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2006

University of South Florida

Ettringite

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Effect Of Tricalcium Silicate Content On Expansion In Internal Sulfate Attack, Troy T. Whitfield Jun 2006

Effect Of Tricalcium Silicate Content On Expansion In Internal Sulfate Attack, Troy T. Whitfield

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to determine the cementitious parameters and placement temperature that impact internal sulfate attack in concrete. Concrete structures make up a large percentage of the infrastructure and multifamily housing. Durability is very important. Cements can be formulated to reduce the impact of external environmental exposure such as high salinity from marine environments or high sulfate levels from soils or surface waters. Concrete is also subject to internal attack such as alkali aggregate reaction, (AAR), and delayed ettringite formation, (DEF). This study focused on some of the cement chemistry issues that determine susceptibility of cement to …


Effect Of Alkalis And Sulfates On Portland Cement Systems, Mahmoud Halaweh Jun 2006

Effect Of Alkalis And Sulfates On Portland Cement Systems, Mahmoud Halaweh

USF Tampa Graduate Theses and Dissertations

The effect of the sulfates and alkalis on the durability of Portland cement systems was investigated through a series of cube and prism mixes. Durability was assessed using expansion of mortar prisms and the compressive strength of mortar cubes. The study covered a large range of both alkali and sulfate contents using 5 different Portland cements. The alkali contents ranged from 0.27 to 3.8%, the sulfate content (as SO3) ranged from 2.54 to 5%. Doping was done using Terra Alba gypsum and potassium hydroxide. In addition to physical measurements, SEM, XRD, chemical analysis and heat of hydration calorimetry were used …