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Analysis Of The Effect Of Different Surface Preparation Methods On Corrosion Resistance And Adhesion Strength Of Astm A36 Steel Substrate With Surface Tolerant Epoxy Paint As Coating Material, Irwan Wijaya Santoso, Daffa Aqila, Rini Riastuti, Rizal Tresna Ramadhani

Journal of Materials Exploration and Findings

In the industrial world, to extend the service life of materials, protection methods are carried out to slow down the material's corrosion rate. The protection method that is often used is the coating method. The coating method is a protection method by coating the substrate material using a coating material to prevent contact between the substrate material and the environment. In this research, the substrate material used is ASTM A36 steel and the coating material used is Surface Tolerant Epoxy paint. The independent variable used in this study lies in the surface preparation method which consists of: solvent cleaning, hand …

Tin-Silver As A Novel Biodegradable Metallic Biomaterial, Charley Goodwin

All Dissertations

The Essure device is a non-hormonal, minimally-invasive, permanent female sterilization implant, removed from the market due to an increase in adverse events, hypothesized to be caused by corrosion of the Sn-Ag component of the implant. The goals of this dissertation were to first develop implant retrieval methods for Essure devices and surrounding tissue, documenting signs of degradation and metallic degradation products, then to characterize the electrochemical behavior of Sn-Ag in biologically representative environments and finally, to assess the biological interaction of Sn-Ag. Retrieval analyses developed successful methods, qualifying the degree of corrosion, primarily of the Sn-Ag component and finding Sn …

Study Of Kinetics Of Hydrocarbon Gas Purification With Composite Absorbents, Oybek Aripdjanov, Shavkat Nurullaev, Shodiyakhon Azimova

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the work is to improve the process of natural gas purification from acidic components using a composite absorbent. To study the sorption of acidic components in the gas composition, a chromatographic analysis method was used. The kinetics and rate of corrosion of carbon steel grade st.10 when using composite absorbents MDEA +DEA + AVRP have been studied. The results of the study show that the volume of absorption increased from 0.55 mol/mol to 0.65 mol/mol, and the amount of H₂S in the purified gas decreased from 0.022 g/m³ to 0.014 g/m³. Corrosion …

Corrosion And Passivation Behavior Of Laser Powder Bed Fusion Produced Ti-6al-4v Under Various Prior Plastic Deformation Strains, P. Qin, L. Y. Chen, Y. J. Liu, S. X. Liang, H. Sun, L. C. Zhang

Research outputs 2022 to 2026

This work investigated the corrosion behavior of LPBF-produced Ti-6Al-4V under varying compression strains in a 3.5 wt% NaCl solution. It identifies that increasing compression strain causes significant alterations in the acicular a'-Ti phase (coarsening, breakage, and further coarsening). Corrosion resistance decreases with higher strains due to deformed a'-Ti phases, leading to increased film growth kinetics (from 0.09× 10−10 cm2/s increase to 12.75 × 10−10 cm2/s). Samples under higher strains (e.g., 32%) exhibit fluctuations in corrosion behavior due to initiated cracks and subsequent crevice corrosion. These findings are vital for understanding LPBF-produced Ti-6Al-4V in applications requiring mechanical strength and corrosion resilience.

Effect Of Passivation And Surface Treatment Of A Laser Powder Bed Fusion Biomedical Titanium Alloy On Corrosion Resistance And Protein Adsorption, Saman Nikpour, Jeffrey Henderson, Sina Matin, Heng-Yong Nie, Jonas Hedberg, Vahid Dehnavi, Yara Hosein, David Holdsworth, Mark Biesinger, Yolanda Hedberg

Chemistry Publications

The biomedical titanium alloy Ti6Al4V has excellent corrosion resistance and biocompatibility and is, therefore, widely used in orthopedic and orthodontic implants. Biomedical implants are increasingly fabricated by additive manufacturing, such as laser powder bed fusion (LPBF). These manufacturing protocols often include sandblasting, surface finish, and passivation. This study aims to investigate the effect of different surface finishes and the commonly used ASTM F86-13 nitric acid passivation for LPBF Ti6Al4V on its corrosion resistance, metal release, and surface changes in benign (bovine serum albumin in a pH 7.4 buffer) and harsh (hydrochloric acid at pH 1.5) solutions using various electrochemical and …

Passive Wireless Corrosion And Temperature Detection In High-Temperature Environments, Noah Lane Strader

Graduate Theses, Dissertations, and Problem Reports

This work focuses on the theory and development of LC sensors for high temperature and corrosion measurement for stainless steel and copper surfaces with power industry and general corrosion detection applications. The LC resonators were fabricated via screen printing an Ag inductor on an alumina substrate. The LC design was modeled using the ANSYS HFSS modeling package. The LC passive wireless sensors operate with resonant frequencies centered at 85-110 MHz. The wireless response of the LC sensor was interrogated and received by a radio frequency signal generator and spectrum analyzer at temperatures from 50-800 °C for copper ground planes and …

A Bio-Tribocorrosion Comparison Between Additively Manufactured And Forged Ti6al4v Parts, Sina Matin, Sahar Toorandaz, Saman Nikpour, Hamidreza Abdolvand, Eshan Toyserkani, Yolanda S. Hedberg

Chemistry Publications

Ti6Al4V has been used widely as a biomedical alloy and is increasingly manufactured by additive manufacturing due to customized shapes. As implant material, it is frequently exposed to both friction and corrosive environments. This study investigates the effect of the fabrication process (laser powder bed fusion and forging) on the tribocorrosion behavior of Ti6Al4V in various environments including diluted hydrochloric acid to simulate the acidic environment in a crevice (HCl), phosphate-buffered saline (pH 7.3) with 10 g/L bovine serum albumin (PBS+BSA), and PBS+BSA with 30 mM H2O2. While the presence of BSA hindered the repassivation (reforming of the protective passive …

Effects Of Perforations On Internal Cathodic Protection And Recruitment Of Marine Organisms To Steel Pipes, Alexander John Paluzzi

Theses and Dissertations

Steel monopile support structures for offshore wind turbines require protection from corrosion on their external and internal surfaces. Cathodic protection (CP) works effectively to protect the external surfaces of monopiles, but internally, byproducts from aluminum sacrificial anode CP (SACP) and impressed current CP (ICCP) induce acidification that accelerates steel corrosion. This project investigated the effects of perforations on the performance of aluminum SACP and ICCP when used inside of steel pipes. Additionally, marine growth on the external and internal surfaces of the pipes was assessed to determine if CP byproducts affect marine organism development.

Two sealed and two perforated steel …

Ti-6al-4v Β Phase Selective Dissolution: In Vitro Mechanism And Prediction, Michael A Kurtz

All Dissertations

Retrieval studies document Ti-6Al-4V β phase dissolution within total hip replacement systems. A gap persists in our mechanistic understanding and existing standards fail to reproduce this damage. This thesis aims to (1) elucidate the Ti-6Al-4V selective dissolution mechanism as functions of solution chemistry, electrode potential and temperature; (2) investigate the effects of adverse electrochemical conditions on additively manufactured (AM) titanium alloys and (3) apply machine learning to predict the Ti-6Al-4V dissolution state. We hypothesized that (1) cathodic activation and inflammatory species (H₂O₂) would degrade the Ti-6Al-4V oxide, promoting dissolution; (2) AM Ti-6Al-4V selective dissolution would occur …

Mechanisms Contributing To Hydrogen-Influenced Early Failure Of Bridge Tendons, David Dukeman

USF Tampa Graduate Theses and Dissertations

Failures in post-tensioned tendons have occurred without warning due to fractures in the high-strength steel strands. These strands are cold-drawn to increase their strength while still retaining the preferential ductile mode of fracture. Recently, a tendon failure that occurred in an upper deviation block of the I-526 James B. Edwards bridge crossing the Wando river showed signs of corrosion and potentially another method of failure, hydrogen embrittlement. One proposed source of hydrogen is through galvanic coupling that may exist between the galvanized steel duct and the steel strands. This coupling, if substantial, can promote hydrogen evolution at the steel strand's …

Corrosion Of Oil Pipeline: A Case Study On The Niger Delta Region Of Nigeria., Victor U. Okoro

Corrosion Research

Corrosion of oil pipelines in Nigeria, particularly in the Niger Delta region, has extensive and detrimental environmental and societal impacts. This issue results in substantial financial losses and reputational damage for oil companies operating in the area. Local communities suffer economically, affecting agriculture and food security. Furthermore, corrosion-related oil spills lead to air quality degradation by releasing volatile organic compounds and greenhouse gases, contributing to respiratory issues and worsening climate change.

These oil spill cleanups are costly and time-consuming, with estimated expenses reaching billions of dollars. Using the Nembe Creek Trunk Line (NCTL) case study, it is evident that addressing …

Impact Assessment Of The Washington D.C. And Flint, Michigan Water Crises, Waruni G. K Senanayake

Corrosion Research

No abstract provided.

Comparison Between Washington D.C. And Flint Crises, Waruni G. K Senanayake

Corrosion Research

No abstract provided.

Evaluation Of Residual Flexural Behavior Of Corroded Fiber-Reinforced Super Workable Concrete Beams, Jingjie Wei, Nima Farzadnia, Alfred Addai-Nimoh, Kamal Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This Study Investigates the Effect of Macro Synthetic Fiber (MSF) Volume and Crack Widths on Corrosion of the Reinforcing Bars and Residual Flexural Behavior of Fiber-Reinforced Super-Workable Concrete (FR-SWC) Beams Exposed to Accelerated Corrosion. FR-SWC Beams Prepared with 0, 0.33%, and 0.66% MSF Were Pre-Cracked at 0.2-, 0.4-, and 0.75-Mm Widths Before Corrosion Testing. the Controlled Crack Width Was Initiated in One Set of Beams that Were Then Unloaded. the Crack Width Was Maintained for Another Set of Beams during Corrosion Testing by Inserting a Shim. Test Results Showed that the Use of 0.33% and 0.66% MSF Reduced Crack Development …

Evaluation Of The Oxidation Process Of Steel Fibers In The Presence Of A Potato Dextrose And Calcium Chloride Solution For The Self-Healing Of Cementitious Matrices, Nahúm Gamalier Cayo Chileno, Gabrielle Avelar Silva, Laércio Mesquita Júnior, Saulo Rocha Ferreira, Maria Alves Ferreira, Joaquin Humberto Aquino Rocha, Jacinta Veloso De Carvalho, Gabriele Melo De Andrade

UBT International Conference

The objective of the research was to experimentally examine the corrosion of steel fibers in two media: a solution containing potato dextrose and calcium chloride (S1) (nutrient of the biological agent Oomicetum Pythium aphanidermatum that facilitates the self-healing of cementitious matrices), and water (S2). The corrosion process was accelerated by the Cebelcor method for 15 days, with immersion/emersion cycles of 5 and 19 hours, respectively. The results revealed that the corrosion of the fibers in solution S1 was 10.64% higher than that in S2. Regarding cross-sectional loss, the corroded fibers in S2 showed linear behavior, unlike those in S1, which …

Comparative Assessment Using Machine Learning Algorithms For Ultimate Bond Strength Estimations, Lukesh Veloso De Parida, Sumedha Melo De Moharana, Sourav Kumar Giri

UBT International Conference

Corrosion-induced bond strength reduction is a critical problem in infrastructure maintenance and repair. This study investigates several machine learning techniques, i.e., SVR, XG Boost, and random forest, for predicting the ultimate bond behavior between corroded reinforcement and concrete. In this study author employed 218 datasets of corroded samples collected from past studies containing input and output parameters used for predicting the models. The model's performance was evaluated and compared using various performance metrics, i.e., MAE, RMSE, MAPE, and MASE. The results show that random forest algorithms can reliably estimate ultimate bond strength with an RMSE value of 1.26 over SVR …

Corrosion Case Study On Historical Monuments, Maryam Khalilvand Nahid

Corrosion Research

No abstract provided.

Supercritical Water Gasification (Scwg) Of Lignocellulosic Biomass For Hydrogen Production: Reaction Kinetics And Corrosion Performance Of Candidate Constructional Alloy, Haoyang Li

Electronic Thesis and Dissertation Repository

Supercritical water gasification (SCWG) holds immense promise as a sustainable and efficient method for green hydrogen production from lignocellulosic biomass, contributing to the transition from a petroleum-based economy towards bioeconomy.

Understanding the kinetics of SCWG processes is critically important for future development and scale-up applications of the SCWG technology. In this thesis work, we developed a general kinetic model to predict the yields of gases from SCWG of various lignocellulosic feedstocks with varying contents of cellulose, hemicellulose, and lignin. Subsequently, a comparison study was conducted between the SCWG of biomass in a batch and a self-built continuous-flow reactor. We discussed …

Corrosion Related To The Nuclear Waste Containers, Ali Ebrahimzadeh Pilehrood

Corrosion Research

The disposal of nuclear waste is a demanding topic, and the existing methods, whether it is temporary storage in spent fuel pools or storage in geological repositories, both face the risk of corrosion-related problems. Any failure in these storage methods can potentially lead to the release of radioactive materials into the environment. To avert such catastrophic scenarios, people in the nuclear industry consistently monitor and maintain these storage facilities endlessly and attempt to improve the plans designed to store nuclear waste. Here, I will examine the nuclear waste management organization (NWMO) plan in Canada. Choosing an appropriate location for the …

Corrosion Case Study On Pipeline - Economic And Environmental Assessment, Kangze Ren

Corrosion Research

The corrosion issue, which was difficult to tackle as the former Soviets had predicted in the first place, was not appropriately addressed by the colonialism-tailored oil production, resulting in astronomical budget blow-out and environmental disaster in the North Caspian Sea region. Unfortunately, limited information on the pipeline leaking accidents regarding the project cost, social impact, and environmental impact was released to the public. The purpose of the review is to draw attention to the Kashagan pipeline leaking accidents, the factors that influence corrosion management for oil production, and the consequences of not adopting proper corrosion control.

Corrosion Case Study On Pipeline, Kangze Ren

Corrosion Research

The Kashagan pipeline leaks were likely caused by sulfur stress corrosion cracking, a combined corrosion mechanism developed by the presence of high pressure, the high level of hydrogen sulfide(the main "ingredient" of sour gas), and poor metallurgical choice. Improper welding and poor metallurgical examination were blamed for causing the leaking issue. The purpose of the current review is to raise the alarm about the inappropriate corrosion management of Kashagan oil production and its societal and environmental consequences.

The Impact Of Lead Corrosion Relating To The Contamination Of Drinking Water In Canada And In Indigenous Communities., Jessie A. Mcdonald

Corrosion Research

No abstract provided.

The Impact Of Lead Corrosion Relating To The Contamination Of Drinking Water In Canada And In Indigenous Communities., Jessie A. Mcdonald

Corrosion Research

No abstract provided.

Application Of Wavelet Analysis And Random Field In Integrity Management Of Pipelines Containing Dents And Corrosions, Junxiong Lin

Electronic Thesis and Dissertation Repository

Metal loss corrosions and dents are two major threats to the integrity of oil and natural gas pipelines. In the pipeline industry, the Fitness-For-Service (FFS) assessment is commonly employed for pipelines containing these defects. However, FFS assessment usually assumes that a defect has a simple shape, and such a simplification may significantly affect the accuracy of the assessment. Therefore, retaining the actual shapes of defects and incorporating them into the FFS assessment can improve assessment accuracy. The main objective of the present thesis is to extract key information about the sizes, directions, and shapes of corrosions and dents from the …

The Effect Of Hydrogen Peroxide On The Corrosion Dynamics Of Carbon Steel, Kwang Soak Gabriel O'Donnell

Electronic Thesis and Dissertation Repository

The Used Fuel Container (UFC) is a key barrier in Canada’s nuclear fuel disposal plan. Understanding the radiation-induced corrosion of the carbon steel (CS) vessel is critical for predicting the long-term integrity of the UFC. Developing a mechanistic understanding of CS corrosion and the effect of solution parameters is essential.

This work investigates the effects of H₂O₂, the key radiolytic oxidant, on CS corrosion dynamics in small, stagnant solutions. Elementary processes are identified, corrosion rates are calculated, and the effects of H₂O₂ concentration are investigated. Corrosion was studied by quantifying the concentrations of …

Predicting Corrosion Damage In The Human Body Using Artificial Intelligence: In Vitro Progress And Future Applications Applications, Michael A. Kurtz, Ruoyu Yang, Mohan S. R. Elapolu, Audrey C. Wessinger, William Nelson, Kazzandra Alaniz, Rahul Rai, Jeremy L. Gilbert

Publications

Artificial intelligence (AI) is used in the clinic to improve patient care. While the successes illustrate the impact AI can have, few studies have led to improved clinical outcomes. A gap in translational studies, beginning at the basic science level, exists. In this review, we focus on how AI models implemented in non-orthopedic fields of corrosion science may apply to the study of orthopedic alloys. We first define and introduce fundamental AI concepts and models, as well as physiologically relevant corrosion damage modes. We then systematically review the corrosion/AI literature. Finally, we identify several AI models that may be Preprint …

Extending The Service-Life Of Bridges Using Sustainable And Resilient Abutment Systems: An Experimental Approach To Electrochemical Characterization Of Lightweight Mechanically Stabilized Earth, Fariborz M. Tehrani, Kenneth L. Fishman, Farmehr M. Dehkordi

Mineta Transportation Institute

Bridges are critical components of transportation infrastructure. This research addresses the need to extend the service life of bridges by improving the safety and reliability of bridge abutments and reducing their life-cycle cost and footprints. Mechanically stabilized earth (MSE) is a known strategy to enhance the economy and performance of bridge abutments. In addition, the application of rotary-kiln-manufactured lightweight aggregate backfills improves the performance of MSE bridge abutments with a leaner structural system. Such improvements include a reduction of structural demands due to a lower density, free drainage of granular materials, a high internal friction angle, less settlement with no …

The Influence Of Bio-Inhibitor On The Corrosion Resistance Of Reinforced Concrete Beams Containing Mswi-Ba As A Partial Sand Replacement, Jamal Khatib, Israa Amer, Ghanem Hassan, Adel Elkordi

BAU Journal - Science and Technology

In this paper, the corrosion behavior of reinforced concrete beams containing municipal solid waste incineration bottom ash (MSWI-BA) as a partial sand replacement and Ceratonia siliqua extract as a green corrosion inhibitor was investigated. Four mixes were prepared: (0 and 20% replacement of sand by MSWI-BA with and without Ceratonia siliqua extract). Tests conducted were UPV, compressive strength, split tensile strength, and elastic modulus. RC beams were prepared for determining the flexural performance. Eight beams were casted. Four beams were exposed to accelerated corrosion test and four beams were kept at room temperature. It was found that the compressive strength, …

Skin Permeation Studies Of Chromium Species - Evaluation Of A Reconstructed Human Epidermis Model., L Hagvall, M Munem, M Hoang Philipsen, M Dowlatshahi Pour, Yolanda S. Hedberg, P Malmberg

Chemistry Publications

A reconstructed human epidermis (RHE) model, the EpiDerm, was investigated and compared to human skin ex vivo regarding tissue penetration and distribution of two chromium species, relevant in both occupational and general exposure in the population. Imaging mass spectrometry was used in analysis of the sectioned tissue. The RHE model gave similar results compared to human skin ex vivo for skin penetration of Cr

Coating Condition Detection And Assessment On The Steel Girder Of A Bridge Through Hyperspectral Imaging, Pengfei Ma, Jiaoli Li, Ying Zhuo, Pu Jiao, Genda Chen

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The organic coating of bridge steel girders is subjected to physical scratches, corrosion, and aging in natural weathering. The breakdown of the coating may cause serviceability and safety problems if left unnoticed. Conventional coating inspection is time-consuming and lacks information about the coating's chemical integrity. A hyperspectral imaging method is proposed to detect the condition of steel coatings based on coating-responsive features in reflectance spectra. A field test was conducted on the real-world bridge, which shows obvious signs of degradation. The hyperspectral signature enables an assessment of the coating's health and defect severity. The results indicated that the coating scratch …