Digital Commons Network^™

Promoting Electrocatalytic Activity Of A Composite Sofc Cathode La0.8Sr0.2Mno3+Δ/Ce0.8Gd0.2O2-Δ With Molten Carbonates, Yunhui Gong, Xue Li, Lingling Zhang, Whitney Tharp, Changyong Qin, Kevin Huang

Faculty Publications

The effect of molten carbonates (MCs) on polarization resistance (R_P), a direct measure of oxygen reduction reaction (ORR) activity, of a composite La_0.8Sr_0.2MnO_3+δ/Ce_0.8Gd_0.2O_2-δ (LSM/GDC) solid oxide fuel cell (SOFC) cathode has been systematically investigated in this study over a temperature range of 550–650°C and partial pressure of oxygen (pO₂) span of 10⁻³ ∼ 1 atm. It is shown that the LSM/GDC cathode, either in the pristine or MC-modified states, can be generally modeled by two consecutive parallel circuits consisting of a resistance and a …

Primary Care And Youth Mental Health In Ireland: Qualitative Study In Deprived Urban Areas, Dorothy Leahy, Elisabeth Schaffalitzky, Claire Armstrong, Gerard Bury, Paula Cussen-Murphy, Rachel Davis, Barbara Dooley, Blanaid Gavin, Rory Keane, Eamon Keenan, Linda Latham, David Meagher, Pat Mcgorry, Fiona Mcnicholas, Ray O'Connor, Ellen O'Dea, Veronica O'Keane, Tom P. O'Toole, Edel Reilly, Patrick Ryan, Lena Sanci, Bobby P. Smyth, Walter Cullen

Faculty Publications

BACKGROUND: Mental disorders account for six of the 20 leading causes of disability worldwide with a very high prevalence of psychiatric morbidity in youth aged 15-24 years. However, healthcare professionals are faced with many challenges in the identification and treatment of mental and substance use disorders in young people (e.g. young people's unwillingness to seek help from healthcare professionals, lack of training, limited resources etc.) The challenge of youth mental health for primary care is especially evident in urban deprived areas, where rates of and risk factors for mental health problems are especially common. There is an emerging consensus that …

Patients’ Attitudes Towards Patient Involvement In Safety Interventions: Results Of Two Exploratory Studies, Rachel Davis, Nick Sevdalis, Anna Pinto, Ara Darzi, Charles A. Vincent

Faculty Publications

BACKGROUND: In recent years, patient-focused interventions have been introduced aimed at increasing patient involvement in safety-related behaviours. However, patients' attitudes towards these interventions and comfort in participating in the recommended behaviours remain largely unexplored. OBJECTIVE: To evaluate patients' attitudes towards a video and leaflet aimed at encouraging patient involvement in safety-related behaviours. DESIGN: Two exploratory studies employing a within-subjects mixed-methods design. SETTING: Six hospital wards on an inner-city London teaching hospital. PARTICIPANTS: Medical and surgical inpatients: 80 patients in study 1 (mean age 55; 69% men) and 80 patients in study 2 (mean age 52; 60% men). INTERVENTION: Patients watched …

The Eps Matrix As An Adaptive Bastion For Biofilms: Introduction To Special Issue, Alan Decho

Faculty Publications

No abstract provided.

The Eps Matrix As An Adaptive Bastion For Biofilms: Introduction To Special Issue, Alan W. Decho

Faculty Publications

No abstract provided.

Creating A Gold Medal Olympic And Paralympics Health Care Team: A Satisfaction Survey Of The Mobile Medical Unit/Polyclinic Team Training For The Vancouver 2010 Winter Games, D Ross Brown, Behrouz Heidary, Nathaniel Bell, Leanne Appleton, Richard K. Simons, David C. Evans, S Morad Hameed, Jack Taunton, Kosar Khwaja, Michael O'Connor, Naisan Garraway, Peter Hennecke, Donna Kuipers, Tracey Taulu, Lori Quinn

Faculty Publications

BACKGROUND:

The mobile medical unit/polyclinic (MMU/PC) was an essential part of the medical services to support ill or injured Olympic or Paralympics family during the 2010 Olympic and Paralympics winter games. The objective of this study was to survey the satisfaction of the clinical staff that completed the training programs prior to deployment to the MMU.

METHODS:

Medical personnel who participated in at least one of the four training programs, including (1) week-end sessions; (2) web-based modules; (3) just-in-time training; and (4) daily simulation exercises were invited to participate in a web-based survey and comment on their level of satisfaction …

The Regressing Progress Clause: Rethinking Constitutional Indifference To Harmful Content In Copyright, Ned Snow

Faculty Publications

The Constitution's Progress Clause purports to restrict Congress's copyright power to works that "promote the Progress of Science and useful Arts." For most of the past two centuries, this Clause has set a minimal content-based standard for copyright eligibility. It denied protection for a work whose content did not rise to the level of useful knowledge, in that the work either lacked compositional value or portrayed an immoral or unlawful subject matter. As evidenced by judicial and scholarly writings, this construction of the Progress Clause was consistent with the 1903 decision in Bleistein v. Donaldson Lithographing Co., where the Court …

'Mother, Wife, And Queen': Tennyson's (Varying) Dedication To Queen Victoria, Patrick G. Scott

Faculty Publications

Discusses the literary precedents, manuscripts, composition, and biographical context for Tennyson's poem "To the Queen," first published in Match 1851, and argues that Tennyson's attitudes toward Queen Victoria and to his role as Poet Laureate were more nuanced and more conflicted than most critics have recognized.

Physiological Arousal In Autism And Fragile X Syndrome: Group Comparisons And Links With Pragmatic Language, Jessica Klusek, G E. Martin, M Losh

Faculty Publications

No abstract provided.

Contributions To Pion Decay From Lorentz Violation In The Weak Sector, Brett David Altschul

Faculty Publications

Lorentz violation in the weak sector would affect the β-decay lifetimes of pions. The decay amplitude may be rendered anisotropic, but only an isotropic violation of boost invariance can affect the net lifetime in the center-of-mass frame. However, since the rest frames of the pions that produce the NuMI neutrino beam at Fermilab vary with the rotation of the Earth, it is possible to constrain anisotropic Lorentz violation using prior analyses of sidereal variations in the event rate at the MINOS near detector. The resulting bounds on weak-sector Lorentz violation are at the 10⁻⁴ level, a substantial improvement over …

Enhanced Reversibility And Durability Of A Solid Oxide Fe–Air Redox Battery By Carbothermic Reaction Derived Energy Storage Materials, Xuan Zhao, Xue Li, Yunhui Gong, Kevin Huang

Faculty Publications

The recently developed solid oxide metal–air redox battery is a new technology capable of high-rate chemistry. Here we report that the performance, reversibility and stability of a solid oxide iron–air redox battery can be significantly improved by nanostructuring energy storage materials from a carbothermic reaction.

A New Solid Oxide Molybdenum–Air Redox Battery, Xuan Zhao, Yunhui Gong, Xue Li, Nansheng Xu, Kevin Huang

Faculty Publications

A new type of rechargeable molybdenum–air battery based on the technologies of reversible solid oxide fuel cells and chemical looping is reported in this study. The reversible solid oxide fuel cell serves as the electrical unit to realize the charging and discharging cycles while a pair of Mo/MoO2 redox couple integrated with the reversible solid oxide fuel cell stores electrical energy via an H2–H2O oxygen shuttle. The specific charge of the new battery reaches 1117 A h per kg-Mo at 550°C, which is 45% higher than the non-rechargeable Mo–air battery. The corresponding discharge specific energy is 974 W h per …

Advances In The Redcat Software Package, Chris Schmidt, Stephanie J. Irausquin, Homayoun Valafar

Faculty Publications

Background

Residual Dipolar Couplings (RDCs) have emerged in the past two decades as an informative source of experimental restraints for the study of structure and dynamics of biological macromolecules and complexes. The REDCAT software package was previously introduced for the analysis of molecular structures using RDC data. Here we report additional features that have been included in this software package in order to expand the scope of its analyses. We first discuss the features that enhance REDCATs user-friendly nature, such as the integration of a number of analyses into one single operation and enabling convenient examination of a structural ensemble …

Trauma History And Depression Predict Incomplete Adherence To Antiretroviral Therapies In A Low Income Country, Kathryn Whetten, Kristen Shirey, Brian Wells Pence, Jia Yao, Nathan Thielman, Rachel Whetten, Julie Adams, Bernard Agala, Jan Ostermann, Karen O'Donnell, Amy Hobbie, Venance Maro, Dafrosa Itemba, Elizabeth Reddy, Chat Research Team

Faculty Publications

Background: As antiretroviral therapy (ART) for HIV becomes increasingly available in low and middle income countries (LMICs), understanding reasons for lack of adherence is critical to stemming the tide of infections and improving health. Understanding the effect of psychosocial experiences and mental health symptomatology on ART adherence can help maximize the benefit of expanded ART programs by indicating types of services, which could be offered in combination with HIV care. Methodology: The Coping with HIV/AIDS in Tanzania (CHAT) study is a longitudinal cohort study in the Kilimanjaro Region that included randomly selected HIV-infected (HIV+) participants from two local hospital-based HIV …

Where The Judiciary Prosecutes In Front Of Itself: Missouri's Unconstitutional Juvenile Court Structure, Josh Gupta-Kagan

Faculty Publications

This article is the first scholarly examination of Missouri’s unusual juvenile court structure: Missouri law charges a “juvenile officer” with exclusive authority to determine which child welfare or delinquency cases to file and what to charge in each case. The juvenile officer is hired and supervised by juvenile court judges, and the juvenile officer litigates cases in front of those same judges. This structure differs from the typical procedures in juvenile courts around the United States, which have generally adapted their juvenile courts to reflect the norm of executive branch agencies or attorneys (not court staff) filing cases to intervene …

Characterization Of The 5 Ghz Elevator Shaft Channel, Ruoyu Sun, David W. Matolak

Faculty Publications

In this paper we provide channel characterization results for the elevator shaft channel in the 5-GHz band, based upon measurements conducted in four buildings. This channel is of interest for several applications, including WiFi and public safety. Although several authors have provided elevator shaft channel characteristics for lower-frequency bands (255-MHz, 900-MHz, 1.9-GHz), to our knowledge this is the first work that addresses the 5-GHz band. Moreover, prior work has not thoroughly addressed channel characteristics when the elevator car is in motion, whereas here we provide measurement and modeling results for this dynamic condition. Our measurements were of power delay profiles, …

Enhanced Reducibility And Conductivity Of Na/K-Doped Srti0.8Nb0.2O3, Guoliang Xiao, Sirikanda Nuansaeng, Lei Zhang, Suwit Suthirakun, Andreas Heyden, Hans-Conrad Zur Loye, Fanglin Chen

Faculty Publications

Donor and acceptor co-doped SrTiO₃ materials have shown interesting features in their conductivity and reducibility. In this work, 10 mol% Na⁺ or K⁺ as acceptor dopants have been introduced into the A-site of donor-doped strontium titanate, SrTi_0.8Nb_0.2O₃, and the doping impact on their properties has been studied. By doping with Na or K, the sinterability of SrTi_0.8Nb_0.2O₃ in reducing atmospheres has been improved. Na_0.1Sr_0.9Ti_0.8Nb_0.2O₃ and K_0.1Sr_0.9Ti_0.8Nb_0.2O₃ show metallic …

Parental Height And Child Growth From Birth To 2 Years In The Who Multicentre Growth Reference Study, Cutberto Garza, Elaine Borghi, Adelheid W. Onyango, Mercedes De Onis, Edward A. Frongillo Jr.

Faculty Publications

inear growth from birth to 2 years of children enrolled in the World Health Organization Multicentre Growth Reference Study was similar despite substantial parental height differences among the six study sites. Within-site variability in child length attributable to parental height was estimated by repeated measures analysis of variance using generalized linear models. This approach was also used to examine relationships among selected traits (e.g. breastfeeding duration and child morbidity) and linear growth between 6 and 24 months of age. Differences in intergenerational adult heights were evaluated within sites by comparing mid-parental heights (average of the mother's and father's heights) to …

Short, Strong Halogen Bonding In Co-Crystals Of Pyridyl Bis-Urea Macrocycles And Iodoperfluorocarbons, Michael F. Geer, James Mazzuca, Mark D. Smith, Linda S. Shimizu

Faculty Publications

No abstract provided.

Towards A Public Health Legal Structure For Child Welfare, Josh Gupta-Kagan

Faculty Publications

The present American child welfare system infringes upon the fundamental liberty interests of millions of children and parents, is adversarial and punitive, and fails to prevent child maltreatment or protect children adequately from its most severe forms. Many in the field now recognize that a public health model would more effectively support the parent-child relationship and protecting children from maltreatment than the current paradigm. Despite much attention to such an approach, the field has yet to develop a clear vision for how the law could or should support a public health approach or shape the actions of individuals and institutions …

Cultures Of Access: Differences In Rhetoric Around Open Access Repositories In Africa And The United States And Their Implications For The Open Access Movement, Natalia T. Bowdoin

Faculty Publications

Open Access (OA) refers to free, online access to peer reviewed scholarship. Many OA proponents view OA as a potential mechanism for reversing inequities in information flows between industrialized and non-industrialized nations. The "green road" of OA (self-archiving in an OA institutional repository) has seen substantial growth in African nations where there have historically been chronic problems both with access to scholarly and scientific materials and participation in the larger scholarly and scientific community. For this study I examined the rhetoric used by OA institutional repositories and what this rhetoric may say about different "cultures of OA". I conducted textual …

A Multi-Physics Model For Solid Oxide Iron-Air Redox Flow Battery: Simulation Of Discharge Behavior At High Current Density, Meng Guo, Xuan Zhao, Ralph E. White, Kevin Huang

Faculty Publications

A rigorous physics-based mathematical model for a solid oxide iron-air redox flow battery system is presented in this paper. The modeled flow battery system combines a Fe-FeO redox couple as the energy storage unit and a regenerative solid oxide fuel cell as the electrical functioning unit in a 2D axial symmetric geometry. This model was developed from fundamental theories of reaction engineering in which basic transport phenomena and chemical/electrochemical kinetics are included. The model shows good agreement with the experimental data. Simulation results for the chemical, electrochemical and transport behavior of the battery are discussed.

Protein Structure Validation And Identification From Unassigned Residual Dipolar Coupling Data Using 2d-Pdpa, Arjang Fahim, Rishi Mukhopadhyay, Ryan Yandle, James H. Prestegard, Homayoun Valafar

Faculty Publications

More than 90% of protein structures submitted to the PDB each year are homologous to some previously characterized protein structure. The extensive resources that are required for structural characterization of proteins can be justified for the 10% of the novel structures, but not for the remaining 90%. This report presents the 2D-PDPA method, which utilizes unassigned residual dipolar coupling in order to address the economics of structure determination of routine proteins by reducing the data acquisition and processing time. 2D-PDPA has been demonstrated to successfully identify the correct structure of an array of proteins that range from 46 to 445 …

Protein Structure Validation And Identification From Unassigned Residual Dipolar Coupling Data Using 2d-Pdpa, Arjang Fahim, Rishi Mukhopadhayay, Ryan Yandle, James H. Prestegard, Homayoun Valafar

Faculty Publications

More than 90% of protein structures submitted to the PDB each year are homologous to some previously characterized protein structure. The extensive resources that are required for structural characterization of proteins can be justified for the 10% of the novel structures, but not for the remaining 90%. This report presents the 2D-PDPA method, which utilizes unassigned residual dipolar coupling in order to address the economics of structure determination of routine proteins by reducing the data acquisition and processing time. 2D-PDPA has been demonstrated to successfully identify the correct structure of an array of proteins that range from 46 to 445 …

Experimental Demonstration Of Accelerated Extinction In Source-Sink Metapopulations, John M. Drake, Blaine D. Griffen

Faculty Publications

Population extinction is a fundamental ecological process which may be aggravated by the exchange of organisms between productive (source) and unproductive (sink) habitat patches. The extent to which such source-sink exchange affects extinction rates is unknown. We conducted an experiment in which metapopulation effects could be distinguished from source-sink effects in laboratory populations of Daphnia magna. Time-to-extinction in this experiment was maximized at intermediate levels of habitat fragmentation, which is consistent with a minority of theoretical models. These results provided a baseline for comparison with experimental treatments designed to detect effects of concentrating resources in source patches. These treatments showed …

A Supramolecular Strategy To Assemble Multifunctional Viral Nanoparticles, Limin Chen, Xia Zhao, Yuan Lin, Yubin Huang, Qian Wang

Faculty Publications

Using a one-pot approach driven by the supramolecular interaction between β-cyclodextrin and adamantyl moieties, multifunctional viral nanoparticles can be facilely formulated for biomedical applications.

A Forward-Secure Certificate-Based Signature Scheme, Jiguo Li, Huiyun Teng, Xinyu Huang, Yichen Zhang, Jianying Zhou

Faculty Publications

Cryptographic computations are often carried out on insecure devices for which the threat of key exposure raises a serious concern. In an effort to address the key exposure problem, the notion of forward security was first presented by Günther in 1990. In a forward-secure scheme, secret keys are updated at regular periods of time; exposure of the secret key corresponding to a given time period does not enable an adversary to ‘break’ the scheme for any prior time period. In this paper, we first introduce forward security into certificate-based cryptography and define the security model of forward-secure certificate-based signatures (CBSs). …

Cyclic Durability Of A Solid Oxide Fe-Air Redox Battery Operated At 650°C, Xuan Zhao, Yunhui Gong, Xue Li, Nansheng Xu, Kevin Huang

Faculty Publications

The recently developed rechargeable solid oxide metal-air redox battery has shown a great potential for applications in mid- to large-scale stationary energy storage. Cyclic durability is one of the most important requirements for stationary energy storage. In this study, we report the cyclic durability of a solid oxide Fe-air redox battery operated at 650°C. The battery was continuously cycled 100 times under a current density of 50 mA/cm² with rather flat performance, producing an average specific energy of 760 Wh/kg-Fe at a round-trip efficiency of 55.5%. The post-test examination indicated that the performance losses could arise from the fuel-electrode …

Cyclic Durability Of A Solid Oxide Fe-Air Redox Battery Operated At 650°C, Xuan Zhao, Yunhui Gong, Xue Li, Nansheng Xu, Kevin Huang

Faculty Publications

The recently developed rechargeable solid oxide metal-air redox battery has shown a great potential for applications in mid- to large-scale stationary energy storage. Cyclic durability is one of the most important requirements for stationary energy storage. In this study, we report the cyclic durability of a solid oxide Fe-air redox battery operated at 650◦C. The battery was continuously cycled 100 times under a current density of 50 mA/cm2 with rather flat performance, producing an average specific energy of 760 Wh/kg-Fe at a round-trip efficiency of 55.5%. The post-test examination indicated that the performance losses could arise from the fuel-electrode of …

What Attributes Of Patients Affect Their Involvement In Safety? A Key Opinion Leaders’ Perspective, Stephen Buetow, Rachel E. Davis, Kathleen Callaghan, Susan Dovey

Faculty Publications

OBJECTIVE: Little is known about which attributes the patients need when they wish to maximise their capability to partner safely in healthcare. We aimed to identify these attributes from the perspective of key opinion leaders. DESIGN: Delphi study involving indirect group interaction through a structured two-round survey. SETTING: International electronic survey. PARTICIPANTS: 11 (65%) of the 17 invited internationally recognised experts on patient safety completed the study. OUTCOME MEASURES: 50 patient attributes were rated by the Delphi panel for their ability to contribute maximally to safe health care. RESULTS: The panellists agreed that 13 attributes are important for patients who …