Digital Commons Network^™

Molecular-Level Studies Of Nanopatterned Biomolecules With Atomic Force Microscopy, Ashley R. Walker

LSU Doctoral Dissertations

Atomic force microscopy (AFM) is an analytical technique in which a tipped probe is gently scanned across the surface in a raster pattern to generate digital images of a sample at the nanoscale. The AFM instrument has three general operational modes, which are contact, non-contact and tapping-mode, that can be used to examine materials at the atomic level. Single-molecular details of biological molecules and other soft organic materials can be captured with minimal denaturation in either ambient or liquid environments when using tapping-mode AFM. In tapping-mode, the probe is driven to oscillate vertically while the tip is scanned across the …

Comparing Editorial And Artificially Generated Fingerings: A Case Study, Lixi Qin

LSU Doctoral Dissertations

Fingering is crucial for piano performance. Unlike other instruments with relatively fixed fingerings, keyboard instruments offer countless fingering combinations. As musical styles have evolved, so too have the instruments themselves, resulting in a rich history of diverse fingering systems, which sometimes conflict with one another. Moreover, due to individual differences in hand shape and size, the fingering advice from editors or teachers may not be universally applicable, and there is a lack of an objective, unified standard for validating these recommendations.

For students who do not fully understand fingering principles and have not been exposed to a wide range of …

An Analysis Of William Bolcom's "Three Classical Rags", Thomas A. Owens

LSU Doctoral Dissertations

This document aims to provide insight into William Bolcom’s Three Classical Rags through harmonic and formal analysis of each rag, investigating the ways in which they fulfill or subvert the expectations of ragtime. The study begins with a description of the harmonic language, form, and metric structure typical of ragtime composers like Scott Joplin and Joseph Lamb. Examples of rags that maintain these characteristics are The Entertainer by Joplin, Heliotrope Bouquet by Louis Chauvin and Joplin, and Top Liner Rag by Lamb. Analysis of Bolcom’s Three Classical Rags ensues, exploring the ways they both honor and subvert the expectations …

Preserving The Historic And Cultural Music Of Louisiana Through School Music: An Ethnographic Case Study, Christopher S. Song

LSU Doctoral Dissertations

The purpose of this ethnographic case study was to examine the lives of teachers, students, community members, and culture bearers within a musical community located in South Central Louisiana. The geographic area of focus in this research was Vermilion Parish and its surrounding area, known as Acadiana, the heart of Creole and Cajun culture where Traditional Louisiana Music finds its origins. Participants’ intrinsic cultural understandings of Louisiana’s music and impact on school music programs was examined through ethnographic interview and observation. A resource pedagogy known as funds of knowledge was used as a theoretical framework meant to maintain participants’ intrinsic …

Scaling The Wall: Math Attitudes And Mindsets Of Middle School High-Achievers, Stephanie R. Gullage

LSU Doctoral Dissertations

This intrinsic case study examined groups of gifted and high achieving middle school mathematics students in one school’s advanced and honors program. The purpose of this study was to determine how the students view themselves in light of noncognitive constructs, how they regard and apply those constructs in their mathematics studies, how the work of those constructs can affect their attitudes toward mathematics, and how they believe educators can help foster success in math via noncognitive factors. The researcher employed a questionnaire, observations, focus group interviews, and interviews with key informants to gather study data. With the theoretical lenses of …

Sexual Abuse: A Multi-Faceted Problem, Marcus Venable

LSU Doctoral Dissertations

On average, US citizens have experienced approximately 400,000 sexual assaults per year, which results in enormous immediate and long-term consequences for individuals, as well as society in general.

In the U.S., the principal method of combatting this crime has been the creation of Sex Offender Registries used to notify the public of the identity and location of convicted sex offenders who may be living in proximity to their residence. In addition to the Registry, laws have been passed forbidding convicted sex offenders from residing within buffer zones around areas of high child concentration [schools/parks/etc.].

The efficacy and consequences of these …

The Influence Of Stage Of Ripeness On Consumer Perceptions Regarding Selected Aspects Of Non-Astringent Asian Persimmons (Diospyros Kaki Thunb), Robert A. Mirabello Jr

LSU Doctoral Dissertations

Asian Persimmon (Diospyros kaki Thunb.) is an important fruit crop in Asia and in recent decades has experienced expanding production around the world. Non-astringent cultivars are highly desirable in world markets. In the United States the Asian Persimmon is lesser known and consumed although it can be successfully grown in California and the Southeastern United States.This novel study examined the physical/chemical properties of the non-astringent Asian Persimmon ‘Jiro’ grown in Southern Louisiana at three distinct stages of ripeness described as Green (mid-September harvest), Light Orange (mid-October harvest) and Dark Orange (mid-November harvest). Data collected included color, weight, size, soluble …

Pregnant Black Bodies In Peril: A Multi-Method Analysis Of Obstetric Outcomes And Gestational Experiences, Courtney E. Williams

LSU Doctoral Dissertations

My multi-method three-paper dissertation provides a better understanding of the relationship between maternal racial identity, obstetric outcomes, and gestational experiences. Using birth certificate data from the 2016 U.S. National Vital Statistics System and binary logistic regression models, in the first paper I explore heterogeneity in severe maternal morbidity (SMM) by maternal race, maternal education, and maternal age. To complement the first paper, in the second paper I allow 35 Black and White women/birthing people to describe pregnancy, birth, and early motherhood in their own words. I situate the Covid-19 pandemic as a unique cultural backdrop in this qualitative paper to …

Learning Proximal Operators With Gaussian Process And Adaptive Quantization In Distributed Optimization, Aldo Duarte Vera Tudela

LSU Doctoral Dissertations

In networks consisting of agents communicating with a central coordinator and working together to solve a global optimization problem in a distributed manner, the agents are often required to solve private proximal minimization subproblems. Such a setting often requires a further decomposition method to solve the global distributed problem, resulting in extensive communication overhead. In networks where communication is expensive, it is crucial to reduce the communication overhead of the distributed optimization scheme. Integrating Gaussian processes (GP) as a learning component to the Alternating Direction Method of Multipliers (ADMM) has proven effective in learning each agent's local proximal operator to …

Decay Spectroscopy Of 134sb Using X-Array And Saturn, Graeme E. Morgan

LSU Doctoral Dissertations

The ground-state decay of ¹³⁴Sb is reported by the current evaluated nuclear data to be dominated by a 0^-→0⁺ first-forbidden Gamow-Teller transition to the ground state of ¹³⁴Te. In 2013, a recoil-ion time-of-flight (RI-TOF) spectroscopy measurement of ¹³⁴Sb with the Beta-decay Paul Trap (BPT) indicated that the ground-state feeding of ¹³⁴Te is weaker than reported. Simulation work of ¹³⁴Sb ground-state decays replicated the RI-TOF results with the addition of a theorised 5-MeV state that was fed with ~17% of the total β-decay strength. To search for higher energy states and transitions that …

It’S Britney, Bitch, Mary Hyepock

LSU Doctoral Dissertations

This dissertation engages public rhetorics surrounding pop princess Britney Spears as a case study for examining the rhetoricity of bodily autonomy. Bodily autonomy is commonly understood as the legal right to control what happens to one’s body without external influence or coercion. However, one’s legal access to bodily autonomy is produced, negotiated, and maintained through discourse. In other words, one’s access to so-called “ownership” over their body and agency to make decisions about it is deeply tied to the gendered and racialized symbolic production of citizenship in the United States. Utilizing a reproductive justice framework, I investigate how Britney Spears’ …

Vibrato Rate And Extent In The Baritone Voice Through The Twentieth And Early Twenty-First Century, Scott Purcell

LSU Doctoral Dissertations

Observations of vibrato rate and extent through the twentieth and early twenty-first century point to an overall decrease in rate and increase in extent. This descriptive analysis studied fifty-five randomly selected recordings of professional operatic baritones, five from each decade from 1910 to 2021, and analyzed their vibrato rate and extent with VoceVista Video Pro. Results showed a consistent decrease in mean vibrato rate from 1910 to 1960, with small increases and decreases from 1960-2021. Vibrato extent was less consistent, but still increased from 1910-2021. The mean vibrato rate was 5.84 Herz (Hz), with a coefficient of variation (CV) of …

An Analysis Of The Musical Gestures In Osvaldo Golijov’S The Dreams And Prayers Of Isaac The Blind And Their Relationship To The Kabbalah Sefirot, Jeremy Gdaniec

LSU Doctoral Dissertations

Osvlado Golijov’s The Dreams and Prayers of Isaac the Blind, scored for klezmer clarinet and string quartet, remains one of his most influential works since its premier in 1994. Inspiration for the work came from the writings of Rabbi Isaac the Blind, a prominent 13^th century figurehead in the branch of Jewish mysticism known as Kabbalah. In Kabbalah, symbols known as the sefirot are emanations of creation and the key to unlocking the divine secrets of the God-head. The analysis presented in this document combines musical gesture theory with Kabbalistic concepts for new perspectives on Golijov’s …

Molybdenum Alkylidyne Complexes With Phenoxide Ligands For Alkyne Metathesis, Marvin L. Stewart Jr

LSU Doctoral Dissertations

Abstract

Alkyne metathesis is a powerful synthetic tool, which provides easy access to complex organic molecules in a single-step. It is a dynamic covalent reaction that scrambles alkynes, carbon-carbon triple bonds (C≡C). Molybdenum- or tungsten-alkylidyne (Mo≡C, W≡C) complexes are typically used as catalyst to cleave and reform alkyne bonds. Our goal has been to gain a deeper understanding of the intrinsic differences between functional ligands by the development of novel phenoxide ligands.

In chapter 2 we explore the detailed synthesis of novel phenoxide podand ligands in an effort to identify their mo-alkylidyne complexes. We were able to synthesize a variety …

The Lowest Discriminant Ideal Of Cayley-Hamilton Hopf Algebras, Zhongkai Mi

LSU Doctoral Dissertations

Discriminant ideals are defined for an algebra R with central subalgebra C and trace tr : R → C. They are indexed by positive integers and more general than discriminants. Usually R is required to be a finite module over C. Unlike the abundace of work on discriminants, there is hardly any literature on discriminant ideals. The levels of discriminant ideals relate to the sums of squares of dimensions of irreducible modules over maximal ideals of C containing these discriminant ideals. We study the lowest level when R is a Cayley-Hamilton Hopf algebra, i.e. C is also a Hopf subalgebra, …

Ammonium Chemotaxis In Chlamydomonas Reinhardtii, Gabela Nelson

LSU Doctoral Dissertations

Analysis of ammonium chemotaxis in Chlamydomonas reinhardtii is largely hindered, compared to that of phototaxis, despite equal importance on flagellated microalgal physiology. A major contribution of this shortfall is the lack of proper assay method. We developed a simple Petri dish assay method in which light is homogenously exposed while patterns of the cellular migration are tracked with a function of time. Using the method, new findings were revealed. First, this research presented that a strain lacking the eyespot organelle required for light gradient-sensing exhibits similar chemotactic behavior compared to a wild-type strain, suggesting Chlamydomonas sense an ammonium gradient not …

Research On 3d Printing Resin Exposure Properties And Its Application On Centrifugal Microfluidic Platform Based On Fluorescence Detection, Zheng Qiao

LSU Doctoral Dissertations

This dissertation encapsulates significant advancements in the field of SLA 3D printing and centrifugal microfluidics. Central to the research is the development of a novel mathematical model for predicting trapped resin thickness in SLA 3D printing, a groundbreaking contribution that addresses a critical aspect of printing intricate structures. This model, the first to establish a mathematical relationship for resin thickness, is rooted in a comprehensive study of the resin curing process. The research leverages the concept of 'critical dosage' for resin curing, leading to a more refined and theoretically grounded approach for calculating curing thickness. Experimentation further validates the model, …

Seeking A Uniform Approach To Trumpet Sound Concept, Coleman T. Scott

LSU Doctoral Dissertations

One of the most challenging aspects of trumpet playing that pedagogues must teach is how to produce a professional tone. Trumpet students are often good musicians, play correct notes and rhythms, and even have proficient technique. However, many are unable to consistently produce a tone comparable to that of a professional. There are a number of methods that can be utilized to improve a student’s tone quality. In my own teaching and in the teaching of many professionals, tone concept has been used as a catalyst for the improvement of tone quality. A students’ exposure to a professional-quality trumpet tone …

All-Optical Probes Of Particle-Like Charge Migration Dynamics, Kyle A. Hamer

LSU Doctoral Dissertations

Particle-like charge migration (CM) is the coherent, back-and-forth motion of a positively-charged electron hole along the backbone of a molecule following a sudden ionization. CM in small molecules generally occurs on an Angstrom (10^-10 m) spatial scale and an attosecond (10^-18 s) timescale. I use time-dependent density-functional theory (TDDFT) to simulate CM modes in organic molecules, and to explore all-optical probes of this attosecond electron dynamics using high-harmonic spectroscopy (HHS). By leveraging my results from previous studies of two-center interferences in carbon dichalcogens, in which I separated the harmonic signal into contributions from individual Kohn-Sham orbitals, I first …

A Study Of Selected Vocal Works By Shande Ding: The Mysterious Sound Of Flute And Poems On Western Yunnan, Chuyan Luo

LSU Doctoral Dissertations

This study aims to delve into and interpret “The Mysterious Sound of Flute” and “Poems on Western Yunnan” from a singer’s perspective while also providing guidance and recommendations for other performers. The research encompasses the history of Chinese art songs, a biography of Shande Ding, and an introduction to his compositional style. A comprehensive examination of each song includes background information, song analysis, translation, a Chinese lyric diction guide, and performance suggestions.

Art songs constitute a significant genre in music composition, and Chinese art songs have yielded numerous outstanding composers and captivating works over the years. Among these composers, Shande …

Spatial Behavior Of Hospital Visits By Hand, Foot, And Mouth Disease Patients In Nanchang, China, Zeliu Zheng

LSU Doctoral Dissertations

Hand foot mouth disease (HFMD) is one of the widespread transmissible diseases that target preschool children, especially in urban regions in East Asia. Understanding the travel patterns of the HFMD patients helps us understand how the spatial behaviors of patients vary across space and what are the underlying forces. It is essential for understanding the healthcare market and planning for resource allocation. Foremost, health behavior and outcome change significantly across geographic regions of various urbanicities (i.e., degrees of urbanization) due to the uneven distribution of healthcare resource. In addition, health studies in the U.S. often use hospital service areas (HSAs) …

Soundscape - A Guided Approach To Post-Tonal Horn Repertoire, Selena B. Boyda

LSU Doctoral Dissertations

More modern post-tonal works are being composed and it is imperative that horn players interpret the music as accurately as possible. Analyzing the music is a way one can interpret the music accurately. The purpose of this research is to develop a guided approach for interpretation of post-tonal horn repertoire using analytical techniques. Selected works analyzed and used are Olivier Messiaen’s “Appel Interstellaire,” Stanley Friedman’s Topanga Variations, and Jenni Brandon’s Dawn. Analytical techniques used include set theory, limited modes of transposition, contour relations, motivic patterns, modal analysis, and motifs.

Finite Monodromy And Artin Representations, Emma Lien

LSU Doctoral Dissertations

Artin representations, which are complex representations of finite Galois groups, appear in many contexts in number theory. The Langlands program predicts that Galois representations like these should arise from automorphic representations and many examples of this correspondence have been found such as in the proof of Fermat's Last Theorem. This dissertation aims to make an analysis of explicitly computable examples of Artin representations from both sides of this correspondence. On the automorphic side, certain weight 1 modular forms have been shown to be related to Artin representations and an explicit analysis of their Fourier coefficients allows us to identify the …

Reducibility Of Schrödinger Operators On Multilayer Graphs, Jorge Villalobos Alvarado

LSU Doctoral Dissertations

A local defect in an atomic structure can engender embedded eigenvalues when the associated Schrödinger operator is either block reducible or Fermi reducible, and having multilayer structures appears to be typically necessary for obtaining such types of reducibility. Discrete and quantum graph models are commonly used in this context as they often capture the relevant features of the physical system in consideration.

This dissertation lays out the framework for studying different types of multilayer discrete and quantum graphs that enjoy block or Fermi reducibility. Schrödinger operators with both electric and magnetic potentials are considered. We go on to construct a …

Race And Racism Through The Lens Of Black Men: Exploring The Talk And Lessons Black Fathers Teach Their Children About Race And Racism In America., Conial C. Caldwell Jr

LSU Doctoral Dissertations

The history of racism and racial violence is embedded in the fabric of America and has driven Black people to develop strategies to navigate society that racism has produced. “The Talk” is a racial socialization practice and cultural phenomenon that has existed within Black families for centuries and remains a necessity due to the ongoing acts of racism and violence of Black Americans. Prior research has found that parents rear their children based on their own lived experiences, which many Black Americans have experienced or have been exposed to racism and racial violence. Yet, there are few empirical studies that …

Assessment Of Engineering Performance And Environmental Impacts Of High Reclaimed Asphalt Pavement (Rap) Asphalt Mixtures In Flexible Pavements, Ibrahim A.I.E. Elnaml

LSU Doctoral Dissertations

Due to the critical role of asphalt pavements in national infrastructure development, there is a pressing need to investigate more sustainable materials and approaches. The use of natural aggregates and asphalt binders in asphalt pavement presents sustainability challenges due to the depletion of finite resources. Recycling Asphalt Pavement (RAP) offers a promising sustainable solution by substituting virgin aggregates and asphalt binders with recycled ones. However, increasing RAP contents in asphalt mixtures (>25%) can lead to premature cracking, insufficient durability, and limited longevity due to the presence of aged RAP-asphalt binder. To address these concerns, the application of novel recycling …

City Boy By Judd Greenstein: A Transcription From Chamber Quintet To Full Wind Band, Emmanuel Rodriguez

LSU Doctoral Dissertations

The goal of this project is to create a wind band transcription of the chamber work City Boy by Judd Greenstein. Greenstein describes his own music as being “built on contrasts and juxtapositions between the jittery, competing pulses of the New York City streets where he grew up and the placid landscapes of the rural farm land he now calls home.”1 His music is also influenced by his passion for contemporary popular music genres, specifically hip-hop and rap. This duality is a major aspect of Greenstein’s musical language, which he describes as “a genre- fluid musical infrastructures that endeavors to …

Round Ii: Exploring The Experiences Of Black, First-Generation Graduate And Professional Students At Historically Black Colleges And Universities (Hbcus), Derrick D. Lathan

LSU Doctoral Dissertations

This phenomenological study explores the experiences of Black, first-generation (first-gen) students pursuing advanced degrees at historically Black colleges and universities (HBCUs), following the COVID-19 pandemic and racial justice movements like Black Lives Matter. Additionally, this study examines the present-day motivations to pursue advanced degrees, particularly the benefits of doing so at an HBCU. The main research question guiding this study is: What are the experiences of Black, first-gen graduate and professional students at historically Black colleges and universities (HBCUs)? The sub-questions are:

1. How do Black, first-gen graduate and professional students describe being a first-gen student?
2. What barriers and supports impact …

Introducing Chinese Folk Songs Through Arrangements For Trombone & Piano And Chamber Music, Tianyu Xue

LSU Doctoral Dissertations

The scarcity of trombone in traditional Chinese music reflects the limited exposure and education for the trombone in China. Additionally, Chinese folk songs have minimal presence on the global stage. This project will bridge this gap by developing a series of trombone pieces that incorporate Chinese musical elements, explicitly focusing on elevating Chinese folk songs through trombone performance. This initiative offers an opportunity for trombonists worldwide to delve into the richness of Chinese folk music. The core of this work involves selecting Chinese folk songs that represent diverse historical contexts, regional characteristics, and emotional content and then arranging them for …

“Redención”: Testimonios Of Latinas Who Chose To Leave The Higher Education Industry, Delia P. Madrid-Nothdurft

LSU Doctoral Dissertations

Using the methodological framework of testimonio, this study was an exploration of the experiences of former higher education professionals who identify as women in the Latinx community. Grounded in Latino Critical Theory (LatCrit) and Critical Race Feminism (CRF), this research aims to highlight the narratives of Latina professionals who have separated from the higher education sector. The study is informed by the conceptual framework of Chicana feminist perspective, which contextualizes the analysis of these experiences within a socio-cultural context. Using semi-structured interviews, participants shared their testimonios, providing rich accounts of their journeys and challenges within higher education. Through thematic …