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Articles 1 - 16 of 16
Full-Text Articles in Entire DC Network
Beyond Zar: The Use And Abuse Of Classification Statistics For Otolith Chemistry, C. M. Jones, M. Palmers, J. J. Schaffler
Beyond Zar: The Use And Abuse Of Classification Statistics For Otolith Chemistry, C. M. Jones, M. Palmers, J. J. Schaffler
OES Faculty Publications
Classification method performance was evaluated using otolith chemistry of juvenile Atlantic menhaden Brevoortia tyrannus when assumptions of data normality were met and were violated. Four methods were tested [linear discriminant function analysis (LDFA), quadratic discriminant function analysis (QDFA), random forest (RF) and artificial neural networks (ANN)] using computer simulation to determine their performance when variable-group means ranged from small to large and their performance under conditions of typical skewness to double the amount of skewness typically observed. Using the kappa index, the parametric methods performed best after applying appropriate data transformation, gaining 2% better performance with LDFA performing slightly better …
Frontiers In Otolith Chemistry: Insights, Advances And Applications, B. D. Walther, K. E. Limburg, C. M. Jones, J. J. Schaffler
Frontiers In Otolith Chemistry: Insights, Advances And Applications, B. D. Walther, K. E. Limburg, C. M. Jones, J. J. Schaffler
OES Faculty Publications
The rapid proliferation of publications employing chemical assays of fish hard parts, and otoliths in particular, has led to many novel insights into the migration patterns, life history strategies and mixed stock dynamics of fishes across the globe (Campana et al., 2000; Elsdon et al., 2008; Walther & Limburg, 2012). These insights include uncovering diverse migratory strategies within species and populations (Kerr et al., 2009; Hogan et al., 2014; Schoen et al., 2016), quantifying rates of mixing among stocks across management boundaries (Rooker et al., 2008; Walther & Thorrold, 2010) and estimating the relative …
Plant Species Rather Than Climate Greatly Alters The Temporal Pattern Of Litter Chemical Composition During Long-Term Decomposition, Yongfu Li, Na Chen, Mark E. Harmon, Yuan Li, Xiaoyan Cao, Mark A. Chappell, Jingdong Mao
Plant Species Rather Than Climate Greatly Alters The Temporal Pattern Of Litter Chemical Composition During Long-Term Decomposition, Yongfu Li, Na Chen, Mark E. Harmon, Yuan Li, Xiaoyan Cao, Mark A. Chappell, Jingdong Mao
Chemistry & Biochemistry Faculty Publications
A feedback between decomposition and litter chemical composition occurs with decomposition altering composition that in turn influences the decomposition rate. Elucidating the temporal pattern of chemical composition is vital to understand this feedback, but the effects of plant species and climate on chemical changes remain poorly understood, especially over multiple years. In a 10-year decomposition experiment with litter of four species (Acer saccharum, Drypetes glauca, Pinus resinosa, and Thuja plicata) from four sites that range from the arctic to tropics, we determined the abundance of 11 litter chemical constituents that were grouped into waxes, carbohydrates, …
The Impact Of Multiple Nursery Areas On The Population Structure Of Atlantic Menhaden, Brevooria Tyrannus, Kristen A. Anstead
The Impact Of Multiple Nursery Areas On The Population Structure Of Atlantic Menhaden, Brevooria Tyrannus, Kristen A. Anstead
OES Theses and Dissertations
Understanding the population structure and patterns of connectivity in marine fishes is essential when making predictions about a species' resiliency and persistence in an increasingly changing environment. The Atlantic Menhaden Brevoortia tyrannus is a clupeid that plays a critical role in the marine food web and supports one of the largest fisheries on the US East Coast. In addition to a decrease in overall numbers and spawning stock biomass, recruitment levels have remained low since the 1990s. Menhaden use numerous estuaries along the Atlantic coast for juvenile development before recruiting to the adult population and the contribution of each of …
Lack Of Equivalence In The Elemental And Stable Isotope Chemistry Within The Sagittal Otolith Pair Of The Summer Flounder, Paralichthys Dentatus, Antranik Kajajian, Jason J. Schaffler, Cynthia M. Jones
Lack Of Equivalence In The Elemental And Stable Isotope Chemistry Within The Sagittal Otolith Pair Of The Summer Flounder, Paralichthys Dentatus, Antranik Kajajian, Jason J. Schaffler, Cynthia M. Jones
OES Faculty Publications
In fish that are not bilaterally symmetrical, the left and right sagittae are often not symmetrical, exhibiting divergent growth patterns and mass, and may have differences in chemical composition. We investigated this in the asymmetrical summer flounder Paralichthys dentatus, collected from different nursery habitats along the US east coast. Significant differences were detected in otolith mass, δ13C, δ18O, Li:Ca, Mg:Ca, and Sr:Ca, and overall chemical signatures. These results refute the hypothesis of left-right equivalence that is prevalent for bilaterally symmetrical fishes. We tested whether a specific side was better suited for classification. The best models …
Effect Of Laser Ablation Depth In Otolith Life History Scans, Renée R. Hoover, Cynthia M. Jones
Effect Of Laser Ablation Depth In Otolith Life History Scans, Renée R. Hoover, Cynthia M. Jones
OES Faculty Publications
Life history scans of fish otoliths are bringing new insight into the structure, connectivity, and movement of fish populations. Data obtained from such scans, however, possess in-herent limitations that have not yet been fully addressed or understood. For example, several investigators have noted delays in otolith elemental uptake that do not appear to reflect habitat exposure. We hypothesized that the 3-dimensional structure of otoliths may produce sampling artifacts in the results obtained from laser ablation scans. To test this hypothesis, we sampled sagittal otoliths from juvenile Atlantic croaker Micropogonias undulatus with laser ablation inductively coupled plasma mass spectrometry to obtain …
Evaluating Methods For Optimizing Classification Success From Otolith Tracers For Spotted Seatrout (Cynoscion Nebulosus) In The Chesapeake Bay, Stacy Kavita Beharry
Evaluating Methods For Optimizing Classification Success From Otolith Tracers For Spotted Seatrout (Cynoscion Nebulosus) In The Chesapeake Bay, Stacy Kavita Beharry
OES Theses and Dissertations
Identifying the natal sources of fish is an important step in understanding its population dynamics. Adult recruits are often sourced from multiple nursery areas, with good quality locations contributing disproportionately more fish to the adult stock. Because population persistence is strongly influenced by nursery habitat, methods that correctly identify the source of recruits are necessary for effective management. Within the last decade, otolith chemistry signatures have been increasingly used as a natural marker to delineate fish from a mixture of nursery sources. Despite the widespread use of otolith trace element and stable isotope ratios as habitat markers, the statistical approaches …
The Use Of Fourier Transform (Ft) Surface-Enhanced Raman Scattering For Biochemical Analysis, Robert Butler Jeffers
The Use Of Fourier Transform (Ft) Surface-Enhanced Raman Scattering For Biochemical Analysis, Robert Butler Jeffers
Chemistry & Biochemistry Theses & Dissertations
Surface-enhanced Raman scattering (SERS) is a powerful spectroscopic technique that has created exciting opportunities in the field of bioanalytical chemistry, where it combines ultrasensitive detection of biologically relevant molecules with vibrational spectroscopy. Due to the difficulties in preparing reproducible SERS active substrates, SERS has been mainly used as a qualitative tool. In order for SERS to be utilized as a viable tool for quantitative analysis, simple, facile SERS substrates which generate clean, highly reproducible signals must be developed. This dissertation deals with the evaluation of three different methods of SERS that led to the development of a novel substrate for …
Method Against Method: Swarm And Interdisciplinary Research Methodology, Dylan E. Wittkower
Method Against Method: Swarm And Interdisciplinary Research Methodology, Dylan E. Wittkower
Philosophy Faculty Publications
Part of a special issue on “swarm methodology,” this paper, written by a swarm participant, reflects upon the purpose and value of this kind of interdisciplinary research methodology. First, by way of a recognition of the interdisciplinary status of this paper itself, the question of what we hope to accomplish when we engage in conversations across disciplinary boundaries is broached. Second, a discussion of the practice of peer-review provides an approximate view of one paradigmatic understanding of how we produce a “conversation” within a given established research methodology. We are then, third, able to consider a number of possible related …
Anthropogenic Osmium In Rain And Snow Reveals Global-Scale Atmospheric Contamination, Cynthia Chen, Peter N. Sedwick, Mukul Sharma
Anthropogenic Osmium In Rain And Snow Reveals Global-Scale Atmospheric Contamination, Cynthia Chen, Peter N. Sedwick, Mukul Sharma
OES Faculty Publications
Osmium is one of the rarer elements in seawater, with typical concentration of ≈10 x 10-15 g g-1 ( 5.3 x 10-14 mol kg-1. The osmium isotope composition (187Os/188Os ratio) of deep oceans is 1.05, reflecting a balance between inputs from continental crust (≈ 1.3) and mantle/cosmic dust (≈ 0.13). Here, we show that the 187Os/188Os ratios measured in rain and snow collected around the world range from 0.16 to 0.48, much lower than expected (>1), but similar to the isotope composition of ores (approximate to 0.2) …
Chemistry Of Surface Waters: Distinguishing Fine-Scale Differences In Sea Grass Habitats Of Chesapeake Bay, Emmanis Dorval, Cynthia M. Jones
Chemistry Of Surface Waters: Distinguishing Fine-Scale Differences In Sea Grass Habitats Of Chesapeake Bay, Emmanis Dorval, Cynthia M. Jones
OES Faculty Publications
We tested the hypothesis that the physical and chemical processes acting in sea grass habitats of the lower Chesapeake Bay are spatially structured and that dissolved elemental chemistry of sea grass-habitat surface waters have their own unique identity. We sampled surface waters from July to September 2001 in five sea grass habitats of the lower bay: Potomac, Rappahannock, York, Island (Tangier-Bloodsworth), and Eastern Shore. Dissolved Mg, Mn, Sr, and Ba concentrations were measured by sector field inductively coupled plasma-mass spectrometry. As expected, Mg, Sr, and Ba exhibited conservative behavior, but Mn exhibited nonconservative behavior along the salinity gradient. Spatial differences …
Experimental Investigation Of Elemental Incorporation In The Otoliths Of Larval And Juvenile Fish: Implications For Use As Environmental Recorders, Gretchen Bath Martin
Experimental Investigation Of Elemental Incorporation In The Otoliths Of Larval And Juvenile Fish: Implications For Use As Environmental Recorders, Gretchen Bath Martin
Biological Sciences Theses & Dissertations
Innovative techniques for discerning fish stocks, identifying nursery habitats, locating spawning sites, tracing larval transport pathways, and quantifying the degree of population connectivity are required to meet the goals of sustainable management of marine capture fisheries. One of the most promising techniques is the use of elemental signatures in fish otoliths (ear stones), which record valuable life history data and serve as the link between fish and their environment. To validate the assumption that otolith elemental composition is a function of water elemental concentrations, and to address the possible effects of external variables such as temperature and salinity, the composition …
The Distribution Of Airborne Coal Dust In Soil Profiles Of Norfolk, Va And Its Implication For Arsenic Loading To These Soils, William Joseph Bounds
The Distribution Of Airborne Coal Dust In Soil Profiles Of Norfolk, Va And Its Implication For Arsenic Loading To These Soils, William Joseph Bounds
OES Theses and Dissertations
Norfolk, Virginia is home to the Northern Hemisphere's largest coal terminal the Lamberts Point Docks. The coal loading process of this terminal creates large amounts of coal dust, which subsequently is distributed throughout the local region by atmospheric transport and deposition. While the coal dust itself poses only minor health hazards, certain trace elements within the coal, particularly arsenic, may pose environmental as well as significant health hazards. Within coal, arsenic occurs primarily in the mineral pyrite. As pyrite in the coal dust is subsequently oxidized via exposure to the atmosphere and/or meteoric water, arsenic may be released to the …
Accurate Classification Of Juvenile Weakfish Cynoscion Regalis To Estuarine Nursery Areas Based On Chemical Signatures In Otoliths, Simon R. Thorrold, Cynthia M. Jones, Peter K. Swart, Timothy E. Targett
Accurate Classification Of Juvenile Weakfish Cynoscion Regalis To Estuarine Nursery Areas Based On Chemical Signatures In Otoliths, Simon R. Thorrold, Cynthia M. Jones, Peter K. Swart, Timothy E. Targett
OES Faculty Publications
We investigated the ability of trace element and isotopic signatures in otoliths to record the nursery areas of juvenile (young-of-the-year) weakfish Cynoscion regalis from the east coast of the USA. Juvenile C. regalis were captured with otter trawls at multiple sites in Doboy Sound (Georgia), Pamlico Sound (North Carolina), Chesapeake Bay (Virginia), Delaware Bay (Delaware) and Peconic Bay (New York), from July to September 1996. One sagittal otolith from each specimen was assayed for Mg/Ca, Mn/Ca, Sr/Ca and Ba/Ca ratios using inductively coupled plasma mass spectrometry (ICP-MS), while delta 13 C and delta 18 O values from the other sagittal …
Development Of Solid Phase Microextraction Methods For Contraband Drugs, Vangielynn Cruz Tersol
Development Of Solid Phase Microextraction Methods For Contraband Drugs, Vangielynn Cruz Tersol
Chemistry & Biochemistry Theses & Dissertations
The objective of this study is to develop analytical methods for studying contraband drugs at nanogram levels and to demonstrate the utility of the methods. A method which combines solid phase microextraction with ion mobility spectrometry (SPME-IMS) was developed. The SPME-IMS method was used as a rapid screening tool in studying the chemistry of cocaine HCI, heroin HCI, and heroin freebase on surfaces. The total time for sample preparation, reaction, and analysis is approximately seven minutes. Another method that was developed is one that combines solid phase microextraction with gas chromatography (SPME-GC) for the quantitative analysis of cocaine freebase and …
Effects Of Multiple Scattering And Surface Albedo On The Photochemistry Of The Troposphere, Tommy Reinhold Robert Augustsson
Effects Of Multiple Scattering And Surface Albedo On The Photochemistry Of The Troposphere, Tommy Reinhold Robert Augustsson
Mechanical & Aerospace Engineering Theses & Dissertations
A one-dimensional photochemical model of the troposphere containing the species of the nitrogen, oxygen, carbon, hydrogen, and sulfur families has been developed and used to investigate the vertical profiles and the natural (including atmospheric chemical reactions) and anthropogenic sources and sinks of these species. The species continuity equations are solved numerically applying prescribed boundary conditions. The vertical flux is simulated by use of the parameterized eddy diffusion coefficients. Heterogeneous losses (e.g. rainout, gas-to-particle chemistry, and dry deposition), are parameterized to make calculated profiles consistent with measurements. The photochemical model is coupled to a radiative transfer model that calculates the radiation …