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Wright State University

2018

Materials Science

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Fabrication And Characterizations Of Lithium Aluminum Titanate Phosphate Solid Electrolytes For Li-Based Batteries, Anurag Yaddanapudi Jan 2018

Fabrication And Characterizations Of Lithium Aluminum Titanate Phosphate Solid Electrolytes For Li-Based Batteries, Anurag Yaddanapudi

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Demands for electric vehicles and flexible electronics have escalated research in developing high-performance lithium batteries based on solid-state chemistry. The present work is to develop highly-conductive and flexible solid electrolyte for such applications. Lithium aluminum titanate phosphate (LATP or Li1.3Al0.3Ti1.7(PO4)3), both in ceramic pellets and free-standing composite membranes, have been fabricated. The crystal structure, surface morphology, and ionic conductivity are systematically studied. LATP pellets are prepared using solid state reaction approach. The results indicate that calcine temperature has significant impacts on the phase impurity and sintering temperature and duration have more impacts on the grain size and porosity of LATP …


Constitutive Modeling Of Creep In Leaded And Lead-Free Solder Alloys Using Constant Strain Rate Tensile Testing, Eric Thomas Stang Jan 2018

Constitutive Modeling Of Creep In Leaded And Lead-Free Solder Alloys Using Constant Strain Rate Tensile Testing, Eric Thomas Stang

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Environmental and safety concerns have necessitated a phase-out of lead-based alloys, which are often used in electronics solder applications. In order to properly assess suitable replacement materials, it is necessary to understand the deformation mechanisms relevant to the application. In the case of electronics solder, creep is an important mechanism that must be considered in the design of reliable devices and systems. In this study, Power-Law and Garofalo constitutive creep models were derived for two medium temperature solder alloys. The first alloy is known by the commercial name Indalloy 236 and is a quaternary alloy of lead, antimony, tin, and …


Microstructural Characterization Of LensTm Ti-6al-4v: Investigating The Effects Of Process Variables Across Multiple Deposit Geometries, Laura Christine Davidson Jan 2018

Microstructural Characterization Of LensTm Ti-6al-4v: Investigating The Effects Of Process Variables Across Multiple Deposit Geometries, Laura Christine Davidson

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Laser based additive manufacturing of Ti-6Al-4V components is under consideration for aerospace applications. The mechanical properties of the finished components depend on their microstructure. Process mapping compares process variables such as heat source power, heat source travel speed, material feed rate, part preheat temperature and feature geometry to process outcomes such as microstructure, melt pool geometry and residual stresses. In this work, the microstructure of two-dimensional pads, multilayer pads, thin walls, and structural components at the steady state location was observed. A method for measuring β grain widths that allows for the calculation of standard deviations, confidence intervals, and variances …