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Structure, Stability, Vibrational, Thermodynamic, And Catalytic Properties Of Metal Nanostructures: Size, Shape, Support, And Adsorbate Effects, Farzad Behafarid
Structure, Stability, Vibrational, Thermodynamic, And Catalytic Properties Of Metal Nanostructures: Size, Shape, Support, And Adsorbate Effects, Farzad Behafarid
Electronic Theses and Dissertations
Recent advances in nanoscience and technology have provided the scientific community with new exciting opportunities to rationally design and fabricate materials at the nanometer scale with drastically different properties as compared to their bulk counterparts. A variety of challenges related to nanoparticle (NP) synthesis and materials characterization have been tackled , allowing us to make more homogenous, well defined, size- and shape-selected NPs, and to probe deeper and more comprehensively into their distinct properties. In this dissertation, a variety of phenomena relevant to nanosized materials are investigated, including the thermal stability of NPs and coarsening phenomena in different environments, the …
Agglomeration, Evaporation And Morphological Changes In Droplets With Nanosilica And Nanoalumina Suspensions In An Acoustic Field, Erick Tijerino
Agglomeration, Evaporation And Morphological Changes In Droplets With Nanosilica And Nanoalumina Suspensions In An Acoustic Field, Erick Tijerino
Electronic Theses and Dissertations
Acoustic levitation permits the study of droplet dynamics without the effects of surface interactions present in other techniques such as pendant droplet methods. Despite the complexities of the interactions of the acoustic field with the suspended droplet, acoustic levitation provides distinct advantages of controlling morphology of droplets with nanosuspensions post precipitation. Droplet morphology is controlled by vaporization, deformation and agglomeration of nanoparticles, and therefore their respective timescales are important to control the final shape. The balance of forces acting on the droplet, such as the acoustic pressure and surface tension, determine the geometry of the levitated droplet. Thus, the morphology …