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Enzymatic Liquefaction Of Untreated Corn Stover, Neal N. Hengge

Open Access Theses

There is an ever increasing need for renewable alternatives to fossil fuels derived from petroleum. This makes feedstocks in the form of lignocellulosic biomass attractive substrates for the production of ethanol and value added chemicals. However, the economics of converting lignocellulosic materials involve high processing costs attributed with pretreatment of the biomass and the use of enzymes for saccharification. Corn stover was obtained for the examination of an upstream processing step to transform the material into a pumpable slurry for subsequent pretreatment and saccharification. Biomass liquefaction was carried out using the enzyme Depol 692L (Biocatalysts, Wales, UK) at 50°C with …

Targeted Products From Fast-Hydropyrolysis And Hydrodeoxygenation Of Biomass, Ian Tad Smith

Open Access Theses

Previously, the H2Bioil process was proposed as a possible way to convert sustainably available intact biomass into liquid fuels. The optimization of this process and possible synergies with other biomass conversion processes are presented in this thesis.

The selectivity of the PtMo hydrodeoxygenation catalyst was tuned using two different hydrogen partial pressures: 25 bar, and 2.5 bar. This effect was studied on cellulose and intact biomass samples to determine the effect that hydrogen has upon the retention of aromatic compounds found in intact biomass. These experiments show that it is possible for the hydrogenation activity of the PtMo catalyst to …

Design And Use Of An Adjustable Clearance Flailing Knife Biomass Shredder To Mechanically Increase Particle Surface Area, Shawn Gregory Ehlers

Open Access Theses

A flailing knife shredder was designed and tested as an alternative to a hammermill for processing biomass. The machine was comprised of two cylinders with four rungs, each with five free-swinging blades. Each of the two cylinders had adjustable clearance hoods and variable speed drives. Energy usage, output characteristics and device capacities were compared with corn stover processed at moisture contents (MC) of 10%, 35% and 50% wet basis (WB). The hammermill produced a more uniform particle size distribution in comparison to the shredder. Accessibility, indicated by conductivity index, to plant constituents, revealed that the method of treatment was not-significant …