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Herbicide-Amine Salt Volatilization From The Solution And Dried Residue, Stephen M. Sharkey

McKelvey School of Engineering Theses & Dissertations

Due to the increasing reports of glyphosate resistant weeds, genetically modified (GM) glyphosate tolerant crops have been supplemented with crops resistant to alternative herbicides such as dicamba (3,6-dichloro-2-methoxybenzoic acid) and 2,4-D (2,4-dichlorophenoxyacetic acid). Since the introduction of dicamba and 2,4-D tolerant crops in the U.S., there has been a substantial increase in reports of off-target dicamba and 2,4-D movement and damage (i.e., drift) to non-tolerant vegetation and crops. The off-target damage has been documented by U.S. news sources and increased complaints to State Departments of Agriculture. These complaints have been especially high for dicamba, with the U.S. Environmental Protection Agency …

The Effects Of Glyphosate Salts And Volatility-Reducing Agents (Vra) On Dicamba Volatility, Nicole Glenn

Theses and Dissertations

Dicamba is often tank mixed with glyphosate to increase herbicidal efficacy but may contribute to off-target movement (OTM). In recent years, volatilization has become problematic for dicamba-containing herbicides, resulting in increased regulatory requirements necessitating the use of volatility-reducing agents (VRA) for application. Research was conducted in 2021 and 2022 using low tunnels in a field environment and humidomes in a greenhouse environment to further assess how glyphosate salts and VRAs affect dicamba volatility. Our data indicate that the inclusion of glyphosate to dicamba can increase dicamba volatility, depending on the glyphosate salt used. The inclusion of the evaluated VRAs will …

Characterization And Management Of Auxin-Resistant Palmer Amaranth In Tennessee, Delaney C. Foster

Doctoral Dissertations

Palmer amaranth has a long history of evolving resistance to herbicides to the point it has become a significant row crop production obstacle. Cotton and soybean growers were offered new technologies in 2016, expanding in-crop herbicide options to include dicamba or 2,4-D. Within three years of commercialization, dicamba use in these crops increased ten-fold and growers began to report Palmer amaranth escapes in west Tennessee auxin-tolerant production systems. A survey of Palmer amaranth escapes in dicamba and 2,4-D-tolerant cotton and soybean fields in Tennessee was conducted in the fall of 2021 with the objective of determining if poor control was …

Soybean (Glycine Max) Response To Multiple, Sublethal Exposures Of 2,4-D And Dicamba From Vegetative Through Reproductive Growth, Graham Robert Oakley

Theses and Dissertations

This study was conducted to determine whether soybean productivity is affected by multiple, sublethal herbicide exposures. The effects of dicamba and 2,4-D on soybean (Glycine max) productivity was investigated at 17 site-years. Relative to a single exposure of dicamba at R1, an additional exposure at either V3 or R3 reduced yield up to 23%. Three or more applications did not further decrease yields relative to an R1&R3 exposure. For 2,4-D, a single application to V3, R1, R3, or R5 soybean did not affect grain yield. However, two exposures of 2,4-D occurring from V3 through R3 reduced yield 5 to 7%. …

Optimization And Resistance Mitigation Of Dicamba And Glufosinate In Xtendflex® Crops, Grant Lawson Priess

Graduate Theses and Dissertations

The commercial launch of XtendFlex® crops enabled the use of dicamba, glufosinate, and glyphosate in-season. Utilizing herbicides that target different sites of action within troublesome weeds has been a tactic proposed to mitigate the likelihood of target-site resistance evolving; however, if interactions of the herbicides are detrimental to control of weedy species the likelihood of metabolic resistance increases. The objective of this research was to: 1) optimize efficacy and economic benefits of dicamba, glufosinate, and glyphosate; 2) characterize any interactions that were observed; 3) understand the mechanisms responsible for the reductions in weed control; 4) attempt to overcome interactions that …

Relative Soybean Response To Aminocyclopyrachlor, 2,4-D, Dicamba, And Aminopyralid, Trey I. Clark

Masters Theses

This research compared the visual symptomology of four auxin herbicides applied at three rates to simulate tank contamination on non-auxin tolerant soybeans. The herbicides examined were aminocyclopyrachlor (ACP), 2,4-D, dicamba, and aminopyralid. The standard labeled rates (SLR) used to base the application rates were 0.12 kg ae ha^-1 for ACP and aminopyralid while dicamba and 2,4-D used 1.12 kg ae ha^-1. These four herbicides exhibit similar symptoms on soybeans which is problematic when diagnosing soybean response. One goal of this project was to obtain high-quality images of the four herbicide’s effect on soybeans, with the hope of …

Characterization And Management Of Glyphosate-Resistant Junglerice, Clay M. Perkins

Doctoral Dissertations

Junglerice has become a major weed in Tennessee and across the mid-south. Glyphosate resistance and dicamba antagonism has resulted in the reported control failures and rise in prevalence. Junglerice was the most prevalent weed escape in cotton and soybean fields across Tennessee from 2018 to 2020. In all, 13% of the junglerice accessions could no longer be effectively controlled with glyphosate. Due to poor in-crop control, it has been recommended to start clean when trying to control junglerice and other grasses. Therefore, research was conducted to determine the best burndown methods utilizing dicamba, glufosinate, or paraquat. A sequential application of …

Evaluation Of Dicamba Volatility When Applied Under Field And Controlled Environmental Conditions, John M. Taylor

Theses and Dissertations

Dicamba resistant (DR) cropping technology has increased dicamba use, resulting in observation of dicamba off-target-movement (OTM). Volatility is one form of this movement. Tank mixtures and environmental conditions impact the volatile behavior of dicamba following application. Research was conducted in 2018, 2019, and 2020 to further assess and understand volatility mitigation by understanding tank-mix effects and utility of irrigation on volatility mitigation. Low tunnel and humidome methodology were used to analyze impact of tank mixtures and irrigation on dicamba volatility. Data suggest tank mixing encapsulated chloroacetamide formulations can mitigate volatility when comparing identical active ingredients formulated as emulsifiable concentrates. Tank-mixed …

Crop Response To Low-Dose Dicamba, Mason Castner

Graduate Theses and Dissertations

The introduction of dicamba-resistant (DR) soybean [Glycine max (L.) Merr.] and cotton (Gossypium hirsutum L.) followed by a label allowing over-the-top applications of dicamba in the 2017 provided growers an additional option for broadleaf weed control. Because non-DR soybean is sensitive to low concentrations of dicamba, postemergence dicamba applications present growers choosing to plant non-DR soybean with concerns of damage from off-target movement through physical drift and volatilization of the herbicide as well as tank-contamination from prior dicamba application. Consequences of low-dose dicamba exposure on sensitive vegetative and reproductive soybean have been well researched, but little is known regarding the …

Sensitivity Of Enlisttm And Roundup Ready Xtend® Technologies To Auxin Herbicides And Comparison Of Resistance To Susceptible Cotton And Soybean Cultivars, James Rose

Graduate Theses and Dissertations

Increases in weed resistance have led to the development of new herbicide-resistant crop technologies, namely the Roundup Ready Xtend® and EnlistTM weed control systems. These new technologies provide resistance to applications of the synthetic auxins dicamba or 2,4-D, respectively, in traited cotton or soybean. It is unknown if there is any resistance to other herbicides within the synthetic auxin group (WSSA Group 4) in these traited crops. Experiments were conducted with auxin herbicides representing all five families within WSSA Group 4. Herbicides were applied either preemergence (PRE) or postemergence (POST) relative to the crop in a single application. Applications were …

Evaluation Of Pesticide Application Technology In Cotton Production, Chase Samples

Theses and Dissertations

There have been many changes in production agriculture over the last 20 years. The use of herbicide resistant crops has become common place in production agriculture. However, the release of crops resistant to auxin herbicides has brought more attention to the pesticide application process regardless of the type of pesticide applied. Moreover, controlling off-target movement of pesticides has become an integral part of the day to day farming tasks. The use of deposition aids when applied with water has been documented; however, the effect of deposition aids on pesticide application is not well understood. Based on these findings, selecting a …

Spectroscopic And Computational Studies Of The Agricultural Active Ingredient Dicamba, James Johnson

Honors Theses

3,6-dichloro-2-methoxy benzoic acid, more commonly known as Dicamba, is the active ingredient in an array of pesticides used on farmlands across the globe. Dicamba’s mode of action works by mimicking the plant hormone auxin, which is synonymous to growth hormones in mammals. The mimicking of auxin results in excessive elongation and growing, which is eventually fatal for plants when the rate of growth can no longer be sustained. Dicamba has risen in prominence in recent years due to drift damage as a result of Dicamba’s high volatility. Having the ability to identify Dicamba is crucial for the agricultural industry. The …

Glyphosate Plus Dicamba Spray Solution Deposition, Coverage, And Efficacy As Influenced By Spray Nozzle Design And Weed Density, Madison Dru Kramer

Theses and Dissertations--Plant and Soil Sciences

Dicamba injury to sensitive soybean and other broadleaf crops due to drift is a major issue and label restrictions have been created to mitigate dicamba drift. One restriction is the mandated use of low drift nozzles to spray dicamba; these nozzles produce larger droplets and minimize the production of driftable fines. Experiments were conducted to evaluate herbicide coverage, deposition, and efficacy. Three spray nozzle designs and different weed densities were the main factors in the analysis. Dicamba plus glyphosate was applied to 5 to 10 cm tall weeds with a Turbo TeeJet (TT11005) nozzle and two drift reduction nozzles approved …

Evaluation Of The Influence Of Dicamba Exposure On Crop Injury And Canopy Closure Of Glufosinate Resistant Soybean, Zachary K. Perry

Theses and Dissertations--Plant and Soil Sciences

Dicamba-resistant soybean along with lower volatility dicamba formulations have been introduced in an attempt to control herbicide resistant weeds such as Amaranthus palmeri. This introduction has increased the amount of dicamba being applied later in the growing season increasing the prevalence of dicamba off-target movement. Dicamba damage was simulated by applying low rates of dicamba directly on soybeans at rates (0.5 g ae ha^-1, 1 g ae ha^-1 and 5 g ae ha^-1 dicamba) and five-exposure timings from June 1 to July 10. The experimental design was a randomized complete block with four replications at …

Reduced Herbicide Antagonism Through Novel Spray Application Techniques, Luke H. Merritt

Theses and Dissertations

Field studies were conducted to test three application methods for applying antagonistic herbicide combinations: 1) tank mix (TMX), 2) mix-in-line (MIL), and 3) separate boom (SPB). Sethoxydim applied with bentazon, glyphosate applied with dicamba or 2,4-D, and clethodim applied with dicamba or 2,4-D had higher efficacy when applied using the SPB method. Antagonism of all the herbicide combinations above was observed when applied using the TMX and MIL methods. In some cases, antagonism was avoided when using the SPB method. Three application methods tested in greenhouse studies were 1) TMX, 2) synthetic auxin applied first (AAF), and 3) synthetic auxin …

Investigating Dicamba Tolerance In Grapevine Cultivars Through Drift Simulation Assays, Bryce David Bentley

MSU Graduate Theses

Dicamba is a synthetic auxin herbicide which acts systematically and selectively controls broadleaf plants and has become increasingly popular in the past several years for weed control in commercial agriculture following widespread adoption of dicamba-resistant, transgenic soybean and cotton. Dicamba may be better acknowledged by growers of specialty crops, like grapes, for its capacity to drift miles away from the site of application and deposit on fields, remaining potent enough to cause crop damage and yield loss to vulnerable plants. Grapes are among the most susceptible agronomic crops to dicamba drift, showing visible injury at rates less than 1% of …

Stewarding 2,4-D- And Dicamba- Based Weed Control Technologies In Cotton And Soybean Production Systems, John Tyler Buol

Theses and Dissertations

Distinguishing 2,4-D and dicamba herbicide formulations in cotton and soybean tissue is challenging in regulation of crop injury from these herbicides. Additionally, stewardship of 2,4-D and dicamba technologies is important to maximize their longevity and efficacy. Research was conducted to (1) characterize cotton and soybean response to various formulations of 2,4-D or dicamba with or without glyphosate, (2) develop a method for classifying these formulations in crop tissue, and (3) optimize use of chloroacetamide herbicides in dicamba systems for mitigation of selection pressure on dicamba. Formulations evaluated include dicamba diglycolamine (DGA), dimethylamine (DMA), N,N-Bis-(3-aminopropyl) methylamine (BAPMA), and DGA plus potassium …

Integrating Cover Crops And Herbicides For Horseweed [Conyza Canadensis (L.) Cronq.] Management Prior To Soybean [Glycine Max (L.) Merr.], Austin Sherman

Theses and Dissertations--Plant and Soil Sciences

Horseweed (Conyza canadensis (L.) Cronq.) is prevalent in Kentucky and can be difficult to control. Research has shown multiple weed control methods to be more sustainable than relying on chemical control alone, so the use of multiple methods for horseweed management was examined in this study. The main objective was to determine best practice(s) to reduce horseweed prior to soybean [Glycine max (L.) Merr.]. Treatments included: fall-planted cover crop [CC; cereal rye (Secale cereale L.) or none], fall-applied herbicide (saflufenacil or none), and spring-applied herbicides (dicamba, 2,4-D ester, or none). We hypothesized horseweed densities would be reduced …

Synthesis Of Dicamba Glucosides For The Study Of Environmental Dicamba Drift Effects On Soybeans, Holly Wallace

Graduate Theses and Dissertations

The most popular herbicide used for weed control has been glyphosate for many years in the Midwestern United States. Plants have begun to develop a resistance to glyphosate due to over use of the herbicide. This herbicide resistance has pushed farmers to turn to alternative herbicides such as dicamba and 2,4-D. Recently agrochemical companies have developed genetically modified crops that are resistant to herbicides such as dicamba. These modified crops allow farmers to spray their fields with dicamba without fear of crop damage. Farmers of non-genetically modified crops, however, suffer damage and loss of yield from herbicide drift effects of …

Soybean Response To Dicamba: Associated Injury Criteria And Development Of A Model To Predict Yield Loss, Matthew Ryan Foster

LSU Doctoral Dissertations

In research conducted using indeterminate soybean [Glycine max (L.) Merr.], fourteen injury criteria observed following dicamba at 0.6 to 280 g ae ha^-1 (1/1000 to ½ of 560 g ha^-1 use rate) were rated using a scale of 0= no injury, 1= slight, 2= slight to moderate, 3= moderate, 4= moderate to severe, and 5= severe. Greatest crop injury 15 d after treatment (DAT) was observed following dicamba applied at 0.6 to 4.4 g ha^-1 at V3/V4 for upper canopy pale leaf margins (3.8 to 4.2) and at R1/R2 for terminal leaf cupping (4.1 to 5.0) …

Dicamba Effects On Soybean (Glycine Max) Growth, Yield, And Offspring, Mark Spencer Mccown

Graduate Theses and Dissertations

Introduction of a new dicamba-resistant (Xtend) trait in soybean and cotton will increase dicamba herbicide use. Consequently, concern for injury to sensitive crops from off-target movement and tank contamination will likely increase. For soybean, foliar symptoms associated with dicamba damage do not necessarily reflect yield losses; hence, experiments were conducted to determine the effects of dicamba on soybean growth, yield, and offspring. Low rates of dicamba [1/64X (8.75 g ae ha-1) and 1/256X (2.18 g ae ha-1) of a normal 1X field rate (560 g ae ha-1)] were applied at two vegetative growth stages (V4, V6) and at each reproductive …

Evaluation Of Dicamba Off-Target Movement And Subsequent Effects On Soybean Offspring, Gordon Travis Jones

Graduate Theses and Dissertations

Commercial launch of cotton with resistance to dicamba, glyphosate, and glufosinate occurred in 2015 and launch of soybean with resistance to dicamba and glyphosate occurred in early 2016. It is likely that non-dicamba-resistant soybean will be planted in close proximity to dicamba-resistant soybean and cotton. Therefore, experiments were conducted to examine the distance dicamba moves during an application using commercial application equipment, as well as the effect the drift events have upon soybean offspring. Additional experiments were designed to investigate the effect glyphosate addition to dicamba has upon soybean growth and yield as well as possible effects on offspring. Lastly, …

Impact Of Reduced Rates Of Hormonal Herbicides Aon Sweetpotato (Ipomoea Batatas Lam.) Growth And Development, Thomas Michael Batts

LSU Master's Theses

Studies evaluated impact of dicamba, 2,4-D, and glyphosate at reduced rates to sweetpotato at root formation (RF) and development (RD) growth stages. For DGA salt of dicamba at RF, glyphosate plus dicamba at 1/10x reduced storage root number 42%, canner grade yield 33%, and total yield 36%. With choline salt of 2,4-D at RF, storage root number compared to the non-treated (6.5) was reduced with glyphosate alone at 1/100x (5.1), 2,4-D alone at 1/250x (5.1), and glyphosate plus 2,4-D applied at 1/10 (4.2) and 1/1000x (5). Canner yield was reduced 32% with glyphosate alone 1/10x, 26 and 27% with 2,4-D …

Evaluation Of Herbicide Formulation And Spray Nozzle Selection On Physical Spray Drift, Jasper Lewis Cobb

Theses and Dissertations

New transgenic crops are currently being developed which will be tolerant to dicamba and 2,4-D herbicides. This technology could greatly benefit producers who are impacted by weed species that have developed resistance to other herbicides, like glyphosate-resistant Palmer Amaranth. Adoption of this new technology is likely to be rapid and widespread which will lead to an increase in the amount of dicamba and 2,4-D applied each season. It is well-documented that these herbicides are very injurious to soybeans, cotton, tomatoes, and most other broadleaf crops, and their increased use brings along increased chances of physical spray drift onto susceptible crops. …

Determining The Effect Of Auxin Herbicide Concentration And Application Timing On Soybean (Glycine Max) Growth And Yield, Alanna Blaine Scholtes

Theses and Dissertations

Auxin resistant cropping systems will provide producers with an alternative option for weed management, but with this new technology also comes the concern of off target movement of dicamba and/or 2,4-D to susceptible crops. Research was conducted over multiple site years in order to determine the effect of soybean response to different application timings and rates of 2,4-D and dicamba. 2,4-D was applied at 1X (0.56 kg ae/ha), 1/4X, 1/16X, 1/64X, and 1/256X rates, and dicamba was applied in a separate study at 1X (0.56 kg ae/ha), 1/4X, 1/16X, 1/64X, 1/256 and 1/1024X. All rates were applied at the V3 …

Management Of Glyphosate Resistant Palmer Amaranth In Bollgard Ii Xtendflex" Cotton, Daniel Zachary Reynolds

Theses and Dissertations

Experiments were conducted to evaluate efficacy of dicamba, glufosinate, and glyphosate on Palmer amaranth (Amaranthus palmeri S. Wats.). Residual control was evaluated after dicamba was applied alone and in combination with fomesafen, fluometuron, acetochlor, and prometryn. Postemergence efficacy of dicamba, glufosinate, and glyphosate on different size Palmer amaranth was also evaluated. In addition, combinations of dicamba, glufosinate, and glyphosate were evaluated for efficacy on Palmer amaranth as well as spray coverage and spray droplet size as affected by various spray nozzles. Lastly, tolerance to dicamba, glufosinate, and glyphosate of cotton cultivars containing Bollgard II® XtendFlex™ technology was examined. Dicamba exhibited …

Postemergence And Residual Control Of Glyphosate-Resistant Palmer Amaranth (Amaranthus Palmeri) With Dicamba, Clifford Blake Edwards

Theses and Dissertations

Onarm research was conducted in 2011 and 2012 to determine the postemergence and residual control by dicamba of glyphosate-resistant (GR) Palmer amaranth (Amaranthus palmeri S. Wats.). Preemergence dicamba at 0, 0.28, 0.56, and 1.1 kg ae ha-1 and 0.07 kg ae ha-1 flumioxazin was applied at 30, 15 and 0 days prior to planting. Postemergence dicamba at 0.28, 0.56, and 1.1 kg ae ha-1 with and without 0.84 kg ae ha-1 glyphosate was applied to 5, 10 and 15 cm Palmer amaranth. In addition, a greenhouse experiment was conducted in 2012 to evaluate and confirm the optimum rate for control …

Anatomical Effects Of Dicamba On Pea Root Tissues, Brent George Ovard

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Peas (Pisum sativum L. Var Alaska) were allowed to absorb calcium and magnesium chloride for 8 hours and then were germinated in a potassium phosphate buffer pH 6.5 for 40 hours. Peas were then treated with 0, 0.1, 0.3, or 0.5 ppm dicamba (3,6-dichloro-o-anisic acid) and harvested at 24, 48, and 72 hour intervals. The following determinations were recorded: root elongation, nuclear volume, and anatomical modifications.

Root elongation recordings showed that dicamba prevented normal root elongation. Treatments induced very short thick primary roots.

Measurements of nuclear volume indicated that all herbicide concentrations were able to reduce the …

Response Of Common Purslane To Dicamba Treatment., Maria Stacewicz-Sapuncakis

Doctoral Dissertations 1896 - February 2014

No abstract provided.