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Synthesis And Characterization Of Carbon-Based Nanomaterials From Lignin, Xuefeng Zhang Dec 2016

Synthesis And Characterization Of Carbon-Based Nanomaterials From Lignin, Xuefeng Zhang

Theses and Dissertations

The main objective of this research was to develop a catalytic thermal conversion process for production of carbon-based nanomaterials (CNs) from kraft lignin. Four specific objectives were to: (1) understand the structural evolution of kraft lignin during its thermal treatment process; (2) investigate effects of temperature, and iron catalyst loading and morphology on the catalytic thermal conversion of kraft lignin to CNs, understand lignin catalytic thermal conversion mechanism; (3) explore potential applications of CNs synthesized from kraft lignin as an adsorbent for lead removing from contaminated water; (4) and propose effective methods for graphene material characterization. Experimental results indicated that …


Specific Phosphate Sorption Mechanisms Of Unaltered And Altered Biochar, Kathryn D. Szerlag Nov 2016

Specific Phosphate Sorption Mechanisms Of Unaltered And Altered Biochar, Kathryn D. Szerlag

Masters Theses

Biochar has been shown to act as an effective sorbent for many organic and inorganic contaminants (including phosphate) and can help to improve the quality of our fresh water resources by preventing eutrophication. Most of the high efficiency biochar phosphate-adsorbent feedstocks are modified with chemical pretreatment, phytoremediation or anaerobic digestion to accumulate desired elements. The main objectives of this project were to first engineer magnesium (Mg) and calcium (Ca) altered biochar by chemical pretreatment followed by pyrolysis at either 350 or 550°C and evaluate their phosphate adsorption rate and potential as compared to their unaltered counterparts. Determination of surface physiochemical …


Removal Of Target Ppcps From Secondary Effluent Using Aops And Novel Adsorbents, Venkateswara Reddy Kandlakuti Aug 2016

Removal Of Target Ppcps From Secondary Effluent Using Aops And Novel Adsorbents, Venkateswara Reddy Kandlakuti

Electronic Thesis and Dissertation Repository

Atenolol (β-blocker), Clofibric Acid (Lipid regulators) and Diclofenac (Anti-inflammatory) are the drugs widely used and reported to have adverse effects on fish and other organisms. These drugs are found at trace levels in lakes, rivers and sewage treatment plants and conventional treatment plants are ineffective to eliminate these at those levels. A high resolution LC-MS/MS was used to quantify these drugs at low levels. Various advanced oxidation methods were used for the present research to eliminate these drugs from secondary effluent. Complete removal of PPCPs was achieved by synthesizing immobilized TiO2 on a stainless steel mesh and using a combination …