Of Substituted Phenylacetylenes. Part Ii. Mercury Accumulation In Trout Of Southern Missouri, Eric T. Lloyd
Masters Theses
"PART I: THERMODYNAMIC ACIDITIES OF SUBSTITUTED PHENYLACETYLENES The thermodynamic acidities (pKa) of phenylacetylene and several para substituted phenylacetylenes in methanol were determined at 25ºC. These acidity constants were determined using a quenching technique which involves converting the phenylacetylenic anion, present at equilibrium as sodium phenylacetylide, to the tritium labelled carbon acid. By liquid scintillation counting techniques, the concentration of the anion was determined and the pKa of the phenylacetylene compound calculated. The resulting pKa's are: p-nitrophenylacetylene, 17.98, p-bromophenylacetylene, 18.10, p-fluorophenylacetylene, 18.14, phenylacetylene, 18.50, and p-methylphenylacetylene, 18.60. The effect of a substituent in the para position on the relative acidities is …
A Study Of The Spectroscopic, Thermodynamic, And Dielectric Properties Of The T-Butylbenzene/Tetracyanoethylene Molecular Complex, Donald W. Mundell
A Study Of The Spectroscopic, Thermodynamic, And Dielectric Properties Of The T-Butylbenzene/Tetracyanoethylene Molecular Complex, Donald W. Mundell
Masters Theses
No abstract provided.