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Development Of A Femtosecond Time-Resolved Raman Spectrometer For Hemoglobin Studies., Junbo Chen
Development Of A Femtosecond Time-Resolved Raman Spectrometer For Hemoglobin Studies., Junbo Chen
LSU Historical Dissertations and Theses
A femtosecond time-resolved Raman spectrometer is developed to study the ultrafast dynamics of hemoprotein. The laser system consists of a dye laser synchronously pumped by the SHG of compressed ML Nd:YAG laser pulse, and a Ti:sapphire regenerative amplifier using chirped-pulse-amplification technique. The laser system provides 350 fs pulses output with 0.4 mJ/pulse energy at the repetition rate of 1 kHz. The tunability covers the whole Ti:sapphire lasing range with the use of different laser dye. Femtosecond time-resolved resonance Raman experiment shows that the ligand photodissociation quantum yield depends on the nature of ligand. With three ligands studied, CO has about …
Studies Of V-Nitrogenase From Azotobacter Vinelandii: Structural Variations, Temperature And Solvent Effects., Carol Zembiak Blanchard
Studies Of V-Nitrogenase From Azotobacter Vinelandii: Structural Variations, Temperature And Solvent Effects., Carol Zembiak Blanchard
LSU Historical Dissertations and Theses
When Q-Sepharose was used in the purification of the V-nitrogenase proteins from Azotobacter vinelandii, an increase in resolution was observed which resulted in a separation of the nitrogenase component 1 protein (Av1$\sp\prime$) into two forms, labeled Av1$\sp\prime\sb{\rm A}$ and Av1$\sp\prime\sb{\rm B}.$ Even though both forms possessed the same enzymatic behavior, Av1$\sp\prime\sb{\rm A}$ exhibited a lower specific activity and migrated during gel filtration with an apparent lower molecular weight than Av1$\sp\prime\sb{\rm B}.$ Furthermore, SDS-polyacrylamide gel electrophoresis showed different relative compositions of the two major subunits of both forms with Av1$\sp\prime\sb{\rm A}$ possessing a trimer $(\alpha\beta\sb2)$ pattern compared to the tetramer $(\alpha\sb\beta\sb2)$ …
The Relationship Between The Accuracy Of Certain "Generalized" Body Density Prediction Equations And Indices Of Fatness, Body Physique/Proportionality And Fat Distribution., Christopher Melancon Hearon
The Relationship Between The Accuracy Of Certain "Generalized" Body Density Prediction Equations And Indices Of Fatness, Body Physique/Proportionality And Fat Distribution., Christopher Melancon Hearon
LSU Historical Dissertations and Theses
There is a need to eliminate the least accurate of the existing equations for anthropometrical body density prediction and support for the use of specific prediction equations over generalized equations. The purpose of the investigation was to examine the accuracy of the Jackson-Pollock (JP) and Durnin-Womersley (DW) generalized anthropometrical body density prediction equations in relation to indices of overall fatness, regional fat distribution and body proportionality. The relationships between prediction accuracy (predicted body density minus hydrodensitometric estimate of body density) and three mass/stature indices (total fatness indices), waist-to-hip circumference ratio (WC/HC)(android/gynoid fat distribution) and the three components of the Heath-Carter …
Solution Behavior Of Cascade Polymers., Keunok Han Yu
Solution Behavior Of Cascade Polymers., Keunok Han Yu
LSU Historical Dissertations and Theses
This thesis consists of four chapters. In the first, a general introduction is presented. Chapter 2 deals with the characterization of polyamidoamine (PAMAM) cascade polymers. Diffusion coefficients of four different generations (generation 3, 5, 7, and 9) of PAMAMs were measured in aqueous solutions by dynamic light scattering. Generation 3 and 5 were characterized again, after labeling with fluorescein isothiocyanate, by fluorescence photobleaching recovery. The dynamic light scattering results depended on the concentration of added salt in the low salt limit, while the fluorescence values were almost independent of salt concentration. The polyelectrolyte effects, or solution nonidealities, strongly affected light …
X-Ray Absorption And Electron Paramagnetic Resonance Studies Of Azotobacter Vinelandii Nitrogenase., Roland Carroll Tittsworth
X-Ray Absorption And Electron Paramagnetic Resonance Studies Of Azotobacter Vinelandii Nitrogenase., Roland Carroll Tittsworth
LSU Historical Dissertations and Theses
Fe K-edge Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy was used to investigate the metal-cluster structure of both the Mo-containing (Av1) and V-containing (Av1$\sp\prime$) nitrogenase component 1 proteins of Azotobacter vinelandii in their as-isolated and thionine-oxidized states. Using the EXAFS data, plausible distance assignments were made for the cofactor clusters. It was shown that small but consistent distance changes occur in both Av1 and Av1$\sp\prime$ upon thionine oxidation. Furthermore, the EXAFS of Av1$\sp\prime$ is very similar to that of Av1, supporting the proposal that the two proteins have homologous metal cluster structures. Fe K-edge and Mo K-edge EXAFS were used …
Theoretical Studies Of Sodium Metal Clusters., Melissa R. Prince
Theoretical Studies Of Sodium Metal Clusters., Melissa R. Prince
LSU Historical Dissertations and Theses
Theoretical methods were used to study small sodium metal clusters. The goal was to find a simple way to model the electronic structure in these clusters that can be used to study large sodium clusters. Monte Carlo studies using Feynman's path integral formulation of quantum mechanics with Bose-Einstein statistics were used to study sodium metal clusters whose valence electrons with opposite spins were paired as bosons. Next, non-atom-based Gaussian s orbitals were used in a Hartree-Fock Monte Carlo procedure. Based on these results, standard quantum chemistry programs were used to test the utility of using non-atom-based basis sets made up …