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Effects Of Urbanization On The Hydrologic Regime Of Johnson Creek, Portland, Oregon, William Vandewater Clement

Dissertations and Theses

The Johnson Creek watershed, Portland, Oregon, has undergone urbanization at an increasing rate. Excessive flooding has occurred in the lower portions of the watershed, resulting in an estimated 1.5 million dollars worth of flood losses annually. In attempts to mitigate the flooding damages millions of dollars have been spent to channelize the creek, and over 200 thousand dollars has been spent during the last 20 years on preliminary feasibility studies alone.

The author saw a need to verify that there has been a change in the rainfall-runoff relationships in the upper Johnson Creek basin since 1941 and to quantify this …

Alternating Current Studies And Kinetic Analysis Of Valinomycin Mediated Charge-Transport Through Lipid Bilayer Membranes, Kenneth Lee Cox

Dissertations and Theses

In this study we have investigated the frequency dependence of bilayer lipid membranes for a series of glycerylmonoolein/n-decane bilayers in various aqueous ionic solutions containing the ionophore valinomycin. Reliable values of membrane capacitance and conductance were obtained over the frequency range 0.2 - 200 KHz using an automatic balancing bridge under the control of a microprocessor unit. The admittance data was then normalized and curve-fitted to produce relaxation times and amplitudes from which the kinetic rate parameters, as deduced from a single slab dielectric membrane model, were calculated. These ac experimental rate constants were then compared with those obtained from …

Derivatives Of Trifluorovinylsulfur Pentafluoride And F-(Tert-Butyl) Hypochlorite, Jo Ann Marie Canich

Dissertations and Theses

Trifluorovinylsulfur pentafluoride dimerizes to (SF₅CFCF₂)₂ in the presence of cesium fluoride. Two derivatives of trifluorovinylsulfur pentafluoride, SF₅CF(CF₃)C(O)F and SF₅CF(CF₃)C(O)NH₂, were used to prepare the new compounds, SF₅CF(CF₃)CO₂H and SF₅CF(CF₃)CN, respectively. The first was prepared by reacting the SF₅-acid fluoride with water, while the second involved the abstraction of water from the SF₅-amide using P₄O₁₀. The attempted preparation of a bis-pentafluorosulfur ketone and a pentafluorosulfur containing acid anhydride …

Geology, Alteration And Mineralization Of A Silicic Volcanic Center, Glass Buttes, Oregon, Michael James Johnson

Dissertations and Theses

Glass Buttes, a Pliocene silicic volcanic complex within the High Lava Plains province of Oregon, was erupted approximately 5.0 to 5.8 million years ago. Geologic mapping revealed that the eastern portion of the complex is underlain by rhyolitic glass domes, flows and rare pyroclastis flows. Basalt flows are interlayered with and onlap the silicic glass. Younger basalt flows, erupted from local vents, overlie silicic glass and onlapping basalts.

The eastern end of Glass Buttes is hydrothermally altered at the surface; a weak geothermal anomaly coincides with the altered areas. Alteration, localized by northwest trending normal faults, occurs primarily as opalite …

Tiltmeter Analysis Of Mount St. Helens, Skamania County, Washington, Edward Charles Brown

Dissertations and Theses

Mount St. Helens returned to an active eruptive state March 20, 1980. Since then explosive and dome building eruptions have caused major topographic changes to the mountain and surrounding drainages. Monitoring of the southern side of the mountain by six tiltmeters at distances between 6 km and 12 km was conducted during the period of July 1, 1980 to December 31, 1980. Records obtained from the tiltmeters were analyzed and compared to data from precision geodetic surveys.

Quaternary Volcanology Of The West Crater-Soda Peaks Area, Southern Washington Cascade Range, David R. Polivka

Dissertations and Theses

The West Crater-Soda Peaks area covering about 100 km is located 35 km southeast of Mount St. Helens in southern Washington State. It is one of several Quaternary monogenetic High Cascade volcanic centers overlying the Ohaaapecosh Formation of the Western Cascade Group and interstratified glacial till.These volcanic centers are the most westerly of the range.

A Theoretical And Experimental Examination Of Sodium Chloride Hydration, Debra Conway Modra

Dissertations and Theses

A Hitachi Hu 125C transmission electron microscope in which the standard specimen holder was replaced by an environmental cell was used to observe the hydration of sodium chloride crystals. To observe Kelvin curvature and solubility effects sodium chloride crystals which were 0.1u or smaller were of special interest. An electrohome video system attached to the electron microscope was used to record the sodium chloride hydration for subsequent particle measurement and viewing.

A theoretical model was also developed. Thermodynamic properties such as the Kelvin curvature and solubility effects were considered as well as the kinetic expressions for salt dissolution/recrystalization and water …

Measurement Of Low Vapor Pressures : A Kinetic Approach, Samuel Bernard Bliden

Dissertations and Theses

A kinetic model was applied to vapor pressure data obtained by a variable flow method. The vapor pressures of benzoic acid, naphthalene, benzophenone, and phenylhydrazine were measured at temperatures of 293K to 307K. The data are summarized in the data table on the following page. These data were obtained by passing air over a sample of the substance in a tube. The air stream was combusted, and a flame ionization detector was used to measure the mass of CO₂ so obtained. Several different flow rates were used at each temperature with each substance.

High Valent Chromium (V) And Chromium (Vi) Complexes, Harry Bennett Davis

Dissertations and Theses

A new preparative route to the only neutral chromium (V) oxide fluoride, chromium oxide trifluoride, has been accomplished by the reaction of xenon difluoride with chromyl fluoride at high temperature. The chromium oxide trifluoride is produced as crystals which are suitable for single crystal studies. In reactions of chromium oxide trifluoride with alkali and alkaline metal fluorides in anhydrous hydrogen fluoride, new chromium(V) oxide fluoride salts were obtained; these salts were not of high purity due to unknown problems. An attempt to prepare chromium oxide tetrafluoride by the reaction of xenon difluoride with chromyl fluoride in anhydrous hydrogen fluoride failed …

Stratigraphy And Sedimentology Of Paleogene Arkosic And Volcaniclastic Strata, Johnson Creek-Chambers Creek Area, Southern Cascade Range, Washington, Warren Jon Winters

Dissertations and Theses

Over 1150 m of middle to late Eocene nonmarine arkose, lithic arkose, mudstone, and siltstone, referred to here as the Chambers Creek beds, are int~r.stratified with, and overlain by over 1600 m of late Eocene-Oligocsne(?) andesitic volcaniclastic and subordinate volcanic rocks assigned to the Ohanapecosh Formation, in a dissected structural high in the southern Washington Cascade Range, about 18 km south-southeast of the town of Packwood.