Digital Commons Network^™

Assessment Of Corn Stover Torrefaction On-Farm Biochar Production, Christina M. Gerometta

Electronic Theses and Dissertations

Torrefaction is a thermochemical pretreatment process that is typically achieved by slowly heating biomass (<50°C/min) within the temperature range of 200 – 300°C under an inert atmosphere. This process yields a storable solid product with enhanced fuel characteristics that are influenced by the ligno-cellulosic composition of the original feedstock and the imposed torrefaction conditions (time and temperature). This study is an assessment of corn stover properties that are relevant for designing an on-farm torrefaction system. The first portion of this study compared the thermal decomposition behaviors of corn stover fractions (leaf, stalk, cob) to the respective ligno-cellulosic composition using thermo-gravimetric analysis. It was found that the thermal decomposition pattern correlates to the structure and ratio of ligno-cellulosic polymers and provides design guidelines for an on-farm torrefaction system capable of handling large quantities of mixed fraction stover. The second part of this study investigated the effects of torrefaction time and temperature on the mass and energy yield of mixed fraction corn stover using a 46.3 L batch style reactor. It was found that longer reaction times and higher temperatures were required to obtain mass and energy yields similar to those found using lab-scale reactors and finely milled samples. Non-uniform torrefaction occurred between fractions due to chemical composition of each fraction and proximity to the heating elements.