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Tris(Dialkylamino)Aluminums: Syntheses, Characterization, Volatility Comparison, And Atomic Layer Deposition Of Alumina Thin Films, Casey R. Wade, Carter Silvernail, Chiranjib Banerjee, Axel Soulet, James Mcandrew, John A. Belot Jr. Dec 2007

Tris(Dialkylamino)Aluminums: Syntheses, Characterization, Volatility Comparison, And Atomic Layer Deposition Of Alumina Thin Films, Casey R. Wade, Carter Silvernail, Chiranjib Banerjee, Axel Soulet, James Mcandrew, John A. Belot Jr.

Chemistry Department: Faculty Publications

The syntheses and characterization of both tris(diethylamino)aluminum and tris(diisopropylamino)aluminum are presented in this letter. Characterization includes vapor pressure measurements and comparison of the two non-pyrophoric precursors showing them to be viable alternatives to trimethylaluminum. Ultimately, tris(diisopropyl)aluminum was successful in the atomic layer deposition of alumina thin films.


Prerapation And Supercapacitor Property Of Al Doped Co_3o_4, Xin Ge, Ye Chen, Chun-Xia Zhang, Chang Shu Aug 2007

Prerapation And Supercapacitor Property Of Al Doped Co_3o_4, Xin Ge, Ye Chen, Chun-Xia Zhang, Chang Shu

Journal of Electrochemistry

With KOH as precipitator to prepare Aluminum doped Co3O4,X-ray diffraction indicated that the doping Al did not change the crystal structure of Co3O4.Electrochemical properties of the sample were tested by cyclic voltammetry and constant-current charge/discharge.The results showed that the chemical doping improved the specific capacitance.When the mol ratio of Co(Ⅱ) with Al(Ⅲ)was 1∶0.05,the specific capacitance was up to 518.07 F/g within 0~400 mV potenitial at current density 5 mA/cm2.


Simulation Of Microporosity In Aluminum Plate Castings, Enrique R. Escobar De Obaldia May 2007

Simulation Of Microporosity In Aluminum Plate Castings, Enrique R. Escobar De Obaldia

Theses and Dissertations

Porosity is known to be one of the primary factors controlling fatigue life and total elongation in cast aluminum components. The thrust of this study is to examine pore nucleation and growth effects for predicting gas microporosity in A356 plates. In this work, a solidification model is used to quantify and evaluate the discrepancy between experimental data and porosity calculated with different approaches. The first approach considers hydrogen supersaturation based on the transport of dissolved hydrogen and Sievert?s law. The second approach uses the hydrogen supersaturation calculated in the first approach combined with a local solidification time. The third approach …


An Investigation Of Wear-Resistant Coatings On An A390 Die-Cast Aluminum Substrate, D. Adam Mower Mar 2007

An Investigation Of Wear-Resistant Coatings On An A390 Die-Cast Aluminum Substrate, D. Adam Mower

Theses and Dissertations

In this investigation, four coatings were tested for their ability to increase the wear life of A390 aluminum primary clutch sheaves used in continuously variable transmission (CVT). The coatings tested were: hard chrome, electroless nickel metal, hard coat anodizing and composite ceramic coating. The primary clutch sheave material is a die-cast A390 aluminum. A wear test stand was developed to duplicate wear found on CVTs currently in use. The wear was evaluated using four methods. First, the change in shift characteristics of the CVT while running on the wear test stand, second a change in performance using an ATV and …


Kegs, Crude, And Commodities Law: On Why It Is Time To Reexamine The Suitability Doctrine, Andrew M. Pardieck Mar 2007

Kegs, Crude, And Commodities Law: On Why It Is Time To Reexamine The Suitability Doctrine, Andrew M. Pardieck

Nevada Law Journal

No abstract provided.


Human Health Risk Assessment For Aluminium, Aluminium Oxide, And Aluminium Hydroxide, Daniel Krewski, Robert A. Yokel, Evert Nieboer, David Borchelt, Joshua Cohen, Jean Harry, Sam Kacew, Joan Lindsay, Amal M. Mahfouz, Virginie Rondeau Jan 2007

Human Health Risk Assessment For Aluminium, Aluminium Oxide, And Aluminium Hydroxide, Daniel Krewski, Robert A. Yokel, Evert Nieboer, David Borchelt, Joshua Cohen, Jean Harry, Sam Kacew, Joan Lindsay, Amal M. Mahfouz, Virginie Rondeau

Pharmaceutical Sciences Faculty Publications

A compendium is provided of aluminium compounds used in industrial settings, and as pharmaceuticals, food additives, cosmetics and as other household products. Most aluminium compounds are solids exhibiting high melting points. The solubility of aluminium salts is governed by pH, because the aluminium(III)-cation (Al3+) has a strong affinity for the hydroxide ion, which promotes precipitation. Like Mg2+ and Ca2+ ions, Al3+ in most situations seeks out complexing agents with oxygen-atom donor sites such as carboxylate and phosphate groups, including in biological systems. Aluminium oxides, hydroxides and oxyhydroxides occur in numerous crystallographic forms, which exhibit different …


Zsm-5 Coatings On β-Sic Monoliths: Possible New Structured Catalyst For The Methanol-To-Olefins Process, B. Madani, S. Ivanova, B. Louis, Jean-Philippe Tessonnier, M. J. Ledoux, C. Pham-Huu Jan 2007

Zsm-5 Coatings On β-Sic Monoliths: Possible New Structured Catalyst For The Methanol-To-Olefins Process, B. Madani, S. Ivanova, B. Louis, Jean-Philippe Tessonnier, M. J. Ledoux, C. Pham-Huu

Jean-Philippe Tessonnier

Structured zeolite/silicon carbide composites were succesfully synthesized by ZSM-5 coatings deposited on macroscopic â-SiC foams with medium surface area. A homogeneous coverage of the support (30 wt % zeolite) by ZSM-5 crystals, having 1 ím average size, was reached after a double-coating procedure. The ZSM-5/â-SiC composite materials were characterized by BET, XRD, SEM, and H/D exchange methods. 27Al MAS NMR analysis revealed that all aluminum was present in a tetrahedral coordination, thus sitting in the zeolite framework. The existence of a nanoscopic layer of silica and silicon oxycarbide on the surface of the support ensures the strong anchoring of the …