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Soil Organic Carbon In Maine, Its Responses To Biochar Addition, And Climate Change, Xue Bai

Electronic Theses and Dissertations

Soil organic carbon (SOC), as one of the largest C pools in terrestrial ecosystems, plays a key role in governing soil ecosystem processes and climate regulation. Climate change concerns have resulted in a rapidly growing interest in understanding the potential for natural climate solutions (NCS) that include enhancing SOC sequestration and reduce net atmospheric greenhouse gas (GHG) emissions. This research focused on addressing information needs about SOC in Maine, specifically in evaluating available soil databases to accurately quantify SOC density and concentration, and study the response of selected representative Maine soils to biochar amendments under a changing climate.

Maine SOC …

Evaluating The Effects Of Pine And Miscanthus Biochar On Water Activity And Escherichia Coli Populations In Commercial Broiler Litter, Christopher Austin Marty

Theses and Dissertations

The decrease in subtherapeutic antibiotic administration in poultry has increased the need to address production challenges caused by pathogens, such as E. coli. One potential way to improve bird health and reduce bacterial infection is through the addition of litter amendments that absorb moisture. Biochar (BC) has previously been shown to increase water holding capacity in poultry litter, but its effects on E. coli mitigation are unknown. The objectives of this research were to 1) evaluate water activity of poultry litter amended with pine and miscanthus BC, and 2) determine the effects of different BC inclusion rates on litter …

Impact Of Wood-Sourced Biochar On Carbon And Nitrogen Capture In Beef Feedlot Systems, Jessica L. Sperber

Department of Animal Science: Dissertations, Theses, and Student Research

A feedlot growing and finishing experiment evaluated the effect of including pine-sourced biochar at 0.8 (growing) and 1.0% (finishing) of dietary DM on steer performance, carcass characteristics, and greenhouse gas (GHG) production (Exp 1). Two nutrient mass balance experiments were conducted during winter and summer seasons to evaluate the effect of spreading unprocessed red cedar biochar on the feedlot pen surface on manure nutrient capture and cattle performance (Exp 2). In Exp. 1, the inclusion of biochar in the growing diet did not impact steer performance. The inclusion of biochar in the finishing diet significantly reduced intake and gain, resulting …

Application Of Biochar As Beneficial Additive In Concrete, Temirlan Barissov

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Biochar is a high-carbon solid material produced via thermal decomposition of organic biomass in a low-oxygen environment. Characterized with high water retention properties and high alkalinity, biochar is generally used for soil amendment and fertilization purposes. This study is intended to explore the feasibility of using biochar as a beneficial additive of the most used manmade material, concrete. Literature review revealed several studies where biochar was successfully implemented as an additive in concrete. The beneficial influence of biochar on the mechanical characteristics of concrete is based on nucleation and densification effects. However, the internal microstructure, porosity and chemical composition of …

Date Palm Waste Pyrolysis Into Biochar For Carbon Dioxide Adsorption, Imen Ben Salem, Mariam Badawi Saleh, Jibran Iqbal, Maisa El Gamal, Suhaib Hameed

All Works

Mitigation of CO2 is a very popular research currently, it is ultimately beneficial to find new ways that are sustainable, low cost and gas emission friendly. Therefore, with biochar’s characteristics and properties it has great potential to be used as a CO2 capture and storage media. The objectives of reducing palm waste by using the low-cost, sustainable method for reducing and storing CO2, characterize the DPL biochar through FTIR, XRD, SEM, EDX, and then evaluate the efficiency of the date palm leaf waste biochar in adsorbing CO2 through the Gas–Solid analyzer technology. Date palm leaf was set in pyrolysis process …

Incorporation Of Biochar To Improve Mechanical, Thermal And Electrical Properties Of Polymer Composites, Chinmoyee Das, Sandeep Tamrakar, Alper Kiziltas, Xinfeng Xie

Michigan Tech Publications

The strive for utilization of green fillers in polymer composite has increased focus on application of natural biomass-based fillers. Biochar has garnered a lot of attention as a filler material and has the potential to replace conventionally used inorganic mineral fillers. Biochar is a carbon rich product obtained from thermochemical conversion of biomass in nitrogen environment. In this review, current studies dealing with incorporation of biochar in polymer matrices as a reinforcement and conductive filler were addressed. Each study mentioned here is nuanced, while addressing the same goal of utilization of biochar as a filler. In this review paper, an …

Commercial Douglas Fir Biochar Based Multifunctional Exotic Adsorbents For Water Remediation, Chanaka Navarathna

Theses and Dissertations

Providing safe drinking water and wastewater remediation are constant worldwide challenges. Adsorption is an attractive alternative to conventional techniques such as coagulation, precipitation (chemically or electrochemically), hybrid membranes, and ion-exchange for the purification of water. Biochar-based composite sorbents are increasingly popular because a range of surface chemical and physical treatments can impart performance and environmental benefits to the material. This is ideal for rural areas where more costly conventional methods may not be readily available or affordable. This dissertation focused on three different projects involving high surface area (~700 m2/g) Douglas fir biochar based multifunctional engineered adsorbents. Chapter II focuses …

Biochar Applications To The Remediation Of Lead And Polychlorinated Biphenyl Contaminated Water, Victory Itua Igberase

Theses and Dissertations

This study investigated the performance of biochar materials as adsorbents to remove Pb and polychlorinated biphenyl (PCB) in aqueous solutions. Batch adsorption and column experiment packed with biochar and geomaterials (pumice) in 1:1 volume ratio was evaluated to address the efficacy of biochar in removing Pb while only batch adsorption was employed for PCB removal with biochar materials. Overall, PT biochars performed the best (42–53 mg g−1) followed by BE biochars (10–32 mg g−1) and AB biochars (17–27 mg g−1) while high temperature biochars were favored in terms of maximum Pb adsorption capacity. Column Pb breakthrough showed similar results, with …

Biodegradation And Microbial Co2 Evolution Of Blended Polymers In Food-Waste And Coffee Supplemented Disposal Environments, Abigail Rolston

Theses

The dependency of many industries on single-use materials, has led to an accumulation of plastic waste and subsequent harm to the planet. Since avoidance of plastic is often not viable and the current processes of recycling have their own environmental impact, many have looked toward development of sustainable replacements for plastics. Homogenous blended polymers made from varied ratios of polycaprolactone (PCL), starch, and biochar were made in the Rochester Institute of Technology (RIT) Packaging Science Department, tested for percent weight loss and for carbon dioxide (CO2) evolution in soils. Testing was done across three burial matrices: soil amended with compost …

What Is Biochar And How Is It Used?, Marion Murray

All Current Publications

Biochar is a charcoal-like product that contains no petroleum. It is made by heating biomass such as herbaceous or woody crop residues, non-salvageable timber, and slash, or animal manure, in a contained system. There are many potential uses for biochar including water treatment, land reclamation, and carbon sequestration. Biochar may also be used as a soil amendment for two purposes – to improve plant health and to store carbon.

Improvement Of Biochar Through Ozonization And Biosafety Of Genetically Engineered Cyanobacteria, Oumar Sacko

Chemistry & Biochemistry Theses & Dissertations

Through the innovative technique of biochar post-production surface oxygenation by ozonization, we were able to improve certain properties of biochar. In project one, the incubation of an insoluble phosphate rock material (hydroxyapatite) with the wet ozonized pine 400 biochar and its filtrate resulted in a solubilization of 80 times more phosphate from hydroxyapatite (569.0 mg/L ± 6.4) compared to the pure water-hydroxyapatite control (7.2 mg/L ± 0.3). The ozonized biochar may provide a new possible way to unlock the phosphorus from insoluble phosphate mineral phases. The cation exchange capacity (CEC) is a key property of biochar when used as a …

Enriched Rice Husk Biochar Minimizes Ammonia Loss From Applied Urea Fertilizer Under Waterlogged Environment [Research Note], Gunavathy Selvarajh, Huck Ywich Ch'ng, Norhafizah Md Zain, Issariyaporn Damrongrak

The Philippine Agricultural Scientist

A laboratory-scale closed dynamic air flow system was carried out to assess the effect of enriched rice husk biochar on ammonia volatilization, soil exchangeable ammonium, and available nitrate from the applied urea in comparison to urea alone under waterlogged conditions. Treatments with enriched rice husk biochar (5, 10, 15, and 20 t ha^-1) significantly minimized ammonia volatilization, however, only biochar with rates of 5, 10, and 15 t ha^-1 had significantly retained more soil exchangeable ammonium by 14% – 43%. Additionally, soil available nitrate was lower in all treatments except in T1 (urea alone). This indicates that …

Soil Health Beneath Amended Switchgrass: Effects Of Biochar And Nitrogen On Active Carbon And Wet Aggregate Stability, Priya Saini, Jason P. De Koff, Richard Link, Chris Robbins

Agricultural and Environmental Sciences Faculty Research

Perennial crops, like switchgrass (Panicum virgatum L.), are important for bioenergy production and long-term carbon sequestration. Biochar, a byproduct of certain bioenergy production processes, is also identified as a potential tool for carbon sequestration and soil quality improvements, especially in marginal soils. Despite the focus on switchgrass, soil health characteristics under switchgrass production for biomass are unclear. This study focused on identifying the effects of four N rates (0, 17, 34, and 67 kg N ha−1) and biochar application (0 and 9 Mg ha−1) in a 3-year switchgrass field study on a silt loam soil. Soil active carbon (AC) and …

Development Of A Numerical Process Model For Adsorbent-Amended Constructed Wetlands, Lillian Mulligan

USF Tampa Graduate Theses and Dissertations

There is a need for alternative methods for municipal landfill leachate treatment as the high concentrations of pollutants in leachate interfere with processes at publicly owned treatment works (POTWs). Constructed wetlands (CWs) have been shown to be a sustainable alternative with good removal efficiencies for chemical oxygen demand (COD) and ammonia nitrogen (NH4+). The addition of an adsorbent media, such as zeolite and biochar, to CWs to further enhance removal efficiencies has been investigated in recent years. However, the long-term effects of zeolite and biochar addition to CWs is not well known. A model could be a useful tool to …

Innovative Water Management Using Advanced Irrigation Systems And Biochar, Jonathan A. Holt

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Two approaches to water optimization in agriculture are to increase soil water retention and improve the efficiency of irrigation. A soil amendment that has received attention for its ability to increase soil water retention is biochar, the remaining biomass after high C materials have been pyrolyzed (burned with limited oxygen and heat). Two studies were conducted at a total of 10 site-years in Utah from 2018 to 2020 to evaluate how wood biochar influences the productivity and crop quality of irrigated alfalfa (Medicago Sativa L.), corn (Zea mays L.), and wheat (Triticum L.), along with soil water tension. One study …

Characterization Of Biochar Produced By Pyrolysis Of Biomass And Co-Pyrolysis Of Biomass And Agricultural Mulch Film, Ibrahim Cisse

Theses

Agricultural wastes can be valuable materials because they are generated in large quantities all over the world and contain a variety of feedstocks. These feedstocks include dairy manure, food wastes, solid wastes and plastics. Current waste management techniques include landfilling and incineration, both leading to an increase in greenhouse gas emissions. However, alternative methods such as pyrolysis can present more sustainable pathways by transforming mixed wastes from the agricultural sector into value-added products such as biochar, bio-oil and syngas. Limited published literature has focused on producing biochar derived from co-pyrolysis of agricultural wastes with plastic wastes such as agricultural mulch …

Low-Cost Adsorbents For Water Purification, Hasara Dilum Samaraweera

Theses and Dissertations

Heavy metals, oxyanions (NO3-, PO4-), pharmaceuticals, and dyes in aquatic environments are inevitable economic and health concerns. Ingestion of these contaminants, even in trace amounts, causes long and short-term serious threats to human health. Conventional pollutant mitigation strategies can be costly or ineffective. Due to high efficiency, simplicity, low price, adsorbent reuse, and pollutant (e.g., phosphates) recovery, adsorption has been widely used for wastewater purification. Many efficient, environmentally compatible, and cost-effective sorbents have been successfully applied in environmental remediation. Chapter I is about characterization of graphene-coated pinewood biochar hybrids and evaluation of their copper removal performances. Here, we synthesized three …

Modified Biochar Adsorbents For Aqueous Contaminant Remediation, Herath Mudiyanselage Nimeshika Amali Herath

Theses and Dissertations

Continuous population growth and rapid industrial advancement and development have paved the way for ever increasing environmental pollution. At present, water pollution is a serious global issue that threatens environmental sustainability. The contamination of aquatic bodies with potentially toxic organic and inorganic substances are the result of world-wide anthropogenic activities. These pollutants can have detrimental health consequences on humans and ecosystems. Over the past decades, techniques such as chemical precipitation, ion-exchange, adsorption, membrane filtration, and electrocoagulation-flocculation have been developed and employed for the treatment of drinking and wastewater. Among the currently available techniques, pollutant removal by adsorption is most promising …

Impact Of Post-Pyrolysis Wash On Biochar Powders And Their Respective Granule Formations, Anthony Fazzalari

Electronic Thesis and Dissertation Repository

Biochar can be an effective soil amendment, but concerns are soil contamination and dust emissions. This thesis developed various post-pyrolysis washing solutions to alleviate these concerns. Washing can reduce biochar hydrophobicity, improve its stability and adsorption properties and remove organic, inorganic, and PAH contaminants. The most effective wash was used to facilitate biochar granulation. Biochars from two different feedstocks were tested in a drum granulator with molasses binder. Washing biochar significantly increased the yield of optimally sized granules. Granules from washed biochar were dense, robust and free-flowing. The research showed how washing improved various biochar powders in terms of their …

Production Of Engineered Carbons From Secondary Waste Streams For Environmental Applications, Ghazaleh Chegini

Electronic Thesis and Dissertation Repository

Pyrolysis and activation were used in this thesis to produce biochar and activated carbon from industrial digestate and hydrochar materials. In the first part of thesis, digestate derived biochars were obtained by varying the pyrolysis heating rate (10, 80, 100, 200, >1000 °C·min^-1) and temperature (300 to 600 °C) to modify their soil-related characteristics (i.e., nutrient leachability, carbon stability, and heavy metal adsorptive capacity). The biochar produced at a temperature of 500 °C and heating rate of 10 °C·min^-1 was also activated under using CO₂ at 800 °C with different holding times (0.5-2 h). Results indicated …

Efecto De La Adición De Biochar Como Enmienda De Un Suelo Degradado, Sobre Microorganismos Relacionados Con El Ciclo Del Carbono, Johan Alejandro Burbano Chinchajoy

Biología

Actualmente, la fuerte demanda agrícola y las malas prácticas han alterado el equilibrio natural del suelo, así como las interacciones físicas, químicas y biológicas, ocasionando su degradación del suelo; por tanto, los índices de calidad del suelo son considerados como herramientas para evaluar el estado de este sustrato en condiciones naturales o el utilizado para la producción agrícola.

Una de las prácticas utilizadas para mitigar su degradación es el uso de enmiendas orgánicas, como el biochar, a nivel mundial se ha evaluado su adición como medio para mejorar la fertilidad del suelo y mitigar el cambio climático, además, sus efectos …

Grey Water Footprint Assessment Of Geothermal Water Resources In The Southeasternanatolia Region, Peli̇n Yapicioğlu, Mehmet İrfan Yeşi̇lnacar

Turkish Journal of Earth Sciences

This paper aimed to determine the grey water footprint (GWF) of geothermal water resources and to investigate the effect of biochar adsorption on grey water footprint in Southeastern Turkey. In this paper, GWF has been calculated in terms of iron (Fe), arsenic (As), manganese (Mn), boron (B), and chrome (Cr) concentrations for fifteen observation geothermal resources located in Southeastern Anatolia Region. In this study, a new approach based on the GWF was developed in order to determine the geothermal water pollution. Grey water footprints related to fifteen geothermal resources were investigated. In the second stage of the study, the effect …

Biolability Of Fresh And Photodegraded Pyrogenic Dissolved Organic Matter From Laboratory-Prepared Chars, K. W. Bostick, A. R. Zimmerman, A. I. Goranov, S. Mitra, P. G. Hatcher, A. S. Wozniak

Chemistry & Biochemistry Faculty Publications

Pyrogenic dissolved organic matter (pyDOM) is known to be an important biogeochemical constituent of aquatic ecosystems and the carbon cycle. While recent studies have examined how pyDOM production, composition, and photolability varies with parent pyrogenic solid material type, we lack an understanding of potential microbial mineralization and transformation of pyDOM in the biogeosphere. Thus, leachates of oak, charred at 400 °C and 650 °C, as well as their photodegraded counterparts were incubated with a soil‐extracted microbial consortium over 96 days. During the incubation, significantly more carbon was biomineralized from the lower versus higher temperature char leachate (45% vs. 37% lost, …

Nano-Black Carbon (Biochar) Released From Pyrogenic Carbonaceous Matter As A Super Suspending Agent In Water/Soil Environments, Fei Lan, Zhenyu Wang, Baoshan Xing

Stockbridge Faculty Publication Series

Nano-black carbon (BC) is one of the most active fractions in the pyrogenic carbonaceous matter continuum. The majority of recent studies mainly focus on the role of nano-BC in the global carbon cycle. However, based on literature and our recent studies, we suggest that nano-BC may also serve as a super suspending agent, carrier, and redox mediator for sorbates during its migration from terrestrial to water bodies due to its unique properties such as high colloidal stability, strong sorption capacity, and high surface reactivity. The full implications of nano-BC in water/soil environments are far more than we expected. Thus, we …

Does Biochar Improve All Soil Ecosystem Services?, Humberto Blanco-Canqui

Department of Agronomy and Horticulture: Faculty Publications

Biochar is considered to sequester C and deliver other soil ecosystem services, but an overview that synthesizes the current knowledge of biochar implications on all essential soil ecosystem services is difficult to find in the ample biochar literature. Most previous research and review articles on this topic focused on a single ecosystem service and did not integrate all essential soil ecosystem services. This overview paper (1) synthesizes the impacts of biochar on water and wind erosion, C sequestration, soil water, nutrient leaching, soil fertility, crop yields, and other soil ecosystem services based on published literature and (2) highlights remaining research …