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Observation Of Fano Asymmetry In Raman Spectra Of Srtio3 And Cax Sr1-Xtio3 Perovskite Nanocubes, Sarbajit Banerjee, Dae In Kim, Richard D. Robinson, Irving P. Herman, Yuanbing Mao, Stanislaus S. Wong
Observation Of Fano Asymmetry In Raman Spectra Of Srtio3 And Cax Sr1-Xtio3 Perovskite Nanocubes, Sarbajit Banerjee, Dae In Kim, Richard D. Robinson, Irving P. Herman, Yuanbing Mao, Stanislaus S. Wong
Chemistry Faculty Publications and Presentations
Bulk SrTi O3 is cubic and not expected to exhibit any first-order Raman scattering. However, nanocubes of SrTi O3 with an edge length of 80±10 nm show strong first-order Raman scattering originating from the breaking of symmetry caused by frozen surface dipoles (local tetragonality) and the presence of nanoscopic polar domains (arising from incorporated impurities). Rapid polarization fluctuations within these nanoscopic ferroelectric regions interfere with a polar phonon, resulting in a Fano-like asymmetric line shape in these SrTi O3 nanocubes, as well as in Ca0.3 Sr0.7 Ti O3 nanocubes.
4,4′-(1,1,1,3,3,3-HexafluoroPropane-2,2-Diyl)Bis(Benzoyl Chloride), Cecilia Rodriguez De Barbarin, Sylvain Bernes, Javier Macossay-Torres, Patrick E. Cassidy
4,4′-(1,1,1,3,3,3-HexafluoroPropane-2,2-Diyl)Bis(Benzoyl Chloride), Cecilia Rodriguez De Barbarin, Sylvain Bernes, Javier Macossay-Torres, Patrick E. Cassidy
Chemistry Faculty Publications and Presentations
In the structure of the title molecule, C17H8Cl2F6O2, the dihedral angle between the least-squares planes of the benzene rings is 66.31 (15)°. The CF3 groups adopt an eclipsed conformation.
High-Resolution Studies Of Tropolone In The S 0 And S 1 Electronic States: Isotope Driven Dynamics In The Zero-Point Energy Levels, John C. Keske, Wei Lin, Wallace C. Pringle, Stewart E. Novick, Thomas A. Blake, David F. Plusquellic
High-Resolution Studies Of Tropolone In The S 0 And S 1 Electronic States: Isotope Driven Dynamics In The Zero-Point Energy Levels, John C. Keske, Wei Lin, Wallace C. Pringle, Stewart E. Novick, Thomas A. Blake, David F. Plusquellic
Chemistry Faculty Publications and Presentations
Rotationally resolved microwave (MW) and ultraviolet (UV) spectra of jet-cooled tropolone have been obtained in S0 and S1 electronic states using Fourier-transform microwave and UV-laser/molecular-beam spectrometers. In the ground electronic state, the MW spectra of all heavy-atom isotopomers including one O18 and four C13 isotopomers were observed in natural abundance. The OD isotopomer was obtained from isotopically enriched samples. The two lowest tunneling states of each isotopomer except O18 have been assigned. The observed inversion splitting for the OD isotopomer is 1523.227(5) MHz. For the asymmetric C13 structures, the magnitudes of tunneling-rotation interactions are found to diminish with decreasing distance …