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Impact Of Several Chemical And Physical Properties Of Two H-Coal Recycle Solvent Streams On Their Relative Solvent Quality, Joe Collins

Masters Theses & Specialist Projects

The purpose of this study was to follow the solvent quality curve of the recycle solvent streams of the H-Coal Pilot Plant run by Ashland Petroleum Company at Catlettsburg, Kentucky. This was done with the use of a microautoclave (shaker-bomb liquefaction unit). Several physical and chemical properties of these recycle oils were determined, and these values were correlated with the observed solvent quality. It is shown that the relative, solvent quality of these recycle oils correlate well with many of the chemical and some of the physical properties determined in this study.

Use Of Ft-Ir And Nmr Spectra Of The Thf Extracts Of Mid-Rank Bituminous Coals To Predict Plasticity, Samuel Adesoji Irefin

Masters Theses & Specialist Projects

Plasticity, which typically develops at 380-420°C, is a unique property of mid-ranked coals. The phenomenon of plasticity in coals has been known for a long time but is still poorly understood. Even among coals of identical subrank and chemical composition, large differences in plastic behavior are commonly encountered. Plastic coals go through a softening and swelling state upon heating before they resolidify. Concurrent with the plastic state of the coal, thermal decomposition of the coal takes place.

The coking ability of a coal can be directly related to the plasticity of the coal. In liquefaction reactions, plastic coals tend to …

The Nature Of Supported Co-Mo And Ni-W And Hydrodenitrogenation And Hydrodesulfurization Of Model Compounds, Eric Dadey

Masters Theses & Specialist Projects

The catalytic vapor-phase isomerization, hydrogenolysis, and/or disproportionation of trimethylbenzen (TMB) over Co-Mo/Al₂O₃ and Ni-W/Al₂O₃ was studied at 480°C, 400 psi reactor pressure, and a constant H₂ flow. Each catalyst was run in the reduced or sulfided form. The results show a marked difference in the product distributions for each catalyst, which is attributed to differences in the catalysts’ acidities.

The hydrodenitrogenation (HDN) of quinolone and the hydrodesulfurization (HDS) of benzothiophene were also studied. The compounds were reacted in a 1 liter autoclave at 325°C and varying partial pressures of H₂. The …

Spontaneous Heating Of Coal & Electrochemical Measurements Of Corrosion Rates, Bihan Naderi

Masters Theses & Specialist Projects

A new and relatively fast method for measuring the susceptibility of coal to spontaneous heating was studied in this work.

This method is based on the ability of coal to adsorb iron(III) from aqueous solutions. The more iron taken up by the coal, the more susceptible the coal is to spontaneous heating. The relationship holds for most of the coals being analyzed during this research project and for other succeeding ones.

The experimental procedures used and results obtained are discussed. A brief literature survey of other applied methods which have been studied, including a description of many factors affecting the …

Enteric Contamination Of An Urban Karstified Carbonate Aquifer: The Double Springs Drainage Basin, Bowling Green, Kentucky, Geary Schindel

Masters Theses & Specialist Projects

Biological and chemical analysis of water samples, collected from surface and subsurface streams was preformed to determine the quantity and biologic sources of enteric contamination in the Double Springs Groundwater Basin, an urban karstified carbonate aquifer under Bowling Green, Kentucky. Major flow paths, drainage basin boundaries and geologic/hydrologic relationships were identified for the basin. Analysis of biologic contaminates using fecal coliform /fecal streptococcus counts and ratios were conducted for baseflow and storm events and related to the Double Springs hydrographs. Analysis was also conducted to determine the source of sulfides responsible for the growth of sulfur fixing bacteria in the …

Non-Matrix Corrected Organic Sulfur Determination In Coal By Energy Dispersive X-Ray Spectroscopy, Carol Clark

Masters Theses & Specialist Projects

A method for non-matrix corrected organic sulfur analysis by energy dispersive X-ray spectroscopy has been developed using petroleum coke standards. This technique capitalizes on the fact that when a substance is excited by an electron beam it will emit photons of electromagnetic radiation in the X-ray range. The emitted X-rays are characteristic of the excited elements in the substance. Typically, electron beam microanalysis is a rapid, nondestructive analytical technique to quantitatively measure organic sulfur in coal. The results show good correlation to ASTM values for numerous well characterized bituminous coals with a wide range in total and pyritic sulfur content. …

Desulfurization Of Coal Using Carboxylic Acids & Peracids, Dwight Watson

Masters Theses & Specialist Projects

Bituminous coals were desulfurized by leaching in a 325 ml, agitated, autoclave with hot, dilute solutions of carboxylic acids, buffered carboxylic acids, carboxylic salts, and carboxylic salt:alkali combinations. The partial pressure of oxygen was not increased as it was found not to increase the amount of organic sulfur removal. The effect of increasing carboxylic size and decree of desulfurization was studied. Among the carboxylic acids studied, formic acid removed the greatest amount of organic sulfur;and iso-valeric acid removed the greatest percentage of pyritic sulfur. It was found that there is a direct correlation between the amount of organic sulfur removal …

A Bacteriological And Chemical Analysis Of Nonpoint Source Pollution In A Karst Aquifer Bowling Green, Kentucky, Wayne Green

Masters Theses & Specialist Projects

Monthly water samples collected from four sites in the Lost River Groundwater Basin, a shallow karst aquifer in the Bowling Green-Warren County area of Kentucky, represented samples from sites receiving conduit and diffuse flow. All sites were severely contaminated with bacteria, and on some occasions the surface water criteria for some heavy metals were exceeded.

Of the total 334 bacterial colonies identified 92.1% were verified as Escherichia coli by the API20E system. Acinetobacter calcoaceticus var. anitratum accounted for 2.10% of colonies; Citrobacter freundii for 0.30% Klebsiella pneumoniae for 0.90%; Klebsiella oxytoca, 0.90%; Citrobacter amalonaticus 0.30%; Enterobacter cloacae, 1.20%; …

The Low-Temperature Pyrolysis Of A Nitrated North Dakota Lignite, Dennis Spears

Masters Theses & Specialist Projects

Low-temperature pyrolysis is the thermal degradation of coal in an inert atmosphere at temperatures below 700°C. Coal pyrolysis is well-studied, being a complex mix of many reactions. Pyrolysis is affected by changes in many different process variables, such as temperature, pressure and heating rate. Low-temperature pyrolysis is an old and well-studied process.

Chemical pretreatments have been used to beneficiate conversion processes, inducln pyrolysis. Nitration has not been one of them. Pyrolyzing a nitrated coal would, hopefully, rapidly devolatilize the coal and break up the matrix into more commercially usable products. The nitration procedure developed by The Standard Oil Company minimizes …

Corrosion Of Carbon Steel In Synthetic Coal Liquid Wash Waters, Keith Evans

Masters Theses & Specialist Projects

The Potentiodynamic corrosion measuring technique is an electrochemical analytical method which measures corrosion rates of a metal exposed to a corrosive environment.

The corrosion characteristics of carbon steel A1044 in aqueous solutions of aniline hydrochloride,simulating a coal liquid wash water, were determined by this method. The effects of solution velocity and oxygen concentration on the system were also determined.

A bimodal corrosion rate effect was observed in deaerated solutions of 1000 and 5000 ppm chloride as aniline hydrochloride. This effect was interpreted to be the result of the formation of a film on the surface of the specimen.

H2o2-Tfa-H2so4 Oxidation Of Coal & Coal Model Compounds, Darrell Pierce

Masters Theses & Specialist Projects

The Deno coal oxidation technique was investigated as a tool for the characterization of the aliphatic components of coal. This technique was applied to three high sulfur Kentucky coals:(1) No. 789673, (2) KCER 4002-Elkhorn No. 2, (3) KCER 7122-Ky. No. 12 and a low sulfur coal from Alpha Resources, Inc. Model compound investigations on toluene, ethyl benzene, propyl benzene, bibenzyl, indan and tetralin were also conducted. Different addition modes were investigated using ethyl benzene and diphenylmethane. The stability of the expected aliphatic acid products in the oxidation reagent were also investigated.

The data indicated the following:

1. Pyrite present in high …

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Ua66/8/2 Growing Season In Kentucky 1951-1980, Wku Climate Center, Glen Conner, Mark Simpson

WKU Archives Records

Kentucky Climate Center report number 26 Growing Season in Kentucky 1951-1980.

Ua66/8/3 Annual Report, Wku Geography & Geology

WKU Archives Records

Annual report of activities of the WKU department of Geography & Geology.