Digital Commons Network^™

Microbe-Mineral Relationships And Biogenic Mineral Transformations In Actively Venting Deep-Sea Hydrothermal Sulfide Chimneys, Tzihsuan J. Lin

Doctoral Dissertations

This dissertation uses a combination of microbiology, mineralogy, and geochemistry to understand dissimilatory iron reduction in hyperthermophilic archaea and the role and potential impact of these and other vent microorganisms within active deep-sea hydrothermal vent chimneys. The central objective of the dissertation is to determine if mineral composition and chimney type are among the primary determinants of microbial community composition and hyperthermophilic, dissimilatory iron reducer growth, in addition to other environmental factors such as nutrient availability, temperature, pH, and chlorinity. This is done using samples and organisms collected from the Endeavour Segment of the Juan de Fuca Ridge in the …

Karst Estuaries: A Newly Described Ecosystem Governed By Aquifer Hydrology, Damian M. Menning

USF Tampa Graduate Theses and Dissertations

The overall goal of this dissertation is to define the hydrological, geochemical, and biological characteristics of a Karst Estuary. These types of estuaries represent a unique ecosystem created by freshwater inputs from direct flow through karst conduits and/or diffuse flow through a karst matrix. In order to determine the characteristics of a Karst Estuary we monitored short-term tidal fluctuations, long-term rainfall patterns, aquifer levels, spring discharge, multiple geochemical parameters, microbial communities in the water column and sediment, and macrofaunal communities in the sediment along a transect from a submarine spring through the Gulf of Mexico. Four sites were selected along …

Iron Oxide-Organic Matter Coprecipitates And Controls On Copper Availability, Neila N. Seda

Master's Theses

Copper availability in wetland systems is controlled by strong interactions with organic matter (OM) and highly sorptive mineral precipitates, such as iron oxides. The purpose of this study is to examine copper sorption and availability by using bench scale experiments to mimic more complex geochemical systems involving iron oxide and OM. Copper, iron oxide and OM coprecipitates were prepared by varying the molar ratio of Fe:OM from 1:0 to 1:10 with a fixed Cu concentration of 1 mg/L Cu, background of 10 mM NaNO₃, and a pH range of 4 to 7. Precipitate mass and Cu sorption per …

Composition, Alteration, And Texture Of Fault-Related Rocks From Safod Core And Surface Outcrop Analogs: Evidence For Deformation Processes And Fluid-Rock Interactions, Kelly Keighley Bradbury, Colter R. Davis, John W. Shervais, Susanne U. Janecke, James P. Evans

Geosciences Faculty Publications

We examine the fine-scale variations in mineralogical composition, geochemical alteration, and texture of the fault-related rocks from the Phase 3 whole-rock core sampled between 3,187.4 and 3,301.4 m measured depth within the San Andreas Fault Observatory at Depth (SAFOD) borehole near Parkfield, California. This work provides insight into the physical and chemical properties, structural architecture, and fluid-rock interactions associated with the actively deforming traces of the San Andreas Fault zone at depth. Exhumed outcrops within the SAF system comprised of serpentinite-bearing protolith are examined for comparison at San Simeon, Goat Rock State Park, and Nelson Creek, California. In the Phase …

Geochemical Analysis Of Eolian Fluxes During The Transition From Greenhouse To Icehouse Conditions In Equatorial Pacific., Daniel Nicholas Miller

Theses and Dissertations

To assess the atmospheric conditions during times of differing pole to equator thermal gradients through the middle Eocene to early Oligocene, 42 to 30 Ma, samples from deep-sea sediment cores U1331, U1332, U1333 from IODP Expedition 320/321 in the eastern equatorial Pacific (EEP) have been chemically leached to isolate the operationally defined eolian dust (ODED; <63 μm fraction). The ODED was analyzed for neodymium (Nd) isotopic compositions and rare earth element (REE) concentrations in order to determine the provenance of the ODED fraction and to elucidate the environmental conditions (e.g. predominant wind patterns) during deposition over the interval of study. The variations in the ODED fraction are expected to be controlled by changes in sources delivered via eolian input. However, negative cerium anomalies in the Post Achaean Australian Shale (PAAS) normalized rare earth element profiles of the ODED show a biasing geochemical seawater phase to the ODED signature. It is found that εNd values and cerium anomalies (Ce/Ce*) of ODED are consistent with fossil fish teeth values that record bottom water signatures from the same location and time period until ~36-37 Ma; around the Priabonian/Bartonian boundary marked by increased thermal gradients due to the emplacement of high elevation glaciers on Antarctica (Scher et. al., 2014). Moreover, the more negative cerium anomalies correlate to more radiogenic εNd values. The geochemical seawater signature in the ODED samples is believed to be caused by a change in sedimentary phase regulated by the spatial paleoposition of the sites relative to the biological high productivity zone and/or the depth of the CCD. Subsequently these regulators on the sedimentary phases of the ODED were investigated for biasing the geochemical signatures of the ODED, assumed to be changes in sources thereby provenance. Together, the Nd and REE results from the study temporally indicate that the ODED fraction may be a mixing between two sources, that of a biasing biogenic and/or authigenic source that records seawater conditions, and that of an older, less radiogenic continental source, inferred as Asian loess, as an increased thermal gradient prevails over the course of the study. Further research needs to be performed to make more robust and conclusive linkages between sources, mixing of sources, and atmospheric eolian delivery patterns, highlighting the necessity for a better understanding of atmospheric conditions during important climatic events throughout the history of the Earth.

Exploring Martian Magmas: From The Mantle To The Regolith, Arya Sigrid Waltraud Udry

Doctoral Dissertations

The planet Mars is geologically more similar to Earth than to other planets of the solar system. For the past 50 years, new rovers, orbital spacecraft, and new martian meteorites have helped us to understand the geological processes that occurred on Mars. In this dissertation, I investigate a wide range of martian igneous compositions, such as shergottite and nakhlite meteorites, Gusev and Gale surface basalts, and the Northwest Africa (NWA) 7034 breccia. I attempt to better understand magmatic processes that occurred in the martian mantle and crust as well as surficial processes using various petrologic and geochemical tools.

As shown …

An Examination Of Radionuclide Transport In The Vadose Zone Using Field Lysimeters, Michael Witmer

All Theses

Understanding how radionuclides interact in the subsurface is important for the remediation of contaminated sites, assessment of risk due to radioactive waste disposal, and designing new radioactive waste management strategies. The current understanding of the geochemical behavior of radionuclides in the subsurface and more specifically the vadose zone has been developed through reactive transport modeling supplemented by laboratory experiments. Interactions between radionuclides with the mineral particles and organic matter in the vadose zone can be very complex and while laboratory experiments produce valuable data, few controlled, intermediate scale transport studies have been performed. In order to accurately predict vadose zone …

Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan

Masters Theses & Specialist Projects

As ever-increasing levels of carbon dioxide alter the chemistry of the Earth’s atmosphere, understanding the global carbon cycle becomes increasingly important. A particularly important component is the riverine carbon cycle, as rivers are the primary conduits for dissolved inorganic carbon from terrestrial watersheds to ocean basins. Stable carbon isotopes (13C/12C) were collected weekly and input into the mixing model IsoSource to delineate seasonal carbon sourcing along two nested basins in the upper Green River System, Kentucky. In the more siliciclastic upstream catchment, dissolved inorganic carbon (DIC) was primarily derived from soil respiration (34%). Groundwater dissolving carbonate bedrock and carbonate dissolution/precipitation …

Hf-Nd Isotopic Variability In Mineral Dust From Chinese And Mongolian Deserts: Implications For Sources And Dispersal, Wancang Zhao, Youbin Sun, William Balsam, Huayu Lu

Dartmouth Scholarship

Mineral dust provenances are closely related to the orogenic processes which may have distinct Hf-Nd isotopic signatures. Here we report the clay-sized (<2 μm) Hf-Nd isotope data from Asian dust sources to better constrain the source and transport dynamics of dust deposition in the North Pacific. Our results show that there is a more positive radiogenic Hf isotopic composition with clay-sized fractions than the corresponding bulk sample and a decoupling of the Hf-Nd couplets in the clay formation during the weathering process. The clay-sized Hf-Nd isotopic compositions of the desert samples from the Sino-Korean-Tarim Craton (SKTC) are different from those of the Gobi and deserts from the Central Asian Orogeny Belt (CAOB) due to varying tectonic and weathering controls. The Hf-Nd isotopic compositions of dust in the North Pacific central province (NPC) match closely with those from the Taklimakan, Badain Jaran and adjacent Tengger deserts, implying that the NPC dust was mainly transported from these potential sources by the westerly jet. Our study indicates that dusts from the CAOB Gobi deserts either didn't arrive in NPC or were quantitatively insignificant, but they were likely transported to the North Pacific margin province (NPM) by East Asian winter monsoon.

Using Nd Isotopes To Understand Changes In Continental Weathering Flux In Mid-Pennsylvanian (Desmoinesian) Carbonate Cycles, Phil Ragonese

Earth and Planetary Sciences ETDs

Decades of study on Phanerozoic sedimentary deposits indicates that changes in Earth's orbital parameters are one of the main drivers of climate change on the 104-105 yr time scales, however understanding the relationships between climate change on coeval marine and continental deposits is difficult due to post-depositional erosion and tectonic processes. Nd isotopes measured in marine carbonates are a proxy for regional-scale continental weathering flux (CWF) and can help resolve these difficulties because its short residence time (less than ocean mixing times). This study focuses on cyclic Middle Pennsylvanian (Desmoinesian) marine successions from the Pedregosa (Arizona) and Bird Spring (southern …

Thermal Histories Of Cb Meteorites: Constraints From Compositions And Microstructures Of Sulfides, Poorna Srinivasan

Earth and Planetary Sciences ETDs

CBs are metal-rich carbonaceous chondrites, and are subdivided into type CBa and CBb, which are primarily distinguished by the size of particles. Although CBs are classified as chondrites, the high abundance of metal (>40%) make them a distinct group of meteorites. The origin of CBs is highly debated, but these meteorites are thought to have formed in an impact-generated vapor plume 4.563 Ga ago [Amelin et al., 2005; Krot et al., 2005], rather than in the solar nebula. This study focuses on textures and compositions of homogeneous and exsolved sulfides in metal grains in CB meteorites to constrain secondary …

Geochemistry And Stable Isotopes Of Surface Water And Groundwater In The Continental Pit In Butte, Montana, Usa, Amber Mcgivern

Graduate Theses & Non-Theses

The Continental porphyry Cu‐Mo mine, located 2 km east of the famous Berkeley Pit lake of Butte, Montana, contains two small lakes that vary in size depending on mining activity. In contrast to the acidic Berkeley Pit lake, the Continental Pit waters have near-neutral pH and relatively low metal concentrations. The main reason is geological: whereas the Berkeley Pit mined highly‐altered granite rich in pyrite with no neutralizing potential, the Continental Pit is mining weakly‐altered granite with lower pyrite concentrations and up to 1‐2% hydrothermal calcite. The purpose of this study was to gather and interpret information that bears on …

Geochemistry And Bioremediation Of Oiled Louisiana Salt Marshes Amended With Clay Minerals, Jill Ghelerter

Geosciences Dissertations

Salt marshes are one of the most difficult environments to remediate due to their sensitive and important ecosystems. Traditional cleanup methods can do more harm to the marsh than the oil itself. Bioremediation is the preferred cleanup approach for these delicate environments. Typically bioremediation has been carried out by the addition of nutrients but the results have been inconsistent. Previous laboratory studies conducted in oiled seawater demonstrated that clay minerals enhanced microbial growth and hence oil degradation. However, this had not been tested at field sites or on oiled marine sediments where oil is known to persist. The main objectives …

Assessing Landfill Contamination In Wyoming, Maxwell Blaine Gade

Theses - ALL

The Wyoming Department of Environmental Quality (WDEQ) suggested landfills across the State are contaminating groundwater with landfill leachate, soliciting an investigation of what useful aquifers might be contaminated, and whether remediation could be appropriate. My research goal is to broadly characterize groundwaters statewide to analyze the validity of WDEQ contamination claims, discuss the reliability of the WDEQ determination, and provide a feasible model of natural groundwater conditions. Volatile anthropogenic compounds such as acetone, methyl chloride, and dichlorobenzene are present in landfill leachte in discarded solvents and clearly can be used to characterize landfill leachate contamination. However, the WDEQ also uses …

Geochemical Effect And Fate Of Gold Nanoparticles (Aunps) In Saturated Soil Matrices, Theodore D. Williams

Theses - ALL

Gold nanoparticles (AuNPs) are extensively used in a number of applications including molecular detection through surface-enhanced Raman scattering, multifunctional nanocarriers for drug delivery, cancer diagnosis and treatment, catalysis and photonic/plasmonic devices. However, environmental fate and toxicity of AuNPs are not well understood or characterized. In this work, AuNPs of different concentrations were introduced and allowed to filter through various soil matrices in an effort to determine the physico-chemical interactions between the AuNPs and the aqueous porous soil medium. AuNPs deposition onto the soil particles and the mechanisms of their transport and release into the soil matrix are key factors that …

Trace/Heavy Metal Accumulation In Soil And In The Shoots Of Acacia Tree, Gümüfihane-Turkey, Alaaddin Vural

Bulletin of the Mineral Research and Exploration

In this study, heavy metal/trace element accumulation was investigated in soils along the
road passing through Gümüshane city center and shoots of 1-2 years of acacia trees
(Robiniapseudoacacia L.) grown in these soils. Heavy metal contents in soils and plants
were analyzed by Enrichment Factor (EF), Geo-accumulation index (Igeo) parameters,
and by Bio Accumulation Factor (BAF), respectively. According to geo-accumulation
index (Igeo) data, it is seen that the soil was unpolluted in terms of Cr, Co, Cu, Rb, Sr;
unpolluted to moderately polluted in terms of V, Ni and Zn; moderate to excessively
polluted in terms of As, and moderate …

Arc Crust-Magma Interaction In The Andean Southern Volcanic Zone From Thermobarometry, Mineral Composition, Radiogenic Isotope And Rare Earth Element Systematics Of The Azufre-Planchon-Peteroa Volcanic Complex, Chile, Sven P. Holbik

FIU Electronic Theses and Dissertations

The Andean Southern Volcanic Zone (SVZ) is a vast and complex continental arc that has been studied extensively to provide an understanding of arc-magma genesis, the origin and chemical evolution of the continental crust, and geochemical compositions of volcanic products. The present study focuses on distinguishing the magma/sub-arc crustal interaction of eruptive products from the Azufre-Planchon-Peteroa (APP 35°15’S) volcanic center and other major centers in the Central SVZ (CSVZ 37°S - 42°S), Transitional SVZ (TSVZ 34.3-37.0°S), and Northern SVZ (NSVZ 33°S - 34°30’S). New Hf and Nd isotopic and trace element data for SVZ centers are consistent with former studies …

The Impact Of Host Rock Geochemistry On Bacterial Community Structure In Oligotrophic Cave Environments, Hazel Barton, Nicholas Taylor, Michael Kreate, Austin Springer, Stuart Oehrle, Janet Bertog

Hazel Barton

Despite extremely starved conditions, caves contain surprisingly diverse microbial communities. Our research is geared toward understanding what ecosystems drivers are responsible for this high diversity. To asses the effect of rock fabric and mineralogy, we carried out a comparative geomicrobiology study within Carlsbad Cavern, New Mexico, USA. Samples were collected from two different geologic locations within the cave: WF1 in the Massive Member of the Capitan Formation and sF88 in the calcareous siltstones of the Yates Formation. We examined the organic content at each location using liquid chromatography mass spectroscopy and analyzed microbial community structure using molecular phylogenetic analyses. In …

Contact Zone Mineralogy And Geochemistry Of The Mt. Mica Pegmatite, Oxford County, Maine, Kimberly T. Clark

University of New Orleans Theses and Dissertations

This study focuses on exocontact mineral assemblages to determine composition, thermal signatures, and the extent of exomorphism that occurred between the Mt. Mica pegmatite and the migmatite host rock at the contact. Biotite-garnet thermometry of country rock samples resulted in an average temperature estimate of 630 °C. Measured biotite Fe/(Fe+Mg) ratios were used to calculate an fO2 of -18. The results indicate that the country rock and pegmatite formed under similar oxidizing conditions near the quartz-fayalite-magnetite (QFM) equilibria buffer. Whole rock (REE) analysis indicates an interaction trend between the country rock and pegmatite. Exomorphism does not appear to have …

A Geochemical Investigation Of The Usakos Gem Tourmaline Pegmatite, Namibia, Leah R. Grassi

University of New Orleans Theses and Dissertations

The Usakos pegmatite, Namibia, is a highly evolved, rare-element LCT-type pegmatite. The pegmatite is emplaced in metasedimentary rocks of the Kuiseb formation. Ca and Al enrichment at the contact, B mineralization in the country rock and Sr mineralization in the core of the pegmatite are all evidence of interaction of the pegmatite melt and hosting country rock. K/Rb ratios within mica and feldspar are very low indicating a highly evolved melt. Tourmaline has a fractionation trend from Fe-rich at contact and intermediate areas to Fe-depleted in core regions and pockets. Columbite tantalite group minerals show a similar trend in fractionation, …

Gastrointestinal Microbial Diversity And Diagenetic Alteration Of Bone From The American Alligator (Alligator Mississippiensis), Sarah Wheeler Keenan

Doctoral Dissertations

One of the most challenging questions in paleobiology is how bone transforms from a living tissue into a fossil. In life, the gastrointestinal tract microbiome of an animal promotes host health. But, in death, these microbial communities, as well as soil communities, begin to degrade tissue, including bones. Using the American alligator from coastal wetland habitats as a model system, the gastrointestinal tract microbiome was found to contain microbial communities consisting of Fusobacteria, Proteobacteria, Bacteroidetes, and Firmicutes, with variations based on tissue type along the length of the digestive tract. The overall dominance of Fusobacteria is distinct from any other …

Geochemical And Isotopic Variations In Surface Waters Of The Monongahela River Basin: An Area Of Accelerating Marcellus Shale Development In West Virginia, Adam J. Pelak

Graduate Theses, Dissertations, and Problem Reports

Water samples were collected from fifty streams in the Monongahela River basin of West Virginia at baseflow condition. The study area was divided into different Marcellus Shale production categories based the amount of Marcellus Shale gas production in a particular HUC-12 sub-watershed. All samples were analyzed for selected major and minor geochemistry, as well as stable isotopes of delta2HH2O, delta18OH2O, delta13CDIC, delta18OSO4 and delta34SSO4. The geochemical and isotopic characteristics of the 50 water samples collected show no clustering based on production category. Extremely high concentrations of total dissolved solids (TDS) are characteristic of produced water from Marcellus Shale production. All …

A Geochemical Study Of Crustal Plutonic Rocks From The Southern Mariana Trench Forearc: Relationship To Volcanic Rocks Erupted During Subduction Initiation, Julie A. Johnson

FIU Electronic Theses and Dissertations

Two suites of intermediate-felsic plutonic rocks were recovered by dredges RD63 and RD64 (R/V KK81-06-26) from the northern wall of the Mariana trench near Guam, which is located in the southern part of the Izu-Bonin-Mariana (IBM) island arc system. The locations of the dredges are significant as the area contains volcanic rocks (forearc basalts and boninites) that have been pivotal in explaining processes that occur when one lithospheric plate initially begins to subduct beneath another. The plutonic rocks have been classified based on petrologic and geochemical analyses, which provides insight to their origin and evolution in context of the surrounding …

Isotopic Fingerprinting Of Shallow And Deep Groundwaters In Southwestern Ontario And Its Applications To Abandoned Well Remediation, Mitchell E. Skuce

Electronic Thesis and Dissertation Repository

Abandoned hydrocarbon wells in southwestern Ontario can act as conduits for Sulphur water, brines, and hydrocarbons from deep Paleozoic bedrock aquifers. Such leakage may pose a threat to shallow groundwater and the environment. Cost-effective plugging of these wells requires knowledge of the sources of the leaking fluids. This study characterizes the isotopic compositions (δ18OH2O, δ2HH2O, δ34SSO4, δ18OSO4, δ13CDIC, 87Sr/86Sr) of groundwaters in the region, which are distinct in different bedrock formations. A Bayesian mixing model was applied to these data to develop a tool for identifying the source(s) of leaking fluids. The geochemical data also improve our understanding of groundwater …

Slides: Thoughts On Regulatory Mechanisms For Natural Resource Development: Alternatives To Command And Control, Including A Look At Open Source Approaches, Stanley Dempsey

Natural Resource Industries and the Sustainability Challenge (Martz Winter Symposium, February 27-28)

Presenter: Stanley Dempsey, Chairman, Royal Gold

17 slides

Reply To Comment By Jianguo Liu, Wen Yan, Zhong Chen, Han Chen, Jun Lu On "Holocene Evolution In Weathering And Erosion Patterns In The Pearl River Delta", Peter D. Clift

Faculty Publications

No abstract provided.

Linking Instrumental Neutron Activation Analysis (Inaa) With Geology In The Ancestral Caddo Region, Robert Z. Selden Jr.

CRHR: Archaeology

This poster illustrates the success of a novel method of INAA that was employed to reveal geochemical signatures in Caddo ceramic vessel sherds that correlate with local surficial geology. The geochemical data from the sherd assemblage were used within an exploration of potential ceramic provenance, which was successful at demarcating sherds from ceramic vessels made from clays in either the Claiborne or Wilcox Groups. Further geochemical segregation was also apparent between the Recklaw Formation in the Claiborne Group, and the Weches Formation in the Wilcox Group. These results point to a high degree of geochemical variability within the East Texas …

At The Confluence Of Gis And Geochemistry: Identifying Geochemical Correlates Of Ripley Engraved Caddo Ceramics, Robert Z. Selden Jr., Timothy K. Perttula

CRHR: Archaeology

In this poster, we discuss a new approach to the identification and definition of spatial trends in archeologically-recovered ceramics associated with geochemical results produced using instrumental neutron activation analysis (INAA). Using all of the Ripley Engraved INAA samples, we posit that clays in the Claiborne and Wilcox Groups can be successfully demarcated by sodium (Na), cerium (Ce), and zinc (Zn). Using a subset of those data from the Big Cypress Creek basin, we find that ceramics manufactured in three different Caddo political communities can be successfully demarcated based upon differential concentrations of arsenic (As), iron (Fe), and vanadium (V) found …

Testing Of The Recently Developed Tectonomagmatic Discrimination Diagrams From Hydrothermally Altered Igneous Rocks Of 7 Geothermal Fields, Kailasa Pandarinath

Turkish Journal of Earth Sciences

Recently developed multidimensional tectonomagmatic discrimination diagrams based on log-ratio variables of chemical elements, discordant outlier-free databases, and probability-based boundaries have been shown to work better than the earlier diagrams. Hydrothermally altered drilled well rock cuttings obtained from different depths of geothermal fields were used to test these diagrams to compare the inferred tectonic setting with the expected one. In spite of the hydrothermal alteration effects, these diagrams provided the following expected tectonic settings: (1) an arc setting for Ahuachapán and Berlin geothermal fields, El Salvador; (2) a rift setting for Cerro Prieto geothermal field, Mexico, and Tendaho geothermal field, Afar …

Exploring The Hydrogeologic Controls On Brackish Water And Its Suitability For Use In Hydraulic Fracturing: The Dockum Aquifer, Midland Basin Texas, Francisco Ruben Reyes

Open Access Theses & Dissertations

Water scarcity in arid regions can limit or impede certain hydrocarbon production activities, such as hydraulic fracturing and well drilling. The Midland Basin, a major oil-producing area in semi-arid far west Texas and the eastern sub-basin of the Permian Basin, is already impacted by limited freshwater availability. A typical tight oil well in the Midland Basin requires ~3.8-11.4 x 103 m3 of water per fracture treatment (Nicot et al., 2012). Despite draught conditions and limited resources, data for 2011 indicate freshwater comprises ~70% of the water used in hydraulic fracturing in the Midland basin. Thus, the Midland Basin represents an …