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Evaluation Of Chlorine Emission Potential At The New Deer Island Wastewater Treatment Plant, Somnath Basu, Kenneth Shilinsky, Irvine Wei

Irvine W. Wei

The Massachusetts Water Resources Authority (MWRA) is currently constructing a 1,200 million gallon per day secondary wastewater treatment facility on Deer Island, in Boston Harbor. Chlorine, in the form of sodium hypochlorite solution, is purchased and barged to Deer Island for use in both effluent disinfection and odor scrubbing. The Process Engineering Department of Deer Island, as part of its on-going cost effectiveness program, is currently evaluating on-site generation of sodium hypochlorite. The technical analysis includes a thorough examination of the chemistry of production and storage, including potential losses to atmosphere. This paper presents an overview of that examination, defines …

Reuse Of Municipal Wastewater As Makeup To Circulating Cooling Systems, D. Goldstein, Irvine Wei, R. Hicks

Irvine W. Wei

The reuse of municipal wastewater for industrial cooling is an excellent way of preserving clean waters for other uses. Details have been collected from several countries and there is no doubt that this is a thoroughly practical reuse option.

Makeup waters successfully used fall in the range 10-30 mg/l BOD, 30-50 mg/l o-PO₄, 1000-1500 mg/l TDS and 30-70 mg/l NH₃. The major problems are phosphate scale and biological fouling. Usual treatments are lime clarification and chlorination.

Most of the industrial users are power plants, which use high alloy metals to avoid corrosion, but industries using carbon-steel heat exchangers have not …

Analysis Of The Fate Of Chlorine Species As Part Of On-Site Generation Evaluation Of Sodium Hypochlorite At Deer Island, Somnath Basu, Kenneth Shilinsky, Irvine Wei

Irvine W. Wei

No abstract provided.

Mechanism And Kinetics Of Oxidation Of 2,4,6-Trichlorophenol By Fenton's Reagent, Somnath Basu, Irvine Wei

Irvine W. Wei

Fenton's reagent is an effective oxidant for pretreatment and toxicity reduction in wastewater contaminated with 2,4,6-trichlorophenol (TCP). The reaction, and its dependence on various parameters (e.g., molar ratios of the reacting chemicals, pH, temperature, etc.) have been reported elsewhere. In this paper a mechanistic interpretation of the reaction pathway, with identity of the intermediate reaction products, has been presented. An empirical expression for the rate of reaction has also been proposed in terms of the disappearance of TCP in water, as a function of the concentrations of the TCP itself and of the oxidant, hydrogen peroxide.

Oxidation Of 2,4-Dinitrotoluene Using Fenton's Reagent: Reaction Mechanisms And Their Practical Applications, Nihar Moriarty, Irvine Wei

Irvine W. Wei

With the strict regulations of present times, chemical oxidation holds tremendous potential for destructive treatment of hazardous wastes which are resistant to biological oxidation. Fenton's reagent has proved to be an inexpensive and powerful oxidant which has been shown to oxidize a wide variety of organics. In this paper, 2,4 dinitrotoluene (2,4 DNT) was chosen as a model compound following previous work where 2,4 DNT was subjected to oxidation by hydrogen peroxide in the presence of medium power UV source. Various factors that are important to optimize the oxidation of organics were studied. The effect of aeration, step dosing and …