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University of Texas Rio Grande Valley

2017

Health and environmental sciences

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Remediation Of Lead And Copper Ions From Water Solutions Using Transition Metal Sulfides, Jesus M. Cantu Jr. Dec 2017

Remediation Of Lead And Copper Ions From Water Solutions Using Transition Metal Sulfides, Jesus M. Cantu Jr.

Theses and Dissertations

Heavy metal contamination in water solutions has been a major concern since many transition metals don’t play a role in any biological function and are actually detrimental to human health. There have been several techniques that have been implemented for the remediation of heavy metal contaminants. For this project, three metal sulfides—Fe7S8, ZnS, TiS 2—were synthesized and studied for their capabilities to remove Pb(II) and Cu(II) from water solutions. Several parameters were investigated to determine the effects of pH, time, temperature, binding capacities, and interfering ions. The room temperature adsorption capacities ranged 6.23–333.3 mg/g for Pb(II) and 1.31–250 mg/g for …


Removal Of Lead And Arsenic From Aqueous Solution By Biochar Produced From Locally-Sourced Biomass, Sergio I. Mireles Jul 2017

Removal Of Lead And Arsenic From Aqueous Solution By Biochar Produced From Locally-Sourced Biomass, Sergio I. Mireles

Theses and Dissertations

This study evaluated the effectiveness of four adsorbent materials, pyrolyzed corn stover, orange peel, pistachio shell, and magnetic biochar for their ability to adsorb lead (Pb) and arsenic (As III, As V) from aqueous solution. An increase in adsorption was seen as the pH of the solution increased from pH 2 to pH 6. Magnetic orange peel biochar with Fe3O4 particles precipitated on the surface of biochar was synthetized by co-precipitation and used for arsenic adsorption. Initial pH value had an influence on the adsorption behavior of As (III) and As (V). In the pH range of 2–6, As (V) …