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Research Progress On Design Strategies, Synthesis And Performance Of Limn2o4-Based Cathodes, Fangxin Mao, Wei Dong Guo, Jianmin Ma Jan 2015

Research Progress On Design Strategies, Synthesis And Performance Of Limn2o4-Based Cathodes, Fangxin Mao, Wei Dong Guo, Jianmin Ma

Australian Institute for Innovative Materials - Papers

Spinel LiMn2O4 (LMO)-based composites, due to their combination of low toxicity, abundant natural resources, and excellent electrochemical performance, are regarded as promising candidate cathode materials for lithium ion batteries. Current energy storage demands are not being met with existing materials, however, because of their defects, such as fast capacity fading, low rate capability, and low specific capacity in practical applications. Manganese dissolution during electrochemical processes bears the major responsibility for capacity loss, apart from the electrolyte factor. Low electrical conductivity, low ionic diffusion efficiency, and large structural variation have adverse effects on the electrochemical performance of materials. With respect to …