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The Peculiar Nature Of Florida’S Sandhill Wetlands, Ponds & Lakes— Their Ecohydrology, Relationship With The Regional Aquifer & Importance Within The Landscape., Renae Starr Nowicki

USF Tampa Graduate Theses and Dissertations

This dissertation explores the ecohydrology of Florida’s peculiar and poorly studied sandhill wetland and water features, particularly those located in west-central Florida. The primary research goals include: compilation and summarization of the available ecohydrologic information for features across Florida; comparison of water level and water geochemistry data between sandhill wetlands and waters and the regional aquifer to provide evidence of regional hydrologic control; and use of geophysical applications to examine the hydraulic connections between sandhill wetlands and waters and the regional aquifer.

From this research, a natural history of sandhill wetland and water ecohydrology is presented, highlighting: the differences between …

Effects Of Reservoir Conditions And Trace Co-Contaminant Gases On Geological Carbon Sequestration, Ram Kumar

USF Tampa Graduate Theses and Dissertations

Geological carbon sequestration in a saline formation is a promising technology for large-scale carbon dioxide (CO2) mitigation. Several factors such as temperature, pressure, salinity, hydraulic conductivity, and mineralogy of a formation affect the CO2 sequestration in saline formations. These factors can vary widely depending upon the type of formation or the degree of heterogeneity within a formation. In addition to these properties of the repositories, the CO2-rich flue gas streams captured from point sources often contains small amounts of impurities such as sulfur oxides (SOx) and nitrogen oxides (NOx), which may have serious implications on the chemistry of the repositories …

Boron Variation And The Subducted Sediment Component In The Volcanics From The Bifurcated Portion Of The Lesser Antilles Island Arc (Laia), Ami Margret Ngo Ward

USF Tampa Graduate Theses and Dissertations

North of Martinique island the Lesser Antilles volcanic arc bifurcates, creating a double arc. Here volcanic activity has migrated up to 50 km westward with time, resulting in two volcanic lines that are distinct in age. The eastern line, commonly referred to as the old arc, was active from Early Eocene to Mid-Miocene (Nagle, 1971; Nagle et al., 1976; Westercamp and Tazieff, 1980; Andreieff et al., 1988). The western line, commonly referred to as the recent arc, has been active since the late Pliocene, ~6 Ma ago (Nagle, 1971; Nagle et al., 1976; Westercamp and Tazieff, 1980; Andreieff et al., …

On The Ablation Of Meteors And The Implications On Organic Delivery To Earth, Christopher Alan Mehta

USF Tampa Graduate Theses and Dissertations

The synthesis of prebiotic organic compounds is a key step in the origin of life. Sources of these materials are divided into endogenous and exogenous sources. Endogenous synthesis—occurring potentially on the surface of the Earth—includes such historic experiments as the Miller spark discharge and formose chemistry. However, one avenue for exogenous synthesis to occur is when meteors enters an atmosphere. Using principles of orbital mechanics, geology, physics, and chemistry, we study meteor ablation and the transport of organic matter to the surface of Earth. To do so, I create numerical models that simulates meteors traveling through the atmosphere of Earth …

The Lampenflora In Show Caves And Its Treatment: An Emerging Ecological Problem, Carlos Baquedano Estévez, Luis Moreno Merino, Almudena De La Losa Román, Juan J. Durán Valsero

International Journal of Speleology

The artificial lighting of caves adapted for touristic visits, leads to the appearance and propagation of a complex community of phototrophic organisms known as “lampenflora”. Formed mainly by algae and cyanobacteria, they produce the degradation of the colonized substrates and decrease the show value of the caves. This phenomenon became famous worldwide in the 1960s due to the damage caused to the paintings in the Lascaux Cave (France). Since then it has become an issue of serious concern to both managers of show caves and to the international scientific community. Over time, the problem has been approached following two complementary …

Genesis Of Iron And Manganese Sediments In Zoloushka Cave (Ukraine/Moldova) As Revealed By Δ13C Organic Carbon, Piotr Kotula, Viacheslav Andreychouk, Jacek Pawlyta, Leszek Marynowski, Izabela Jendrzejewska

International Journal of Speleology

Zoloushka Cave is one of the largest maze gypsum caves in the world. Mining of the gypsum bedrock and lowering of the water level due to the pumping of groundwater led to exposure of the cave passages to vadose conditions and changed the hydrochemistry of the karst water. As a result, large quantities of Fe and Mn hydroxides were deposited in the passages. It was found that at least two groups of various organisms were involved in depositing ferrous and manganese sediments. In order to establish the mechanism of deposition, we conducted chemical analyses of the sediments and isotopic analyses …

Multi-Phased Hypogene Speleogenesis In A Marginal Horst Structure Of The Malé Karpaty Mountains, Slovakia, Pavel Bella, Pavel Bosák, Petr Mikysek, Juraj Littva, Helena Hercman, Jacek Pawlak

International Journal of Speleology

The Plavecká jaskyňa Cave on the western fault edge of the Malé Karpaty Mountains (western Slovakia) is a result of multi-phased hypogene speleogenesis. It formed in fractured Triassic carbonates by waters ascending along the Vienna Basin Transform Fault between Malé Karpaty Mountains and Záhorská nížina Lowland (the north-eastern part of the Vienna Basin) and/or the N–S-trending faults that intersect it in the cave vicinity. Morphologically, the cave is featured by (1) phreatic chimneys, cupolas, ceiling pockets, enlarged fissures with spongework cavities, upward wall channels and upward oriented large scallops, (2) epiphreatic flat corrosion bedrock floors, feeding fissures and wall water-table …

Fluid-Mobile Trace Element Variability Of Serpentinites And Entrained Crustal Rocks Across The Mariana Forearc System, Raymond M. Johnston

USF Tampa Graduate Theses and Dissertations

In the Mariana subduction system, active serpentinite mud volcanoes are associated with the subduction of the Pacific plate beneath the Philippine plate in a non-accretionary convergent plate margin. This location offers a unique opportunity to study the subduction zone interface with little crustal contamination. The systematics of fluid-mobile trace elements (FME) (As, Cs, Rb, Sb, Tl, Pb, and Sr) in erupted serpentinite muds and entrained serpentinized ultramafic and mafic clasts can place constraints on the release of slab-derived fluids from the downgoing plate, and ultimately the pressure/temperature (P/TC°) conditions at which these fluids are mobilized.

The samples analyzed in this …

Breakdown Mechanisms In Iron Caves. An Example From Brazil, Marcelo R. Barbosa, Allan D.F. Da Silva, Rafael G. De Paula, Georgete M. Dutra, Airton Barata, Iuri V. Brandi, Chrystophe R.P. Da Silva, Robert A. Osborne

International Journal of Speleology

An iron cave in the vicinity of a mine in Carajás, Brazil, was selected to be mined within an assisted elimination project, planned to control all mine advancement operations towards the cave along with a strict speleological physical monitoring. It allowed, in a pioneering way, the recording of events in the cave from the first signs of damage until to the total collapse of the cave. The project lasted four years and it was possible to identify and describe four breakdown mechanisms in iron caves: Fragment downfall, Block downfall, Controlling structure reactivation, and Open discontinuity movement. The mechanisms occurred independently …

Stable Isotope Geochemistry Of Shelled Marine Invertebrates: Wide-Ranging Applications, Nasser M. Al-Qattan

USF Tampa Graduate Theses and Dissertations

Mollusks grow by adding discrete growth layers throughout their lifetime (i.e., accretion). More specifically, most marine mollusks precipitate their shells in oxygen isotopic equilibrium with seawater or with a constant offset from equilibrium. The stable oxygen isotope values (δ¹⁸O) of their shells are determined by the temperature and δ¹⁸O values of the surrounding water during calcification without significant vital effects. In comparison, the stable carbon isotope values (δ¹³C) of their shells reflect those of the dissolved inorganic carbon (δ¹³C- DIC) and respired carbon dioxide. Therefore, variations in the oxygen and carbon isotope …

Modeling And Assessing Lava Flow Hazards, Elisabeth Gallant

USF Tampa Graduate Theses and Dissertations

Lava flow hazards are one of the few constant themes across the wide spectrum of volcanic research in the solar system. These dynamic hazards are controlled by the location of the eruption, the topography and material properties of the land upon which the flow spreads, and the properties of the lava (e.g., volume, temperature, and rheology). Understanding the influences on eruption location and how lava flows modify the landscape are important steps to accurately forecast volcanic hazards. Three studies are presented in this dissertation that address di˙erent aspects of modeling and assessing vent opening and lava flow hazards.

The first …

Framing Geologic Numeracy For The Purpose Of Geoscience Education: The Geoscience Quantitative Preparation Survey, Victor J. Ricchezza

USF Tampa Graduate Theses and Dissertations

The Geoscience Quantitative Preparation Survey (GQPS) was developed to address a deficiency in the available literature regarding the competency and preparation of early-career geologists in geoscience job-related quantitative skills – namely, geologic numeracy. The final version of the GQPS included self-confidence, usage, satisfaction, and demographic sections. The GQPS was expected to produce data that would allow for an evaluation of the geologic numeracy of early-career geologists and the success of approximately 20 years of increased focus on quantitatively literate geoscience graduates.

The self-confidence section of the GQPS included quantitative methods and quantitative skills. The usage section asked whether participants used …

Tracking Sediment Bypassing, Geomorphological Analysis, And Regional Sediment Management At Tidal Inlets, Tanya M. Beck

USF Tampa Graduate Theses and Dissertations

Tidal inlets on sandy shorelines separate barrier islands and serve as a conduit for transport of sand and water between embayments and oceans, seas, or other tidally influenced waterbodies. Tides and waves induce currents along the coastline that transport sediment across-shore and alongshore. Coastal managers must optimize barrier-inlet system stability while conserving limited sediment resources, and often base management decisions and engineering design upon geomorphic and numerical models that predict the morphological behavior of tidal inlets on short-to-medium timescales (years to decades). The overall goal of this study was threefold. First, to provide science-based practical guidance for regional sediment management …

Rethinking Map Literacy And An Analysis Of Quantitative Map Literacy, Ming Xie

USF Tampa Graduate Theses and Dissertations

Maps are increasingly being used in traditional and virtual media, and civic discourse on political, social, and environmental issues, among others, is more and more becoming influenced by them. The often-used expression of a “picture tells a 1000 words” has never been so apt in our progressively more visual world. Despite this increased role and importance of maps, map literacy, as a field of research, remains rather underdeveloped. This is especially so for thematic maps, the very type of map that is finding increasing currency in discourse. As part of this under-developed nature of map literacy, the quantitative skills used …

Documenting Evolution: Comparing And Contrasting Late Mesozoic And Late Cenozoic Molluscan Patterns, Joshua Slattery

USF Tampa Graduate Theses and Dissertations

Despite major advances, evolutionary theory still has numerous shortcomings in terms of fully understanding the controls on speciation and diversification. A major factor limiting our knowledge is how biology and paleobiology view speciation from separate micro- and macro-evolutionary perspectives, respectively. Biologists typically examine microevolutionary changes within species from various biogeographic, behavioral, morphological, and genetic perspectives, which contrasts to the macroevolutionary approach of most paleobiologists, who have examined the same phenomena at larger scales but with the standpoint of time, have also concentrated on aspects of global or regional diversification (e.g., richness, origination rates, and extinction rates) over the long-term. Noticeably …

Volcanic Electrification: A Multiparametric Case Study Of Sakurajima Volcano, Japan, Cassandra M. Smith

USF Tampa Graduate Theses and Dissertations

Electrical activity at volcanoes has been recently recognized as a potential new remote sensing technique for plume-forming eruptions. Volcanic electrical activity takes place in the conduit and plume and therefore has the benefit of being a direct indicator of surface activity. This is unlike seismic signals, which indicate magma/gas movement underground, and infrasound signals, which indicate a surface explosion but not necessarily the formation of an ash plume. There are two distinct types of volcanic electrical discharges: volcanic lightning and continual radio frequency (CRF) impulses. This dissertation explores the relationships between these two electrical signals and other commonly monitored volcanic …

High-Resolution Investigation Of Event Driven Sedimentation: Response And Evolution Of The Deepwater Horizon Blowout In The Sedimentary System, Rebekka A. Larson

USF Tampa Graduate Theses and Dissertations

This Dissertation combines the investigation of the sedimentological impacts of the Deepwater Horizon (DwH) blowout event in the deep-sea benthos, with the refinement and advancement of methods and approaches for high-resolution investigations of events preserved in sedimentary records. An approach that combined, rapid collection of cores, a continued annual time series collection of cores, and high-resolution sampling and analyses, in particular short-lived Radioisotopes (SLRad), enabled the temporal resolution required to detect the sedimentary response to the short-duration DwH event, and evaluate post-event sedimentation patterns at a comparable time scale (months).

The collection of 179 sediment cores from 80 sites between …

Variations Of Sedimentary Biogenic Silica In The Gulf Of Mexico During The Deepwater Horizon And Ixtoc-I Oil Spill., Jong Jin Lee

USF Tampa Graduate Theses and Dissertations

The goal of this research is to understand the impacts of the 2010 Deepwater Horizon oil spill and the 1970-1980 IXTOC-I oil spill and other anthropogenic activity (e.g. dam construction) on surface water primary productivity by measuring sedimentary biogenic silica. It is known that sedimentary biogenic silica is distinct from mineral – bound silica, therefore it has been used as a proxy record for surface water primary productivity (e.g. diatom blooms). The Deepwater Horizon oil spill resulted in a widespread Marine Oil Snow Sedimentation and Flocculent Accumulation (MOSSFA) event. The IXTOC-I oil spill was one of the largest oil spills …

Examining The Spatial And Temporal Variations In Co2 Partial Pressure In The Deep Vadose Zone Above Jinapsan Cave, Guam, Jamar Regis

USF Tampa Graduate Theses and Dissertations

Carbon dioxide is the primary driver of dissolution and precipitation reactions in epigene limestone caves. While much work has been conducted on CO2 dynamics involved in dissolution in the phreatic zone, less research has been conducted on vadose CO2 dynamics, especially in tropical caves developed in eogenetic limestones. In this study, we investigate spatial and temporal variation in pCO2 in the deep vadose zone of eogenetic limestone above Jinapsan Cave, located in northern Guam. Five years of carbonate chemistry data from three dripwater sites in Jinapsan Cave (Flatman, Station1, and Trinity) were used to model the theoretical pCO2 with which …

Assessing Paleo-Coastal Caves Evolution And Sea Level Changes In Mallorca: Results From Radiometric Dating Of Speleothems, Giuseppe Lucia

USF Tampa Graduate Theses and Dissertations

Sea level affects the littoral morphology and structure in different ways. In coastal karst basins, dissolutional and depositional processes are strictly related to sea level variation. A great variety of karst-related geomorphological features and cave deposits exist above, below, and at sea level, and are extremely useful to study past changes of relative sea level. Within these, vadose speleothems such as flowstones and stalagmite, can document unequivocal maximum sea level constraints as well as record phreatic phases of sea level rise. Here we present a series of geochronological data from the eastern Mallorca and show the implication of relative sea …

Modeled Affinity Constants For Phosphorus Adsorption And Desorption Due To Saltwater Intrusion, Yasemin Taşcı

USF Tampa Graduate Theses and Dissertations

It is important to understand the processes that regulate phosphorus (P) fluxes to coastal environments, because P is an important nutrient in coastal ecosystems. Phosphorus adsorbs to the surface of minerals in sediment and bedrock, and an influx of seawater can cause some of that P to desorb, raising the P concentration of ambient water. Although seawater-induced P desorption is thought to be an important source of P to coastal environments, the chemical reactions that underlie it have not been established. Previous work provides some relevant surface reactions and associated affinity constants between various aqueous P species and the surface …

Timing And Rates Of Events In The Generic Volcanic Earthquake Swarm Model, Tianyu Rong

USF Tampa Graduate Theses and Dissertations

In this thesis I combine data from 29 volcanic earthquake swarms that follow the pattern predicted by the Generic Volcanic Earthquake Swarm Model (GVESM; Benoit and McNutt, 1996) to investigate whether the relative timing of various parameters of pre-eruptive volcanic earthquake swarms could be used to forecast the time of an impending eruption. Based on the analysis of seismic unrest preceding many eruptions, the GVESM suggests that it is common to see an increase first in high-frequency earthquakes, then low-frequency earthquakes, then the onset of volcanic tremor. While this pattern is useful to volcano-seismologists, the relative timing and durations of …