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Heterocyclic Syntheses Utilizing Aryl Cyanates, Joseph Eugene Drumm

Masters Theses

No abstract provided.

Geology Of A Section Of The Northwest Tobacco Root Mountains, Madison County, Southwest Montana, Kiff James Samuelson

Masters Theses

The northwest Tobacco Root Mountains are located on the boundary between two major tectonic provinces: the fold and thrust belt and the Rocky Mountain foreland. Deformation typical of the Rocky Mountain foreland is present in the form of two major northwest trending faults with associated folds. Paleozoic rocks were passively draped over at least one of the elevated Precambrian blocks. Foliation of the Precambrian rocks also appears to have been gently folded in the process.

Folds and thrusts occur within the Precambrian and Paleozoic rocks, on the westernmost flank of the range, appearing to follow the general trend of the …

Hydrogeologic And Geochemical Factors Influencing The Impact Of A Chromium-Arsenic-Copper Wastewater Discharge On A Glacial Outwash Aquifer, Michael J. Gallagher

Masters Theses

A discharge of chromium-arsenic-copper laden wastewater occurred periodically from 1970 to 1980 at a wood preserving company located in southwestern Kalamazoo County, Michigan. As a result of this discharge, soils at the company site became contaminated with chromium, arsenic, and copper, and a local glacial outwash aquifer became contaminated with hexavalent chromium.

Soil samples collected from the discharge site were analyzed for clay-silt-sand-gravel content, organic matter, pH, clay mineralogy, and chromium, arsenic, copper, iron, and manganese content. Background soil samples were analyzed for most of the above catagories. Pearson r coefficients of correlation were calculated to determine the correlation of …

Uranium-Lead Zircon Ages And Crustal Contamination Of The Northeastern Idaho Batholith, James J. Dexter

Masters Theses

The magmas which formed the northeastern Idaho batholith were contaminated with, or derived from, old crustal material as evidenced, from previous studies, by high whole-rock ⁸⁷Sr/⁸⁶Sr ratios, relatively high ²⁰⁷Pb/²⁰⁶Pb ages, and Archean to Proterozoic upper intercept ages for batholithic zircons.

The old zircon component has been identified in this study by separating zircons into fractions based on size and morphology. Pb/U isotopic ratios are distributed on a chord with a lower concordia intercept intrusive age of 73.6+6 m.y. Zircons from a batholithic sample located one kilometer inward from the contact were separated according …

The Depositional History Of The Point Pleasant Member Of The Cynthiana Formation In Northern Kentucky, Gary J. Stefaniak

Masters Theses

Bioclastic limestones, siltstones, and shales of the Point Pleasant Member were deposited in a shallow marine environment immediately below normal effective wave base. High-energy conditions produced by storms lowered the effective wave base and stirred the bottom sediments and redistributed them into bedforms. The different types of contacts, distribution of the faunal groups, and fabrics permit inferences regarding energy levels and assignment of samples to a mode of deposition. Vertical and lateral trends were then deduced. High-energy conditions are believed to have occurred during Early and Late Point Pleasant time, whereas, low-energy conditions prevailed during deposition of the middle Point …

The Application Of Multiderivative Infrared Spectroscopy To Iodine Number Determination, Jeffrey C. Lowry

Masters Theses

The Food and Drug Administration requires the disclosure of total unsaturation of commercial products as an indication of nutritional value. This unsaturation is a guide to the expected stability of food additives, such as edible oils and foods in which they are used. Unsaturation is typically evaluated as an iodine number, calculated for these additives based on their consumption of iodine through addition across the carbon-carbon double bonds. This titration method can typically take 45 minutes.

The investigation presented develops an alternative method for determining iodine numbers of some common oils using a computerized infrared spectophotometer. The analysis time, as …

Resolution Algorithms In A Parallel Processing Environment, Paula Beth Brandman Hencken

Masters Theses

An ever increasing number of processors are becoming available to the multiprocessor user. For faster response and efficient utilization of parallel processing systems it is necessary to develop parallel algorithms to solve a single problem.

This paper evaluates the complexity of resolution algorithms run in a parallel processing environment. An overview of parallel processing is presented along with a discussion of general resolution and resolution-refutation systems. An analysis of the complexity required by different control strategies to perform resolution programing is presented using both uniprocessor and multiprocessor systems.

Kinetics Of The Formation Of The Nickel(Ii) Complex With N, N' -Dimethylethylenediaminediacetic Acid And The Metal Exchange Reaction Between N,N'-Dimethylethylenediaminediacetatonickel(Ii) And Copper(Ii), Roger A. Karel

Masters Theses

The kinetics of the reaction of aquonickel (II) ion with N'N'-dimethlethylenediaminediacetic acid has been studied at 25°C and 0.1M iconic strength over a pH range of 6.0 to 9.3 using stopped-flow techniques. Formation reactions in all cases were first-order in Ni (II) and in ligand. The formation rate constant for the protonated and unprotonated species were evaluated and compared to their theoretical value. The rate-determining step is shown to be ring closure. A comparison of this system with other studies involving complexation of nickel (II) confirm the magnitude of the internal conjugate base effect and also shows a correlation between …

The Kinetics Of The Metal Exchange Reaction Between N-(2-Hydroxyethyl) Iminodiacetatonickelate (Il) And Copper(Ii), Craig R. Weed

Masters Theses

The reaction between copper(II) and N -(2-hydroxyethyl)iminodiacetatonickelate( II) (NiHEIDA) was studied between pH 4.0 and 5.6 over a 70 fold variation in copper concentration at an ionic strength of 1.25 and a temperature of 25° C. The reaction order in both NiHEIDA and Cu(U) is first. The reaction rate is pH sensitive and a hydrogen dependent pathway as w ell as copper dependent and copper and hydrogen independent pathways were found.

Evidence is given for a stepwise mechanism for the unwrapping of HEIDA from its nickel complex, follow ed by copper attack to give a dinuclear intermediate, which then breaks …

A Study Of Integral Equations For Computing Radial Distribution Functions, Robert C. Scherzer

Masters Theses

The use of integral equations to find radial distribution functions for computing thermodynamic properties is examined. The system considered is a simple classical fluid with interactions according to the Lennard-Jones (6-12) pair potential function. Two parametric integral equations (C and T) are studied in detail. Derivation of equation T and a power series solution are given. Computer solutions at several different temperatures, densities, and parameter values are obtained. Comparisons are made betv/een these results and results from integral equation N, PY, and HNC, and results from Monte Carlo, molecular dynamics, and power series methods. Equations C and N are found …

Geology Newsletter- 1984, Department Of Geology

Geological and Environmental Sciences News

Vol.1 No.9

• Dear Alumni and Friends
• Advisory Council
• Geology Development Fund
• Graduate Students
• Geology & Earth Science Club
• W. David Kuenzi Scholarship Fund
• 1983-84 Awards & Scholarships
• Faculty News
• Alumni News

Naphthalene-2,3-Dialdehyde: A Synthon To 7,9-Polymethylene-8h-Cyclohepta[B]Naphthalene-8-One And A Study Of Their Aromaticity, Edward O. Crapps

Dissertations

This report describes the synthesis of naphthalene-2,3-dialdehyde, and an analytical method for determining its purity by thin layer chromatography. Subsequently, the dialdehyde was condensed with various cyclic ketones to generate a series of polymethylene bridged naphthotropones. It was found that planarity and aromaticity increase with the size of the methylene bridge, although, the bridge must contain six or more methylene groups for the latter to be true. The claim for aromaticity is supported by NMR and IR data, which indicates the positive charge for a perchlorate cation salt is delocalized over the naphthalene and tropone ring system. Furthermore, from the …

On The Genus Of A Block Design, Joan Marie Rahn

Dissertations

The genus of a design (BIBD or PBIBD) is defined to be the genus of its corresponding hypergraph (objects as vertices, blocks as edges); that is, the genus of the bipartite graph associated with the hypergraph in a natural way. The Euler formula is used to establish a lower bound (gamma) for the genus of a block design. An imbedding of the design of the surface of genus (gamma) is then described by a voltage hypergraph or voltage graph. Use of the lower bound formula leads to a characterization of planar BIBDs. A connection between a block design derived from …

I. A Temperature Dependent Nmr Study Of 6,6-Dicarbethoxy-5,5-Dideuteodi-Benzo--[A,C]-[L, 3]-Cycloheptadiene Ii. The Synthesis Of Four Deuterated Analogs Of 6, 6-Dicarbethoxydibenzo-[A,C]-[1,3]-Cycloheptadiene, Patrick F. Jonas

Masters Theses

The kinetics of conformational interchange of 6,6-dicarbethoxydi-benzo- a,c - 1,3 -cyloheptadiene and its 5,5-dideuterated analog were studied using variable temperature NMR techniques. The free energy of activation for conformational interchange of the parent compound was found to be 9.02 kcal mol^-1 and that of the 5,5-dideuterated analog to be 9.42 kcal mol^-1. Values of the entropy of activation were found to be -19.91 e. u. and -18.12 e. u. respectively. The spectra were recorded on a Nicolet NMC-360 wide bore spectrometer and the data collected treated as an AB spin system.

The 4,8-dideutero, 4,5,5,8-tetradeutero and 5,5,7,7-tetradeutero analogs …

Land Use Effects On Shallow Earth Resistivity, Gary James Barton

Masters Theses

No abstract provided.

An Improvement In The Performance Of A Learning System For Finite State Machines, Lea F. Fuller

Masters Theses

A learning system is examined which is capable of learning a finite state machine from a class of finite state machines based on the observed behavior of the machine. The size of the search space becomes very large as the number of states in the machine increases. The size of the search space quickly becomes the limiting factor in the size of the class of machines which may be learned. An investigation is made of methods to improve the performance of the learning system. The application of a depth first approach to the development of the search space is shown …

The Chromatic And Cochromatic Number Of A Graph, John Gordon Gimbel

Dissertations

Clearly, there are many ways that one can partition the vertex sets of graphs. In the first chapter of this work I examine the problem of determining, for a given graph, the minimum order of a vertex partition having specified properties. In the remaining chapters I concentrate on partitions of two types--those in which each subset induces an empty graph and those in which each subset induces an empty or a complete graph.

The chromatic number of a graph G is the minimum number of subsets into which V(G) can be partitioned so that each subset induces an empty graph. …

A Quantitative Study Of The Copper Content In Granite Rocks, Samir F. Al-Mandwee

Masters Theses

A spectrographic analysis was conducted on ten granite samples of different geological origin from the Pioneer Mountains in Central Idaho. A qualitative analysis was performed first and then a quantitative analysis to determine the presence and relative amounts of copper in the various samples. This spectrographic analysis employed a direct current arc source of 340 volts and 4 amperes to excite the samples which were dissolved in acid and dried on the ends of high purity carbon electrodes. The emitted light passed through a step sector and a medium quartz spectrograph to a photographic plate. The optical density of the …

Learning Computer Logic Architectures On Apple Ii System, Falah Reda Al-Saffar

Masters Theses

For this thesis seven computer-assisted instruction packages have been designed to illustrate the design of electronic circuits of gates , the logic of combinational and sequential circuits, and integrated and magnetic core memories.

The programs in these packages have been written in the Pascal computer language on an Apple II microcomputer and stored on a double-sided floppy disk.

A Computer Aided Instructional System And Its Application Towards A Course On Snobol4 Programming Language, Abtin Edelji

Masters Theses

Computers are rapidly replacing humans in many tasks. Computer Aided Instructional System is an application of the computer in the teaching of a subject. Currently, a large number of educational Institutes use Computer Aided Instructional Systems.

The objectives of this thesis is to review some techniques in implementing such systems and to present a Computer Aided Instructional System called TEACH. The emphasis of this thesis is on the type of the directory used to minimize the search time for the TEACH System.

The Synthesis And Characterization Of Some Transition Metal Complexes Prom Mixtures Of Poly Pyrazolyl Borates, Robert Matthew Alway

Masters Theses

This is a report of the synthesis and separation of transition metal complexes of hydrotris(1-pyrazolyl)- borate and hydrotris(3,5-dimethyl-l-pyrazolyl)borate. These complexes contain a central metal ion and two tridentate ligands, one hydrotris(1-pyrazolyl)borate and one hydrotris(3,5-dimethyl-l-pyrazolyl)borate. Mass spectrometry proved to be an extremely useful technique for identifying products. Many mass spectra are included and discussed extensively.

Complexes containing hydrobis(pyrazole)(3,5-dimethyl -1-pyrazolyl)borate and hydrobis(3,5-dimethyl-l-pyrazole) (pyrazolyl)borate also were synthesised and mass spectra obtained.

A Geophysical Investigation Of A Possible Astrobleme In Southwestern Michigan, Suhas L. Ghatge

Masters Theses

A circular pattern to the oil production in Calvin Township, Cass County, Michigan, absence of about 1200 feet of Ordovician sediments and uplift indicated by a deep drill hole in the center of the productive area and absence of anomalies on the regional gravity and magnetic maps led to detailed gravity and magnetic surveys over this structure to delineate it and provide information regarding its genesis.

The Bouguer gravity and magnetic anomaly maps show no anomaly associated with the structure. The 28-mile wavelength second harmonic residual gravity and magnetic maps show linear features in the area. Two dimensional gravity modeling …

A Query-Processing Optimization Strategy For Generalized File Structures, Donna Marie Kaminski

Masters Theses

In processing a Boolean query against a non-inverted file, a subset of the query's keys must be selected. Only the records satisfying these keys need to be retrieved from the file. A dynamic programming algorithm, the Dual-to-minDF, is developed here for arriving at the optimum set of keys, i.e., the minimum number of external record retrievals. Previously suggested greedy methods yield feasible solutions which may or may not be optimal. This algorithm has exponential time complexity. However, it is useful for applications involving relatively short queries with duplication of keys within different conjuncts, and in cases where the files have …

Structural Geology Of The Northern Snowcrest Range, Beaverhead And Madison Counties, Montana, Mark Kenneth Sheedlo

Masters Theses

The Snowcrest Range was uplifted in Late Cretaceous and Early Tertiary time as a consequence of thrusting in Precambrian basement and Phanerozoic cover rocks.

The Snowcrest-Greenhorn thrust system is associated with largescale overturned, eastward verging folds. Mean orientation of the thrust system is N.40°E., 35°N.W.. The trend of the thrust system and associated transverse faults appear to be controlled by earlier structures. Mesoscopic and microscopic analyses indicate that metamorphic basement rocks accommodated congressional strain largely by brittle faulting and cataclastic shearing. Kinematic indicators suggest that local stresses were directed east-southeastward.

Northeast-trending Neogene faults along the western flank of the range …