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Multi-Physicochemical Modeling Of Solid Oxide Fuel Cells And Electrolyzer Cells, Yuanyuan Xie Jan 2013

Multi-Physicochemical Modeling Of Solid Oxide Fuel Cells And Electrolyzer Cells, Yuanyuan Xie

Theses and Dissertations

Multi-physicochemical models are developed for solid oxide fuel cells and electrolysis cells. The models describe the complicated transport processes of charge (electron/ion) conservation, mass/species conservation, momentum conservation, and energy conservation. Transport processes are coherently coupled with chemical reforming processes, surface elementary reaction processes, as well as electro-oxidation processes of both hydrogen and carbon monoxide. The models are validated with experimental data and utilized for fundamental mechanism studies of SOFCs fueled with different type of fuels, such as hydrogen, hydrocarbon, e.g., methane, H2S, and their mixtures. The fundamental mechanisms associated with syngas generation using electrolysis cell are also extensively investigated using …


Modeling Of Sic Power Semiconductor Devices For Switching Converter Applications, Ruiyun Fu Jan 2013

Modeling Of Sic Power Semiconductor Devices For Switching Converter Applications, Ruiyun Fu

Theses and Dissertations

Thanks to recent progress in SiC technology, SiC JFETs, MOSFETs and Schottky diodes are now commercially available from several manufactories such as Cree, GeneSiC and Infineon. SiC devices hold the promise of faster switching speed compared to Si devices, which can lead to superior converter performance, because the converter can operate at higher switching frequencies with acceptable switching losses, so that passive filter size is reduced. However, the ultimate achievable switching speed is determined not only by internal semiconductor device physics, but also by circuit parasitic elements. Therefore, in order to accurately predict switching losses and actual switching waveforms, including …


New Approach For Modeling Hybrid Pressure Swing Adsorption-Distillation Processes, Fan Wu Jan 2013

New Approach For Modeling Hybrid Pressure Swing Adsorption-Distillation Processes, Fan Wu

Theses and Dissertations

A new methodology for modeling hybrid pressure swing adsorption (PSA)-distillation processes has been developed. Two hybrid systems were simulated as examples. One is for ethanol dehydration, and the other is for propane/propylene separation. Firstly, a distillation process simulator such as Chemsep was used to simulate the distillation process of the hybrid system, in which the PSA unit was treated as a "black box" with an assumed process performance. In this way, a hybrid PSA-distillation process can be analyzed simply by performing mass balances around these units and running Chemsep to determine the possibility of energy saving compared to a reference …


A Geographic Modeling Framework For Assessing Critical Infrastructure Vulnerability: Energy Infrastructure Case Study, Leanne Sulewski Jan 2013

A Geographic Modeling Framework For Assessing Critical Infrastructure Vulnerability: Energy Infrastructure Case Study, Leanne Sulewski

Theses and Dissertations

Vulnerability of critical infrastructure systems is of the utmost importance to a nation's national security interests, especially the electric grid. Despite the importance of these systems, disruptions continue to occur at an alarming rate, thus indicating that there is a fundamental flaw in the way critical infrastructure systems are analyzed for vulnerability.

Critical infrastructure systems are typically analyzed using mathematical approaches such as graph theory, which strip systems of their important geographic information, and only look at their connections to each other. While these relationships and metrics provide useful information, they cannot provide the entire picture. As such, this research …