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Electrocatalytic Reduction Of Carbon Dioxide By Cobalt-Phthalocyanine-Incorporated Polypyrrole, Jun Chen, Gordon G. Wallace, Jiaxing Lu, Aijian Zhang, Weimin Zhang
Electrocatalytic Reduction Of Carbon Dioxide By Cobalt-Phthalocyanine-Incorporated Polypyrrole, Jun Chen, Gordon G. Wallace, Jiaxing Lu, Aijian Zhang, Weimin Zhang
Faculty of Science - Papers (Archive)
In the quest for catalysts for the electrocatalytic reduction of , a cobalt phthalocyanine/polypyrrole (CoPc/PPy) composite electrode has been developed. The electrode is prepared by drop casting CoPc onto the PPy film from the CoPc/tetrahydrofuran solution (1 mg/mL). The onset potential for reduction occurred at potentials 160 mV more positive than observed with a simple PPy electrode. Furthermore, in the potentiostatic electrolysis, the catalytic current for reduction at CoPc/PPy was very stable, with a higher current density and current efficiency when compared to the PPy electrode.
Carbon-Nanotube Biofiber Microelectrodes, Carol M. Lynam, Gordon G. Wallace, Willo Grosse
Carbon-Nanotube Biofiber Microelectrodes, Carol M. Lynam, Gordon G. Wallace, Willo Grosse
Faculty of Science - Papers (Archive)
All-biocompatible carbon-nanotube fibers were formed using wet spinning. In this process the spinning solutions used are carbon nanotubes dispersed using biomolecules such as hyaluronic acid and chitosan. We compare the effect of a coagulation bath containing either a polymer binder, e.g., polyethyleneimine, or simply a precipitating solvent system, e.g., acetone. The electrical, mechanical, and morphological properties of the resulting fibers were studied. Biocompatible electrode structures were generated suitable for a variety of biomedical applications, e.g.,in biosensors or in systems where the application of an electrical field is advantageous e.g., stimulation of electrically excitable cells such as nerve and muscle cells.
Evaporation And Carbon Dioxide Exchange By Sugar Cane Crops, G Bryant, Travis A. Naylor, Stephen R. Wilson, O T Denmead, David W. Griffith, B.C.T. Macdonald, I. White
Evaporation And Carbon Dioxide Exchange By Sugar Cane Crops, G Bryant, Travis A. Naylor, Stephen R. Wilson, O T Denmead, David W. Griffith, B.C.T. Macdonald, I. White
Faculty of Science - Papers (Archive)
RECENT developments in water and carbon trading and biofuel production highlight the need to document the water and carbon balances of Australia’s cropping systems including sugarcane. This paper presents the results of studies of evaporation and CO2 exchange throughout the growing seasons of two sugarcane crops, a 1st ratoon crop at Murwillumbah where burnt-cane was practised and a 5th ratoon crop at Mackay where trash blanketing was employed. At both locations, a micrometeorological eddy covariance technique was employed to measure water vapour and CO2 exchange between crop and atmosphere and manual and automatic chambers to measure CO2 emission from the …
Towards Novel Entangled Carbon Nanotube Composite Electrodes, Gordon G. Wallace, P. Sherrell, J. Chen, A. Minett
Towards Novel Entangled Carbon Nanotube Composite Electrodes, Gordon G. Wallace, P. Sherrell, J. Chen, A. Minett
Faculty of Science - Papers (Archive)
The commercialization of carbon nanotube electrodes is impeded by the lack of bulk processing techniques. One approach to overcome this impediment is the growth of macroscopic CNT composite architectures which do not require any extra processing. Unfortunately the fundamental growth mechanisms of these carbon composites is not currently understood. To probe this mechanism a systematic examination of the effect of certain growth parameters was undertaken. Within this paper we present the promising preliminary findings of this study revealing extremely complex relationships between variables during growth. We also present the performance of the produced architectures as capacitor electrodes and the further …
Development And Application Of A System For The Analysis Of Atmospheric, Water And Sediment Nitrogen And Carbon, Ann Stavert, Stephen R. Wilson, Dianne F. Jolley
Development And Application Of A System For The Analysis Of Atmospheric, Water And Sediment Nitrogen And Carbon, Ann Stavert, Stephen R. Wilson, Dianne F. Jolley
Faculty of Science - Papers (Archive)
Eutrophication and climate change, key environmental concerns, are both linked to the carbon and nitrogen cycles hence the improved understanding of these cycles is essential. Currently, there is no system that simultaneously measures the fluxes of the three key gas phase products of nitrogen and carbon cycling (CO2, CH4 and N2O) in submerged ecosystems with hourly time resolution. A “Lake-in-a-box” (mesocosm) was developed in the laboratory which allowed the monitoring of key components of the carbon and nitrogen cycles within the air, water and sediments. The approach is automated, simple and time efficient and novel in its ability to examine …