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Theses/Dissertations

LSU Doctoral Dissertations

Engineering

Wettability

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A Systematic Multiscale Investigation Of Nanoparticle-Assisted Co2 Enhanced Oil Recovery (Eor) Process For Shale Oil Reservoirs, Dayo A. Afekare Mar 2021

A Systematic Multiscale Investigation Of Nanoparticle-Assisted Co2 Enhanced Oil Recovery (Eor) Process For Shale Oil Reservoirs, Dayo A. Afekare

LSU Doctoral Dissertations

Shale oil reservoirs are prolific on the short term due to hydraulic fracturing and horizontal drilling but experience significant production decline, leading to poor ultimate recovery and leaving billions of barrels of oil buried in the ground. In this study, a systematic multi-scale investigation of an enhanced oil recovery (EOR) process using relatively inexpensive silicon dioxide nanoparticles and carbon dioxide for shale oil reservoirs was conducted. Using the Tuscaloosa Marine Shale (TMS) as a case study, aqueous dispersions of nanosilica in conjunction with CO2 were investigated at nano-to-core scales. At the nanoscale, atomic force microscope was used to investigate …


Investigation Of Flow Mechanisms In Gas-Assisted Gravity Drainage Process, Iskandar Dzulkarnain Aug 2018

Investigation Of Flow Mechanisms In Gas-Assisted Gravity Drainage Process, Iskandar Dzulkarnain

LSU Doctoral Dissertations

In this study we investigate displacement mechanism for oil recovered using Gas- Assisted Gravity Drainage (GAGD) method. For a typical oil recovery under gravity drainage, the recovery profile can be characterized by an initial bulk flow which occurs rapidly and a later film flow that extends for a longer duration. It is the latter period where film spreading, the ability of oil to spread above water in the presence of gas, is identified as the displacement mechanism responsible for recovering the remaining oil in gravity drainage process. Literature survey indicates that mathematical models for gravity drainage do not account for …


Investigation Of Flow Mechanisms In Gas-Assisted Gravity Drainage Process, Iskandar Dzulkarnain Aug 2018

Investigation Of Flow Mechanisms In Gas-Assisted Gravity Drainage Process, Iskandar Dzulkarnain

LSU Doctoral Dissertations

In this study we investigate displacement mechanism for oil recovered using Gas- Assisted Gravity Drainage (GAGD) method. For a typical oil recovery under gravity drainage, the recovery profile can be characterized by an initial bulk flow which occurs rapidly and a later film flow that extends for a longer duration. It is the latter period where film spreading, the ability of oil to spread above water in the presence of gas, is identified as the displacement mechanism responsible for recovering the remaining oil in gravity drainage process. Literature survey indicates that mathematical models for gravity drainage do not account for …


Pore-Scale And Conventional Wettability Measurement Considerations For Improving Certainty Of Geological Co2 Sequestration, Mohammad Jafari Jun 2018

Pore-Scale And Conventional Wettability Measurement Considerations For Improving Certainty Of Geological Co2 Sequestration, Mohammad Jafari

LSU Doctoral Dissertations

Parallel to the approach of developing zero-carbon-emission energies, other solutions have been recently proposed to decrease the amount of CO2 emissions into the atmosphere. Geological CO2 sequestration (GCS) has provided economic benefits and slight adverse environmental effects. GCS involves capturing CO2 from large producers, then injecting it into deep layers of the earth’s subsurface to be stored for hundreds to thousands of years. A safe and economic GCS requires a profound knowledge of immiscible CO2-water/brine fluid flow in CO2 storage sites including capillary pressure which has a barrier effect against leakage. The main uncertainty in measuring capillary pressure is due …


The Role Of Surface Active Compounds In Crude Oil On Reservoir Wettability., Paulina Metili Mwangi Jan 2017

The Role Of Surface Active Compounds In Crude Oil On Reservoir Wettability., Paulina Metili Mwangi

LSU Doctoral Dissertations

This study examines the role of crude oil’s surface active compounds (SAC) in determining the reservoir wettability. Wettability describes the relative preference of a reservoir rock for oil or water. Wettability influences the distribution of fluids in a reservoir and the efficiency of oil recovery methods. Unfortunately, the chemical mechanisms controlling wettability in individual reservoirs remain hazy. Wettability is conditional and is influenced by rock mineralogy, fluid chemistry, and temperature. An extensive experimental study was executed to understand the impact of naturally-occurring SACs typically found in crude oil, on the wettability of sandstone and carbonate rocks over a range of …


Effect Of Surfactants And Brine Salinity And Composition On Spreading, Wettability And Flow Behavior In Gas-Condensate Reservoirs, Yu Zheng Jan 2012

Effect Of Surfactants And Brine Salinity And Composition On Spreading, Wettability And Flow Behavior In Gas-Condensate Reservoirs, Yu Zheng

LSU Doctoral Dissertations

The well-known condensate blockage problem causes severe impairment of gas productivity as the flowing bottom-hole pressure falls below the dew point in gas-condensate reservoirs. Hence, this study attempts to investigate the concept of modifying the spreading coefficient and wettability using low-cost surfactants in the near wellbore region, to prevent the gas flow problems associated with condensate buildup. This study also examines the effect of brine salinity and composition on wettability, spreading and adhesion in condensate buildup regions, to evaluate the ability of brine salinity/composition for enhanced gas productivity in gas-condensate reservoirs. In this study, experiments were performed at both ambient …


Characterization Of Rock/Fluids Interactions At Reservoir Conditions, Dayanand Saini Jan 2010

Characterization Of Rock/Fluids Interactions At Reservoir Conditions, Dayanand Saini

LSU Doctoral Dissertations

In this study, interfacial phenomena of spreading, wettability, and rock/oil adhesion interactions in complex rock/oil/water systems were characterized at reservoir conditions of elevated pressures and temperatures. Capabilities of both ambient and reservoir condition optical cells were used for measuring the oil/water interfacial tension and dynamic (the water-receding and the water-advancing) contact angles for various complex rock/oil/water systems. Well known sessile oil drop volume alteration method was successfully used in this study for evaluating the applicability of the modified Young’s equation for characterizing the line tension in complex rock/oil/water systems at reservoir conditions. This appears to be first time when rock/fluids …


Flow And Distribution Of Water In Fractional Wettability Unsaturated Porous Media, Zaydoun Turkey Abusalem Jan 2007

Flow And Distribution Of Water In Fractional Wettability Unsaturated Porous Media, Zaydoun Turkey Abusalem

LSU Doctoral Dissertations

In recent years, interest in fluid flow and transport in the unsaturated zone has gained more attention, due to growing concerns that the quality of the subsurface environment is adversely affected by agricultural, industrial, and municipal activities. The wettability properties (e.g., water repellency) of soil in the unsaturated zone play an important role in determining fluid movement and ultimate distributions. A number of studies have shown that preferential flow and spatially variable moisture content is likely to occur in water repellant soils. Development of appropriate constitutive relations for numerical modeling becomes even more difficult in systems that contain water repellant …