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Use Of Food Waste Activated Carbons For Wastewater Treatment, Abigale Monasterial Dec 2020

Use Of Food Waste Activated Carbons For Wastewater Treatment, Abigale Monasterial

Honors Scholar Theses

Activated carbons are often used to remove phenol from wastewater. However, they are usually derived from expendable resources, such as coal and have high regeneration costs. In this work, the adsorption of phenol on activated carbon derived from food waste was studied to understand its kinetics, determine its maximum adsorption capacity, and compare it to commercial activated carbons. Adsorption experiments were performed at 298 K for 48 hours at various pHs and initial phenol concentrations. The adsorption data was then fit to the pseudo-first order, pseudo-second order, and intraparticle diffusion models to understand the kinetics and to the Langmuir and …


Production And Characterization Of Twelve Different Biochars And Evaluating Their Effects On Soil Health And Plant Growth, Shagufta Gaffar Nov 2020

Production And Characterization Of Twelve Different Biochars And Evaluating Their Effects On Soil Health And Plant Growth, Shagufta Gaffar

FIU Electronic Theses and Dissertations

Biochar has been a topic of growing interest in the scientific community. It is a product derived from carbon rich organic materials through the process of pyrolysis. It has received wide attention as a means to improve soil fertility and crop productivity, absorb pollutants in soil, and sequester carbon to mitigate climate change. Recent research on biochar explores its impacts on the environment with particular focus on use as a soil amendment in agriculture. Biochar produced from different biomass and under different production process effects the environmental and agronomic impacts of its application in different ways. This means biochar can …


Removal Of Molybdenum From Contaminated Water Using Douglas Fir Biochar/Iron Oxide Composites, Naba Krishna Das Aug 2020

Removal Of Molybdenum From Contaminated Water Using Douglas Fir Biochar/Iron Oxide Composites, Naba Krishna Das

Theses and Dissertations

Molybdenum (Mo) is a naturally occurring trace element that is present in drinking water mostly in the molybdate (MoO42-) form in well water. Recently, the EPA deemed Mo as a potential contaminant because exposure can lead to health effects such as gout, hyperuricemia, and lung cancer. In this work, we have assessed the sorptive removal of Mo using Douglas fir biochar (DFBC) and its chemically-coprecipitated iron oxide analogue (DFMBC). Adsorption was studied varying the batch sorption conditions; pH, equilibrium time (5 min-24 h), initial Mo concentrations (2.5-1000 mg/L), temperatures (5, 25, and 40 °C) and equilibrium method. Langmuir capacities for …


Sorption-Mediated Chemical Processes For The Versatile Treatment Of Per- And Polyfluoroalkyl Substances (Pfas) In Complex Media, Naomi Gevaerd De Souza Aug 2020

Sorption-Mediated Chemical Processes For The Versatile Treatment Of Per- And Polyfluoroalkyl Substances (Pfas) In Complex Media, Naomi Gevaerd De Souza

Civil Engineering Dissertations

In recent years, per- and polyfluoroalkyl substances (PFAS) have gained notoriety due to environmental and health concerns. These molecules are chemically stable which contributes to their persistence in biological systems and their increased detections in surface waters. Treatment of highly persistent PFAS has been a challenging but significant task. The most practical technique for removal of PFAS is through adsorption onto granular activated carbon (GAC) or other novel materials. Meanwhile, PFAS are resistant to simple oxidation, and although decomposition of specific PFAS has been reported through advanced oxidation technologies, often energy-intense technologies capable of generating electrons such as ultraviolet radiation, …


Insights Into The Adsorption Of Pb(Ii) Over Trimercapto-S-Triazine Trisodium Salt-Modified Lignin In A Wide Ph Range, Qiaorui Wang, Chunli Zheng, Fei He, Yuan Yao, Tian C. Zhang, Chi He Jun 2020

Insights Into The Adsorption Of Pb(Ii) Over Trimercapto-S-Triazine Trisodium Salt-Modified Lignin In A Wide Ph Range, Qiaorui Wang, Chunli Zheng, Fei He, Yuan Yao, Tian C. Zhang, Chi He

Department of Civil and Environmental Engineering: Faculty Publications

A novel fabrication method for modifying alkaline lignin (AL) was reported, in which trimercapto-s-triazine trisodium salt was used as a modifier to tune surface properties of AL. Molecular structure of modified AL (FAL) was determined by 3D-EEM, synchronous fluorescence, FTIR, 13C MAS NMR and XPS. Two-dimensional correlation spectroscopy and electron localization function demonstrated that both of electrostatic and coordinate bonds formed between these functional groups and Pb(II) at higher pH of 3.0 to 6.0 while only coordinate bond at lower pH of 0.2 to 1.2. The higher the solution pH was, the stronger the adsorption capacity of FAL had. The …


Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Jacqueline Payne, Mary Johnson, Kevin Le, Michelle Dopp, Courtney Golman, Adrian Damian, Ethan Phan May 2020

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Jacqueline Payne, Mary Johnson, Kevin Le, Michelle Dopp, Courtney Golman, Adrian Damian, Ethan Phan

Chemical Engineering Undergraduate Honors Theses

The process of mining minerals and elements from ores and rocks creates acid rock drainage (ARD). This drainage is water that contains heavy metals and minerals that can be dangerous for human consumption or damaging to the environment. The mining industry has employed various water treatment methods to prevent these metals and minerals from being discharged into water sources such as ponds, lakes, and streams. Currently, the most used treatment process in the mining industry is a cost-effective highdensity sludge (HDS) process. This method reduces the concentration of metals and elements with the use of lime/limestone. However, the concentration of …


Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Courtney Golman, Kevin Le, Michelle Dopp, Adrian Damian, Mary Johnson, Jacqueline Payne, Ethan Phan May 2020

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Courtney Golman, Kevin Le, Michelle Dopp, Adrian Damian, Mary Johnson, Jacqueline Payne, Ethan Phan

Chemical Engineering Undergraduate Honors Theses

The process of mining minerals and elements from ores and rocks creates acid rock drainage (ARD). This drainage is water that contains heavy metals and minerals that can be dangerous for human consumption or damaging to the environment. The mining industry has employed various water treatment methods to prevent these metals and minerals from being discharged into water sources such as ponds, lakes, and streams. Currently, the most used treatment process in the mining industry is a cost-effective highdensity sludge (HDS) process. This method reduces the concentration of metals and elements with the use of lime/limestone. However, the concentration of …


Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Michelle Dopp, Kevin Le, Ethan Phan, Mary Johnson, Jacqueline Payne, Adrian Damian, Courtney Golman May 2020

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Michelle Dopp, Kevin Le, Ethan Phan, Mary Johnson, Jacqueline Payne, Adrian Damian, Courtney Golman

Chemical Engineering Undergraduate Honors Theses

The Moo Pig Sooie’s researched, designed, and economically analyzed a full-scale adsorption column system to be applied in mining processes that leave high amounts of fluoride in their effluent. This system was designed to remove fluoride from water saturated with calcium sulfate, as calcium sulfate is present in high amounts in certain mining processes. Currently, high density sludge (HDS) is commonly employed to reduce fluoride concentrations, but due to solubility limits the sludge treatment cannot lower fluoride below 10 mg/L (ppm). The current enforceable EPA standard for discharged water is at 4 mg/L (ppm), although mining companies anticipate that this …


Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Kevin Le, Adrian Damian, Mary Johnson, Ethan Phan, Courtney Golman, Michelle Dopp, Jacqueline Payne May 2020

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Kevin Le, Adrian Damian, Mary Johnson, Ethan Phan, Courtney Golman, Michelle Dopp, Jacqueline Payne

Chemical Engineering Undergraduate Honors Theses

The team researched, designed, and economically analyzed a full-scale adsorption column system to be applied in mining processes that leave high amounts of fluoride in their effluent. This system was designed to remove fluoride from water saturated with calcium sulfate, as calcium sulfate is present in high amounts in certain mining processes. Currently, high density sludge (HDS) is commonly employed to reduce fluoride concentrations, but due to solubility limits the sludge treatment cannot lower fluoride below 10 mg/L (ppm). The current enforceable EPA standard for discharged water is at 4 mg/L (ppm), although mining companies anticipate that this standard will …


Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Ethan Phan, Adrian Damian, Kevin Le, Mary Johnson, Courtney Golman, Michelle Dopp, Jacqueline Payne May 2020

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Ethan Phan, Adrian Damian, Kevin Le, Mary Johnson, Courtney Golman, Michelle Dopp, Jacqueline Payne

Chemical Engineering Undergraduate Honors Theses

The process of mining minerals and elements from ores and rocks creates acid rock drainage (ARD). This drainage is water that contains heavy metals and minerals that can be dangerous for human consumption or damaging to the environment. The mining industry has employed various water treatment methods to prevent these metals and minerals from being discharged into water sources such as ponds, lakes, and streams. Currently, the most used treatment process in the mining industry is a cost-effective high-density sludge (HDS) process. This method reduces the concentration of metals and elements with the use of lime/limestone. However, the concentration of …


Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Adrian Damian, Kevin Le, Mary Johnson, Ethan Phan, Courtney Golman, Michelle Dopp, Jacqueline Payne May 2020

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Adrian Damian, Kevin Le, Mary Johnson, Ethan Phan, Courtney Golman, Michelle Dopp, Jacqueline Payne

Chemical Engineering Undergraduate Honors Theses

The process of mining minerals and elements from ores and rocks creates acid rock drainage (ARD). This drainage is water that contains heavy metals and minerals that can be dangerous for human consumption or damaging to the environment. The mining industry has employed various water treatment methods to prevent these metals and minerals from being discharged into water sources such as ponds, lakes, and streams. Currently, the most used treatment process in the mining industry is a cost-effective highdensity sludge (HDS) process. This method reduces the concentration of metals and elements with the use of lime/limestone. However, the concentration of …


Modified Biochar From Moringa Seed Powder For The Removal Of Diclofenac From Aqueous Solution, Afrouz Bagheri, Emmanuel Abu-Danso, Jibran Iqbal, Amit Bhatnagar Mar 2020

Modified Biochar From Moringa Seed Powder For The Removal Of Diclofenac From Aqueous Solution, Afrouz Bagheri, Emmanuel Abu-Danso, Jibran Iqbal, Amit Bhatnagar

All Works

© 2019, The Author(s). In this study, Moringa seed powder (MSP) was pyrolyzed at 450 °C to synthesize Moringa seed powder biochar (MSPB) and treated with phosphoric acid (H3PO4) to synthesize phosphate-modified Moringa seed powder biochar (MSPB-HPO) as an adsorbent for the removal of diclofenac (Dfc) from aqueous solution. Fourier transform infrared (FTIR) analysis, energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), and pH point of zero charge (pHpzc) were conducted to give more insight into the adsorbent’s properties. The SEM analysis showed the transformations in the surface morphology from the parent material to the synthesized materials after the …


Application Of Biochar Derived From Pyrolysis Of Waste Fiberboard On Tetracycline Adsorption In Aqueous Solution, Deliang Xu, Yaxuan Gao, Zixiang Lin, Wenran Gao, Hong Zhang, Karnowo Karnowo, Xun Hu, Hongqi Sun, Syed S. A. Syed-Hassan, Shu Zhang Jan 2020

Application Of Biochar Derived From Pyrolysis Of Waste Fiberboard On Tetracycline Adsorption In Aqueous Solution, Deliang Xu, Yaxuan Gao, Zixiang Lin, Wenran Gao, Hong Zhang, Karnowo Karnowo, Xun Hu, Hongqi Sun, Syed S. A. Syed-Hassan, Shu Zhang

Research outputs 2014 to 2021

In this study, biochars derived from waste fiberboard biomass were applied in tetracycline (TC) removal in aqueous solution. Biochar samples were prepared by slow pyrolysis at 300, 500, and 800°C, and were characterized by ultimate analysis, Fourier transform infrared (FTIR), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Brunauer–Emmett–Teller (BET), etc. The effects of ionic strength (0–1.0 mol/L of NaCl), initial TC concentration (2.5–60 ppm), biochar dosage (1.5–2.5 g/L), and initial pH (2–10) were systemically determined. The results present that biochar prepared at 800°C (BC800) generally possesses the highest aromatization degree and surface area with abundant pyridinic N (N-6) and …


Treatment Of Combined Acid Black 48 And Coffee Wastewater By Low-Cost Adsorbents, Yung-Tse Hung Jan 2020

Treatment Of Combined Acid Black 48 And Coffee Wastewater By Low-Cost Adsorbents, Yung-Tse Hung

Civil and Environmental Engineering Faculty Publications

© 2020, Kaunas University of Technology. All rights reserved. Removal of synthetic dyes from wastewater is essential both from the environmental and human health point of view. A small concentration of synthetic dyes can reduce water transparency and consequently influence photosynthesis and alter aquatic ecosystems. Acid black 48 is an Azo dye that falls under the category of synthetic dyes used in the textile industry. With dyes, coffee wastewater has high chemical oxygen demand (COD) that can affect dissolved oxygen (DO) in surface waters. A mixture of wastes in surface waters creates a need to investigate the efficiency of existing …