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Novel Design And Synthesis Of Composite Nanomaterials For Lithium And Multivalent Ion Batteries, Wangwang Xu

LSU Doctoral Dissertations

Nowadays, the fast-increasing energy demand for efficient, sustainable and environmentally-friendly energy storage devices remains a significant and challenging issue. Lithium ion batteries (LIBs) have been widely used as commercial energy devices in portable electronics and also shown great promise in upcoming large-scale applications due to their advantages of environmental safety, efficiency in energy delivering and light weight. However, due to their limited capacity, energy densities and cycle ability, LIBs still need further improvement to expand their applications to a larger field, especially electric vehicle (EVs) and hybrid electric vehicles (HEVs), in which energy storage devices with large capacity and high …

Development Of Polymer-Based In-Plane Nanopore For Dna Sequencing, Zheng Jia

LSU Doctoral Dissertations

Mechanically robust solid-state nanopores have the potential to be the next generation DNA sensing platforms. However, mass production and limited base-calling accuracy are the hurdles for solid-state nanopore based DNA sensing. In order to solve these problems, a polymer dual-nanopore device fabricated via high throughput nanoimprint lithography (NIL) was proposed to sequence DNA by time-of-flight (ToF) measurement. As a proof of concept, this study presents mononucleotides discrimination via ToF measurement using polymer in-plane dual-nanopore device.

First, fabrication of polymer in-plane nanopore with controllable dimensions was studied in consideration of experimental conditions and materials selection. Then, surface charge density effect on …

Large Eddy Simulations Of Vertical Jets In Crossflow, Pranaya Pokharel

LSU Doctoral Dissertations

Jets in crossflow (JICF) have applications ranging from oil spill to film cooling of turbine blades. Hence, an understanding of the flow physics is important. The majority of the research has been conducted for low velocity ratios between jet and crossflow with round jets. JICF is demonstrated to behave differently for high velocity ratios and different jet shapes. Circular and rectangular jets are commonly used in aircraft applications. Current study focuses on high velocity ratio JICF issuing from both circular and rectangular exit.

For simulating JICF, an in house code “Chem3D” is used with Large Eddy Simulation (LES) to model …

Coupled Thermo Mechanical Modeling Of Friction Stir Welding And Fatigue Life Improvement Of Friction Stir Welding Structures, Saad Bin Aziz

LSU Doctoral Dissertations

Friction- stir- welding (FSW) is comparatively a new welding process invented by The Welding Institute in 1991. Since no melting or fusion occurs during the welding process, FSW is free of high heat input and solidification defects. Two main objectives have been set forth in this work. The first object of this thesis is to develop thermomechanical models based on experimental knowledge and understanding the FSW process at a fundamental level. The quality of friction-stir-welding (FSW) joints depends on many critical weld process parameters. The main challenge for the FSW is in the selection of these critical process parameters that …

Microstructural Characterization Of Shear Transformation Zones And Modeling Indentation Size Effect In Amorphous Polymers, Leila Malekmotiei

LSU Doctoral Dissertations

The first aim of this work is developing a procedure for experimental and analytical characterization of nano-scale microstructures which mediate large scale deformation in amorphous polymers. Glassy polymers are extensively used as high impact resistant, low density, and clear materials in industries. Nevertheless, their response under severe loading conditions is yet to be appropriately unraveled. Due to the lack of long-range order in the microstructures of glassy solids, their plastic deformation is different from that in crystalline solids. Shear Transformation Zones (STZs) are believed to be the main plasticity carriers in amorphous solids and defined as the localized atomic or …

Experimental, Analytical, And Numerical Evaluation Of The Mechanical Properties Of The Brain Tissue, Aref Samadidooki

LSU Doctoral Dissertations

A true understanding of the mechanisms behind most of the brain diseases is still out of reach. For several years, the interest of scientists has been focused on the genetic and biological causes, however, recent studies unraveled the importance of the biomechanics of the brain growth, folding, impact resistance, and deformation on its pathological conditions. While, a wide range of different methods have been used for characterization of the mechanical properties of the brain at the tissue level, the obtained results from different studies are extremely scattered and sometimes in contrast to one another. Since the brain tissue is extremely …

Formation Control Of Nonholonomic Multi-Agent Systems, Milad Khaledyan

LSU Doctoral Dissertations

This dissertation is concerned with the formation control problem of multiple agents modeled as nonholonomic wheeled mobile robots. Both kinematic and dynamic robot models are considered. Solutions are presented for a class of formation problems that include formation, maneuvering, and flocking. Graph theory and nonlinear systems theory are the key tools used in the design and stability analysis of the proposed control schemes. Simulation and/or experimental results are presented to illustrate the performance of the controllers.

In the first part, we present a leader-follower type solution to the formation maneuvering problem. The solution is based on the graph that models …

Developing Nanopore Electromechanical Sensors With Transverse Electrodes For The Study Of Nanoparticles/Biomolecules, Mohammadsadegh Beheshti

LSU Doctoral Dissertations

This study concerns development of a technology of utilizing metallic nanowires for a sensing element in nanofluidic single molecular (nanoparticle) sensors formed in plastic substrates to detect the translocation of single molecules through the nanochannel. We aimed to develop nanofluidic single molecular sensors in plastic substrates due to their scalability towards high through and low cost manufacturing for point-of-care applications. Despite significant research efforts recently on the technologies and applications of nanowires, using individual nanowires as electric sensing element in nanofluidic bioanalytic devices has not been realized yet. This dissertation work tackles several technical challenges involved in this development, which …

Microfluidic Technology And Application In Urinal Analysis, Jiwen Xiang

LSU Doctoral Dissertations

Microfluidic technology offers numerous advantages in minimizing and integrating the traditional assays. However, the lack of efficient control components of the microfluidic systems has been hindering the widely commercialization of the technology. The research work in this dissertation focused on the development of effective control components for microfluidic applications.

A linear peristaltic pump was firstly designed, fabricated, and tested for conventional microfluidics by synchronously compressing the microfluidic channel with a miniature cam-follower system in Chapter 2. The miniature cam-follower system and microfluidic chip was prototyped using three-dimensional (3D) printing technology and soft lithography technology. Results from experimental test showed that …