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Minimizing Corrosion Of Outdoor Metalworks Using Dispersed Chemically Stabilized Nanoclays In Polyvinylidene Fluoride Latex Coatings, Natasja Alexandria Swartz, Capri A. Price, Tami Lasseter Clare Jul 2016

Minimizing Corrosion Of Outdoor Metalworks Using Dispersed Chemically Stabilized Nanoclays In Polyvinylidene Fluoride Latex Coatings, Natasja Alexandria Swartz, Capri A. Price, Tami Lasseter Clare

Chemistry Faculty Publications and Presentations

Nanoclays are small enough to appear optically transparent, yet they have large surface-to-volume and high aspect ratios that can significantly inhibit water diffusion when incorporated into protective coatings. Clear coatings, which minimally affect the aesthetics of metalworks, are commonly applied to outdoor metalworks, such as sculptures, to prevent and slow corrosion. In recent years, waterborne clear coatings, rather than solvent-based clear coatings, are increasingly used in many applications to reduce the quantity of volatile organic components in the formulation, yet the performance of dry films produced from waterborne colloidal suspensions is generally poorer. In this work, we aim to improve …


Expanding The Versatility Of Nano Assembled Capsules As Platform Of Potential High Payload Mri Contrast Agents, Annah Farashishiko Jul 2016

Expanding The Versatility Of Nano Assembled Capsules As Platform Of Potential High Payload Mri Contrast Agents, Annah Farashishiko

Dissertations and Theses

Magnetic resonance imaging (MRI) has become a powerful clinical modality in diagnostic medicine. It is non-invasive and offers high spatial and temporal resolution. The goal of molecular imaging is to reveal the pathophysiology underlying the observed anatomy and diagnose diseases. The detection of pathological biomarkers can lead to early recognition of diseases and improved monitoring for recurrence. Clinically available contrast agents are limited in their discrimination of contrast between tissues and they tend to have very high detection limits. Because biomarkers are very low in concentration there is a need for high payload deposition of contrast agent (CA) and targeted …


A Novel Methodology For Spatial Damage Detection And Imaging Using A Distributed Carbon Nanotube-Based Composite Sensor Combined With Electrical Impedance Tomography, Hongbo Dai, Gerard J. Gallo, Thomas Schumacher, Erik T. Thostenson Mar 2016

A Novel Methodology For Spatial Damage Detection And Imaging Using A Distributed Carbon Nanotube-Based Composite Sensor Combined With Electrical Impedance Tomography, Hongbo Dai, Gerard J. Gallo, Thomas Schumacher, Erik T. Thostenson

Civil and Environmental Engineering Faculty Publications and Presentations

This paper describes a novel non-destructive evaluation methodology for imaging of damage in composite materials using the electrical impedance tomography (EIT) technique applied to a distributed carbon nanotube-based sensor. The sensor consists of a nonwoven aramid fabric, which was first coated with nanotubes using a solution casting approach and then infused with epoxy resin through the vacuum assisted resin transfer molding technique. Finally, this composite sensor is cured to become a mechanically-robust, electromechanically-sensitive, and highly customizable distributed two-dimensional sensor which can be adhered to virtually any substrate. By assuming that damage on the sensor directly affects its conductivity, a difference …


Semiconductor Film Grown On A Circular Substrate: Predictive Modeling Of Lattice-Misfit Stresses, Ephraim Suhir, Johann Nicolics, G. Khatibi, M. Lederer Mar 2016

Semiconductor Film Grown On A Circular Substrate: Predictive Modeling Of Lattice-Misfit Stresses, Ephraim Suhir, Johann Nicolics, G. Khatibi, M. Lederer

Mechanical and Materials Engineering Faculty Publications and Presentations

effective and physically meaningful analytical predictive model is developed for the evaluation the lattice-misfit stresses (LMS) in a semiconductor film grown on a circular substrate (wafer). The two-dimensional (plane-stress) theory-of-elasticity approximation (TEA) is employed in the analysis. The addressed stresses include the interfacial shearing stress, responsible for the occurrence and growth of dislocations, as well as for possible delaminations and the cohesive strength of a buffering material, if any. Normal radial and circumferential (tangential) stresses acting in the film cross-sections and responsible for its short- and long-term strength (fracture toughness) are also addressed. The analysis is geared to the GaN …


Synthesis, Structure And Contrast Efficacy Of Bismuth (Iii) Chelated With 1,4,7,10-Tetraazacyclododecane-1,4,7,10-Tetramethylene Phosphonate And Its Incorporation Into Nano-Assembled Capsules, Karley B. Maier Jan 2016

Synthesis, Structure And Contrast Efficacy Of Bismuth (Iii) Chelated With 1,4,7,10-Tetraazacyclododecane-1,4,7,10-Tetramethylene Phosphonate And Its Incorporation Into Nano-Assembled Capsules, Karley B. Maier

University Honors Theses

Medical imaging now plays an integral role in the diagnosis and treatment of illness. The use of contrast agents in molecular imaging has been instrumental in the diagnosis of cancer and similar pathologies. The incorporation of lanthanide-based contrast agents employed in magnetic resonance imaging (MRI) into nano-assembled capsules (NACs) have shown potential utility for improved contrast in MRI by slowing the tumbling of the polyanionic paramagnetic metal ions. The utility of NACs was herein extended to computed tomography (CT) imaging by the incorporation of electron dense bismuth (III)-based chelates into NACs in order to provide a high payload of agent …