Digital Commons Network^™

Exploring Soil Microbial Dynamics In Southern Appalachian Forests: A Systems Biology Approach To Prescribed Fire Impacts, Saad Abd Ar Rafie

Doctoral Dissertations

Prescribed fires in Southern Appalachian forests are vital in ecosystem management and wildfire risk mitigation. However, understanding the intricate dynamics between these fires, soil microbial communities, and overall ecosystem health remains challenging. This dissertation addresses this knowledge gap by exploring selected aspects of this complex relationship across three interconnected chapters.

The first chapter investigates the immediate effects of prescribed fires on soil microbial communities. It reveals subtle shifts in porewater chemistry and significant increases in microbial species richness. These findings offer valuable insights into the interplay between soil properties and microbial responses during the early stages following a prescribed fire. …

Characterizing Silicate Materials Via Raman Spectroscopy And Machine Learning: Implications For Novel Approaches To Studying Melt Dynamics, Blake O. Ladouceur

Doctoral Dissertations

Silicate melt characteristics impose dramatic influence over igneous processes that operate, or have operated on, differentiated bodies: such as the Earth and Mars. Current understanding of these melt properties, such as composition, primarily comes from investigations on their volcanic byproducts. Therefore, it is imperative to innovate on modalities capable of constraining melt information in environments where a reliance on laboratory methods is severed. Recent investigations have turned to Raman Spectroscopy and amorphous volcanics as a suitable pairing for exploring these ideas. Silicate glasses are a proxy for igneous melts; and Raman spectroscopy is a robust analytical technique capable of operating …

Morphologic Analyses Of Paleozoic Rhombiferan Echinoderm Stems, Aidan R. Sweeney

Doctoral Dissertations

During the Paleozoic, echinoderms exhibited a diverse array of morphologies. This work specifically deals with an extinct stemmed group called glyptocystitoid rhombiferans. The goal of this work is to investigate functional morphology of the stem in this enigmatic group. Abnormalities in form are addressed herein by a brief literature review of teratologic features and in the description of a new species of pleurocystitid Pleurocystites? scylla. Morphologic specialization is discussed in the investigation of the internal structure and morphometrics of the mesotem of Brockocystis. Linear morphometrics, multiple imputation, and multivariate statistics were used to describe the variability exhibited in …

Utilizing Phylogenetic And Geochemical Techniques To Examine Echinoderms Through Time, Maggie Ryan Limbeck

Doctoral Dissertations

Understanding biotic changes through Earth’s history has been the goal of paleobiology since the inception of the field. Advances in science and technology have progressed allowing us to reassess old questions and new questions that could have not been addressed without these new methods. Echinoderms (sea stars, sea urchins, etc.) appear in the fossil record during the early Cambrian and are still abundant in marine ecosystems today. This persistence through time has made echinoderms model organisms to answer questions about Earth’s past and present. Despite this role as a model organism there are many questions that remain with respect to …

Metagenomic Investigation Of Microbial Dark Carbon Fixation, Viral Interactions, And Horizonal Gene Transfer Within A Convergent Margin Subsurface Ecosystem, Timothy Joseph Rogers

Doctoral Dissertations

Convergent margins are geological regions where two or more tectonic plates collide, and the denser “subducting slab” is pushed beneath the less dense overriding plate. As the slab descends, it devolatilizes under higher temperatures and pressures, allowing dissolved inorganic carbon (DIC) and redox active volatile rich fluids to cycle between the upper crust and Earth’s mantle. These fluids migrate through cracks and fissures in the upper mantle and crust, fueling chemolithoautotrophy-based microbial ecosystems in the subsurface before they are expelled on the surface in the form of hydrothermal seeps and springs. Chemolithoautotrophic ecosystems, such as those in the Costa Rican …

Numerical And Experimental Constraints On Trace Element Fractionation During Lunar Magma Ocean Solidification, Dian Ji

Masters Theses

Traditional lunar magma ocean (LMO) theory suggests the anorthositic lunar crust formed by floating of buoyant plagioclase, one of the major products of LMO solidification, on the surface of LMO. To test this model, after applying experimentally determined LMO solidification sequences, we compared calculated Rare Earth Element (REE) concentrations of lunar plagioclase to plagioclase in Apollo ferroan anorthosites and lunar anorthositic meteorites. Several initial LMO compositions, and lunar-relevant mineral-melt partition coefficient predictive models were tested (where the partition coefficient is the concentration ratio of a specific element between two phases). Compared with plagioclase in the natural samples, modeled plagioclase directly …

Large-Scale Volcanism On The Terrestrial Planets, Keenan Ben Golder

Doctoral Dissertations

Evidence for mafic volcanism has been found on each planet in the inner Solar System. Lava flows on these planets range in size from 10s to 1000s of kilometers in extent. I investigated large-scale lava flows on Mercury, Earth, and Mars throughout the chapters in this dissertation. Each of these lava flows provides an avenue to study the emplacement and evolution of lava on various planets and under differing conditions, the factors that affect their overall extent, and potential source areas.

Chapter One investigates large-scale lava flows in the Cerberus region on Mars, specifically to understand their emplacement history, material …

Evaluating Bulk Carbon And Nitrogen Isotope Compositions Of Acidic Hydrothermal Sediments On Earth– Implications For Mars Astrobiology, Chance Sturrup

Masters Theses

Carbon isotopes have been widely used as unique biosignatures because biologic processes commonly result in distinctive negative delta ¹³C values (-35 to -10 ‰) within organic material on Earth. However, the bulk delta ¹³C analysis in Gale crater sediments on Mars revealed a wider range of values, from -25 to +56 ‰ (Franz et al., 2020), which suggests a more complex origin. To determine if bulk isotope analysis can be successfully used to detect a microbial signature in a martian analog environment, we analyzed concentrations and isotope compositions of C within hydrothermal sediments in Iceland (Námafjall, Krýsuvík, Hveragerdi) …

Impact Of Cover Crop Species Diversity On Soil Nutrient Availability And Crop Productivity, Amanda Kramer

Masters Theses

Cover crops provide multiple environmental benefits that improve both soil and water quality; however, farmers only utilize them on approximately 5% of harvested U.S. cropland. Low adoption rates are attributed to yield impact concerns, seed and planting costs, and lack of advocacy. This study, which began in October 2019, assessed the effects of nitrogen rate and cover crop diversity on weed biomass, soil coverage, in-situ residue decomposition, soil nitrogen and phosphorus availability, and cash crop yield to better understand the costs and benefits of cover crop adoption at two locations in Tennessee (Milan and Spring Hill). Treatments were replicated 4 …

Natural, Experimental, And Educational Explorations Of The Interiors Of Terrestrial Planetary Bodies, Nadine L. Grambling

Doctoral Dissertations

Planetary interiors are enigmatic, inaccessible, and vital to the processes that have formed the rocks we see on the surface of bodies in the inner Solar System today. Based on geophysical explorations of the Moon and Earth, along with information gleaned from rocks at the surface today, there is understanding of the basic structure and processes at depth. Using a combination of natural samples and experimental studies, we attempt to learn more about the physical conditions beneath the surface, and their effect on material properties and tectonics processes in the mantle.

On Earth, mid-ocean ridge processes have long been debated, …

Geochemical And Climatic Controls On The Sulfur Cycle In Volcanic Settings: Implications For The Origin Of Sulfur-Rich Deposits Investigated By The Spirit And Opportunity Rovers On Mars, Rhianna D. Moore

Doctoral Dissertations

On Earth, volcanic activity with elevated sulfur (S) degassing in the presence of water leads to the formation of hydrothermal deposits enriched in S-bearing minerals. Similar processes may have been an important source of S on Mars. The landing sites of Gusev crater and Meridiani Planum investigated by the Spirit and Opportunity rovers, respectively, showed elevated SO₄^2- [sulfate] concentrations, suggesting high- and low-temperature aqueous processes. However, the SO₄^2- contribution from subsequent aqueous weathering of hydrothermal S deposits has been poorly constrained, thus its importance to regional S cycling in the landing sites is unclear. In this …

Experimental Approaches To Evaluating Silicate Melt Properties And Trace Element Fractionation During Crystallization At High Pressures And High Temperatures, Megan D. Mouser

Doctoral Dissertations

Current understanding of the evolution and behavior of silicate materials that form in planetary interiors at high-pressures and high-temperatures largely come from experimental work as natural samples are either rare, or physically inaccessible. Laboratory experiments provide a comprehensive way to constrain the crystallization history, elemental partitioning, and viscosity of different silicate materials at planetary mantle pressure and temperature conditions. This work utilizes two high-pressure experimental techniques, the Paris-Edinburgh apparatus, and the piston cylinder apparatus, to measure physical and chemical properties of silicate materials. The viscosity of reduced, Fe-free silicate liquids, with and without sulfur (S-free and S-bearing), were measured to …

Fan And Fracture Formation: Morphologic And Sedimentologic Characteristics Of Alluvial Fans On Earth And Mars, And Fracture Population Distributions On Europa, Claire A. Mondro

Doctoral Dissertations

Planetary science is inherently limited by the resolution and coverage of the currently available data. What can be observed in person, measured precisely in high-resolution data, or sampled for lab analysis in terrestrial investigations ca only be inferred, modeled, or hypothesized on other planetary bodies. The Earth remains our best tool for understanding the geologic systems of the rest of the Solar System. By applying what is known or can be measured about terrestrial systems, it is possible to determine how large-scale controls and observable features relate to geologic complexity that is beyond the resolution of planetary data. This dissertation …

Precambrian Molar-Tooth Structure: Unraveling The Diagenesis Of Ancient Carbonates, Agustin Kriscautzky

Doctoral Dissertations

Molar-tooth structure (MTS) is an enigmatic carbonate fabric that occurs mainly within Proterozoic carbonate host rocks. It is composed of two distinct features: cracks of various morphologies and crack-filling calcite microspar. Although the origins of MTS remain unknown, most previous investigation has focused on the formation of the cracks and mechanisms involved in the void space generation, with less emphasis on the intriguing carbonate fill. In this study I have investigated molar-tooth bearing carbonates from regions that span both paleogeography and geologic time. Analysis at the microscopic scale, including traditional petrography, cathodoluminescence petrography, scanning electron microscopy, and micrometer-scale geochemical analyses …

Comparative Geochemical Analysis Of Recent Volcanic Flows On Barva Volcano, Costa Rica, Julie Coulombe

Masters Theses

ABSTRACT

Barva Volcano is a dormant stratovolcano in the Cordillera Central region of Costa Rica, rising above the capital city of San Jose with a population of 347,000. Barva’s recent inactivity and extensive forestation have resulted in fewer investigations of its composition, petrogenesis, and eruptive history. The objective of this research is to analyze the geochemical data from several of the most recent lava flows, evaluate variability between eruptive units, and ascertain physical conditions within the Barva magma storage region. The data collected in this study helps constrain the geochemistry of units seen in the quarry and provides information regarding …

Manganese Geochemistry And Plant Availability In Response To Agricultural Practices, Ashleigh R. Montgomery

Masters Theses

Manganese (Mn) is an essential micronutrient for all organisms. In soils, Mn forms determine availability to plants. Most Mn research has been conducted in forest ecosystems and Mn cycling in agricultural systems is understudied. Therefore, the objective of the experiment is to understand the effect of different agricultural management strategies on Mn cycling and plant availability. First, a greenhouse experiment was conducted to determine the effect of different application rates of two Mn fertilizers (MnSO₄ and MnEDTA) on soil geochemical properties and growth of corn (Zea mays) and soybean (Glycine max). The fertilizers were applied to …

The Characterization Of Dynamic Soil Properties And Their Relation To Soil Organic Carbon In East Tennessee Soils, Shannon Marissa Newell

Masters Theses

Quantifying how dynamic soil properties (DSPs) are affected by different management regimes is essential for understanding how these vital resources can be better managed. The Dewey soil series is a critical soil series in East Tennessee. For this study, the University of Tennessee, Knoxville (UTK) worked alongside the National Cooperative Soil Survey (NCSS) in an effort to better understand the dynamics of the Dewey soil series through a wide range of DSP data. To accomplish this, Dewey soil was collected from five sites which are considered representative of five management regimes: well-managed cropland (WMC), poorly-managed cropland (PMC), well-managed pasture (WMP), …

Kinematic And Vorticity Analysis Of The Slide Lake And Homestake Shear Zones, Central Colorado, Carsen T. Adams

Masters Theses

Kinematic and quantitative vorticity analysis of the Homestake shear zone (HSZ) and the Slide Lake shear zone (SLSZ) in central Colorado provide further insight into crustal processes that controlled deformation within the Colorado Mineral Belt (CMB) shear zone system throughout the Proterozoic. Evaluating vorticity, that is, the relative contributions of pure to simple shear in sheared rocks, is crucial to understanding lithospheric tectonic evolution and allows for kinematic modeling of shear zone development at a variety of scales. Moreover, novel vorticity analyses involve determining the orientation of the vorticity vector and vorticity normal surface which can give insight into shear …

Challenges In Approaching The Detection Limits For Hillslope Erosion Using Terrestrial Laser Scanning, Gene Nathan Bailey Iii

Masters Theses

Accurately quantifying soil loss due to water erosion is a critical step in managing soils. Terrestrial LiDAR (Light Detection and Ranging) presents a potential alternative to traditional soil loss measurement by estimating soil erosion and deposition through detecting surface changes. Terrestrial LiDAR can also provide spatial distribution information without disturbing the observed surface. While erosion estimation through terrestrial LiDAR detects large magnitude erosion well, the finer temporal/spatial scale erosion experienced on the hillslope in sheet and rill erosion has remained a challenge to detect. This research addresses two of the challenges in using terrestrial LiDAR on fine scales in two …

Evaluation Of Microbiometer As A Tool To Estimate Soil Health In A West Tennessee Cotton Crop, Daniel T. Sain

Masters Theses

Healthy soils are critical for optimized yields and sustainability in agriculture. Soil health testing can provide valuable information on how management practices are affecting soil health. In west Tennessee, existing soil health tests were unable to discern between significant differences in management practices. A new soil health test called microBIOMETER® has been developed by Prolific Earth Sciences® (Montgomery, NY). MicroBIOMETER® utilizes a new methodology for estimating microbial biomass and uses that estimate as a soil health score. This test has not been validated for use in west Tennessee. This research was focused on the validation of microBIOMETER® in a continuous …

Understanding Hydrogen Variations In Silicate Glasses As A Result Of Degassing: Fire-Fountaining On The Moon And Earth, Erin M. Recchuiti

Masters Theses

Volatiles, particularly hydrogen, play a key role in volcanic eruptions, especially explosive eruptions like fire-fountaining [e.g., Saal et al. 2002; Dixon 1997; Arndt & von Engelhardt 1987; Yoder 1976]. Discerning volatile abundance and behavior during ascent and eruption can aid in understanding the source melt and primary volatile content of planetary interiors. Volcanic glasses are samples closest to the primary melt, as they quench quickly enough to limit fractionation or crystallization. This is paramount for volatile studies, especially pertaining to water as its constituents are oxygen and hydrogen. Hydrogen is the most volatile element and one of the first to …

Texture And Composition Of An Arid-Climate Weathering Profile And The Link Between Bedrock And Derived Sediment Composition, Kristan Leigh Watkins

Masters Theses

Multiple compositional aspects of Holocene, terrigenous-clastic sediment differ from its source, the underlying Cretaceous Stepladder granodiorite (Mojave Desert, California). Different processes can cause sediments to change in composition from source, including chemical weathering, hydrodynamic sorting during transport, and diagenesis. Sorting and physical processes have previously suggested. To assess the relative contributions of these processes to understand provenance reconstruction, the textures and compositions of an exposed Holocene saprolite weathering profile, grus, and granodiorite bedrock were studied. Fracture density in the weathering profile decreased from ~10% at the top to ~2% at the bottom of the profile in contact with the bedrock. …

A Connectivity Framework To Explore The Role Of Anthropogenic Activity And Climate On The Propagation Of Water And Sediment At The Catchment Scale, Christos Giannopoulos

Doctoral Dissertations

Anthropogenic disturbance in intensively managed landscapes (IMLs) has dramatically altered critical zone processes, resulting in fundamental changes in material fluxes. Mitigating the negative effects of anthropogenic disturbance and making informed decisions for optimal placement and assessment of best management practices (BMPs) requires fundamental understanding of how different practices affect the connectivity or lack thereof of governing transport processes and resulting material fluxes across different landscape compartments within the hillslope-channel continuum of IMLs. However, there are no models operating at the event timescale that can accurately predict material flux transport from the hillslope to the catchment scale capturing the spatial and …

Influence Of Physical Variability Of Highly Weathered Sedimentary Rock On Nitrate In Area 3 Of The Enigma Field Research Site At Y-12, Erin Kelly

Masters Theses

Uranium processing and waste storage in unlined waste ponds leached contaminants into the groundwater at Y-12, Oak Ridge, Tennessee, from the 1950s to 1980s. Groundwater wells near the S-3 ponds have had the highest nitrate concentrations of groundwater anywhere in the world (>10,000 mg/L). For reference, the maximum contaminant level for nitrate in drinking water set by the U.S. Environmental Protection Agency is 10 mg/L. Since 2012, the ENIGMA (Ecosystems and Networks Integrated with Genes and Molecular Assemblies) group has been characterizing, monitoring, and conducting field experiments to understand the interactions between contaminants, microbes, and the subsurface. The goals …

Vorticity And Kinematic Analysis Of The Cordillera Blanca Shear Zone, Peru, Corey Flynn

Masters Theses

Quantitative vorticity analyses applied to naturally deformed rocks are essential for studying kinematics in shear zones and can be performed using a range of methods, which have been developed over the last two decades. An understanding of vorticity, or the contribution of pure vs. simple shear, can permit for the modeling of shear zone development in a deformed region. Recent (5 Ma-present) deformation in the Cordillera Blanca Shear Zone of the Peruvian Andes has exposed sections of the middle crust at the surface, allowing for observation and analysis of shear zone processes. Oblique grain-shape (OGS) analysis and crystallographic vorticity analysis …

Planetary Processes Active And Ancient: Hollowing On Mercury, Ancient Crust Formation On Mars, And Identifying Mars-Analog Habitats., Michael Steven Phillips

Doctoral Dissertations

This dissertation comprises a thermophysical model that shows elemental sulfur may be involved in the potentially active processes that form enigmatic features called hollows on the Mercurian surface, a suite of remote sensing techniques that unveil anorthositic rocks in ancient martian crust, and deep learning to discover the spatial resolutions necessary to identify astrobiology targets in images of Mars analog landscapes.

On Mercury, hollows are high-reflectance, flat-floored depressions observed nearly globally. Hollows are thought to form via sublimation, or a “sublimation-like” process, but the identity of the sublimating phase is poorly constrained. To better understand which phase might be responsible …

Experimental Alteration Of Venusian Surface Basalts In A Hybrid Co2-So2 Atmosphere, Robert B. Reid

Masters Theses

Venus’ surface and interior dynamics remain largely unconstrained, due in great part to the major obstacles imposed by its 470°C, 90 bars surface conditions and its thick, opaque atmosphere. Orbiter-based thermal emission data provide an opportunity to characterize the Venus surface. However, interpretations of such spectra critically depend on understanding interactions between the planet’s surface basaltic rocks and its caustic, SO₂-bearing CO₂ atmosphere. Several studies, using remote sensing, thermodynamic modeling, and laboratory experiments have placed constraints on alteration mineralogies and rates. Yet constraint with respect to SO₂-mediated reactions with basalts of contrasting compositions remains incomplete. …

Cover Crop Treatment Impacts On Selected Soil Health Indicators In Two Tennessee Long-Term No-Till Corn-Soybean Rotations, Adam A. Zimmerman

Masters Theses

Soil hydraulic conductivity (K_sat) and soil microbial biomass carbon (SMB-C) estimates in Tennessee no-till corn (Zea mays L.) and soybean (Glycine max L.) rotation systems may be changed with cover crops. This study assessed differences in K_sat rates and SMB-C values under common cover crop treatments of two no-till corn and soybean rotation systems in west and middle Tennessee. Wheat (Triticum aestivum L.), cereal rye (Secale cereale L.), wheat/crimson clover (Trifolium incarnatum L.), cereal rye/crimson clover, a five species mix (containing cereal rye, crimson …

Architectural-Element Analysis And Depositional Models For Pre-Vegetation Braidplain And Braid-Delta Environments, With Modern Analogues, Jason Gerhard Muhlbauer

Doctoral Dissertations

Pre-vegetation landscapes that blanketed the continents before the emergence vascular plants in the late-Silurian are proposed habitats for the earliest terrestrial biota and are analogous to martian setting thought to have potentially hosted life. Analysis of the middle member of the Wood Canyon Formation, a Cambrian age sandstone, reveal new details about terrestrial pre-vegetation environments. In fluvial middle-member stratigraphy, units are defined by stacking patterns of three facies associations (FA1-3). In FA1, stacked cosets, interpreted as braidplain barforms and channel fills, preserve vertical- and downstream-accretion elements under unimodal paleoflow. Floodplains, represented by FA2, include red-orange intervals of fine- to medium-grained …

Local Structure And Dynamic Studies Of Mixed Ch4-Co2 Gas Hydrates Via Computational Simulation And Neutron Scattering, Bernadette Rita Cladek

Doctoral Dissertations

Permeated throughout the ocean floor and arctic permafrost, natural gas hydrates contain an estimated 3000 trillion cubic meters, over three times that of traditional shale deposits, of CH₄ that is accessible for extraction. Gas hydrates are a crystal structure in which water molecules form a cage network, the host, through hydrogen bonds while trapping a guest molecule such as CH₄ in the cavities. These compounds form naturally where the appropriate low temperature and high pressure conditions occur. A promising and tested method of methane recovery is through exchange with CO₂, which energetically takes place of the …