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University of Texas Rio Grande Valley

Theses and Dissertations

Theses/Dissertations

2021

Forcespinning

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Production And Characterization Of Polyurethane Fibers By Forcespinning Method And Incorporation Of Luminiscense Nanoparticles, Sunanda Kumar Saha Aug 2021

Production And Characterization Of Polyurethane Fibers By Forcespinning Method And Incorporation Of Luminiscense Nanoparticles, Sunanda Kumar Saha

Theses and Dissertations

In this work, Polyurethane (PU) fine fiber nonwoven mats are generated using the Forcespinning® method. A detailed study focusing on the effect of PU concentration within solutions of N, N Dimethylformamide and the effect of relative humidity (RH) on fiber average diameter and fiber yield is presented. Solutions were prepared with 4 different concentrations, 14, 15, 16 and 17 wt% of PU. It was observed that as concentration of PU increases, average diameter shows a tendency to increase. Production of fibers with RH varying from X to X was analyzed. It was shown that higher RH is convenient for PU …


Exploration Of Antimicrobial And Cell Proliferation Properties Of Nanofibers Incorporating Nopal (O. Cochenillifera) Extract, Cristobal Rodriguez May 2021

Exploration Of Antimicrobial And Cell Proliferation Properties Of Nanofibers Incorporating Nopal (O. Cochenillifera) Extract, Cristobal Rodriguez

Theses and Dissertations

This study focused on the fabrication of Forcespinning® nanofibers composed of Opuntia cochenillifera, ‘nopal’, mucilage (N) extract, chitosan (CH), and pullulan (PL) (N/CH/PL) were developed with an optimum fiber average diameter of 406±127 nm, and studied for their ability to sustain adhesion and proliferation of mouse embryonic fibroblast (NIH 3T3) cells. After a 6-day incubation period, N/CH/PL nanofibers displayed robust cell proliferation, while also exhibiting inhibitory properties through an N extract dip-coating process against gram-negative bacteria Escherichia coli in a 24 h bacterial growth study. A demonstration of integrated natural bioactive compounds with combined biodegradable polymers, provide an enhanced …


Development And Characterization Of Nanofiber-Based Thermoelectric And Piezoelectric Composites, Julio Enrique Trevino May 2021

Development And Characterization Of Nanofiber-Based Thermoelectric And Piezoelectric Composites, Julio Enrique Trevino

Theses and Dissertations

This study focuses on the development and characterization of nanofiber-based composites with the goal of developing flexible, lightweight, and cost effective thermoelectric and piezoelectric devices. The following materials were used in the development of the composites: polyvinylidene fluoride (PVDF) with polyaniline (PANI), polypyrrole (PPY), polyindole (PIN), polyanthranilic acid (PANA), polycarbazole (PCZ), polyacrylonitrile (PAN), functionalized multi-walled carbon nanotubes (MWCNT-COOH), and camphorsulfonic acid (CSA). Blends and in-situ polymerization techniques were utilized to increase the desired thermoelectric/piezoelectric response. Nanofiber systems were produced utilizing the Forcespinning® technique. The morphology, structure, electrochemical, thermal stability, thermoelectric, and piezoelectric performance was analyzed. All of the nanofiber PVDF/CP …