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Nickel(Ii) And Cobalt(Ii) Nitrate And Chloride Networks With 2-Aminopyrimidine, Robert D. Pike, Mi Jung Lim, Ellen A. L. Wilcox, Tristan A. Tronic
Nickel(Ii) And Cobalt(Ii) Nitrate And Chloride Networks With 2-Aminopyrimidine, Robert D. Pike, Mi Jung Lim, Ellen A. L. Wilcox, Tristan A. Tronic
Arts & Sciences Articles
The coordination chemistry of 2-aminopyrimidine (PymNH2) with nickel(II) and cobalt(II) nitrate and chloride is reported, including seven new X-ray crystal structures. Two [Ni(NO3)2(PymNH2)2(OH2)] isomers were found (A: C2/c, a=13.3006(5), b=7.9727(3), c=28.5453(11), β=101.758(2), V=2963.48(19), Z=8 and B·1/2 acetone: P21/c, a=7.66060(10), b=10.6792(2), c=20.6790(3), β=100.2970(10), 1664.48(5), Z=4). In both cases one nitrate is monodentate and the other is chelating and the PymNH2 ligands coordinate through ring nitrogen atoms. Hydrogen bonding results in double sheet structure for isomer A, and a three dimensional channeled network for isomer B. [Co(NO3)2(PymNH2)2(OH2)] ( …
Copper(I) Chloride Carbonyl Polymers, Austin B. Wiles, Robert D. Pike
Copper(I) Chloride Carbonyl Polymers, Austin B. Wiles, Robert D. Pike
Arts & Sciences Articles
Addition of bridging diamine ligands to methanolic solutions of CuCl under a CO purge produces the polymeric complexes [(CuCl)2(CO)2(biL)] (biL = diazabicyclo[2.2.2]octane (DABCO), piperazine (Pip), N,N‘-dimethylpiperazine (DMP)). X-ray crystal structures of the three complexes reveal rhombic OC−Cu(μ-Cl)2Cu−CO bridged by biL. Unsaturated bridging ligands fail to produce carbonyl-bearing products.
Peroxynitrite Oxidation Of Aromatic Thiols: Characterization Of The Products Formed Through Oxidation Of Thionitrobenzoic Acid And Thionitropyridine By Peroxynitrite, Catherine Balchunas Mall
Peroxynitrite Oxidation Of Aromatic Thiols: Characterization Of The Products Formed Through Oxidation Of Thionitrobenzoic Acid And Thionitropyridine By Peroxynitrite, Catherine Balchunas Mall
Dissertations, Theses, and Masters Projects
No abstract provided.
2,2′,3,3′-TetraMethyl-6,6′-Biquinoxaline, Ralph N. Salvatore, Jorden P. Kass, Ricky J. Paul Gibson, Cesar H. Zambrano, Robert D. Pike, Eric E. Dueno
2,2′,3,3′-TetraMethyl-6,6′-Biquinoxaline, Ralph N. Salvatore, Jorden P. Kass, Ricky J. Paul Gibson, Cesar H. Zambrano, Robert D. Pike, Eric E. Dueno
Arts & Sciences Articles
The molecule of the title compound, C20H18N4, has twofold rotational symmetry. Each aromatic ring of the fused quinoxaline ring system is skewed from the other by 4.93 (7)°. The two quinoxaline units make a dihedral angle of 43.52 (2)°
Automated Peak Identification For Time -Of -Flight Mass Spectroscopy, Haijian Chen
Automated Peak Identification For Time -Of -Flight Mass Spectroscopy, Haijian Chen
Dissertations, Theses, and Masters Projects
The high throughput capabilities of protein mass fingerprints measurements have made mass spectrometry one of the standard tools for proteomic research, such as biomarker discovery. However, the analysis of large raw data sets produced by the time-of-flight (TOF) spectrometers creates a bottleneck in the discovery process. One specific challenge is the preprocessing and identification of mass peaks corresponding to important biological molecules. The accuracy of mass assignment is another limitation when comparing mass fingerprints with databases.;We have developed an automated peak picking algorithm based on a maximum likelihood approach that effectively and efficiently detects peaks in a time-of-flight secondary ion …
Uv Cure Kinetics Of Dimethacrylate Thin And Thick Samples, Yuemei Zhang
Uv Cure Kinetics Of Dimethacrylate Thin And Thick Samples, Yuemei Zhang
Dissertations, Theses, and Masters Projects
UV curing is using UV light as the energy source to induce the polymerization of liquid monomers and oligomers to form a solid polymer. Because UV polymerization is fast and energy-saving and a UV curable system has no VOC (volatile organic compound), this new technology has developed rapidly from thin film applications to thick sample applications. In addition, since the UV cure process can be controlled spatially and temporally, it also has an important application to make gradient materials with locally optimized properties. However, most research on UV cure is based on thin film applications, and the cure kinetics of …
Bis([Mu]-ThioPhene-2-Carbaldehyde ThioSemicarbazonato)Bis[AcetonitrileCopper(I)] Bis(TetraFluoroBorate), Robert D. Pike, Austin B. Wiles, Tristan A. Tronic
Bis([Mu]-ThioPhene-2-Carbaldehyde ThioSemicarbazonato)Bis[AcetonitrileCopper(I)] Bis(TetraFluoroBorate), Robert D. Pike, Austin B. Wiles, Tristan A. Tronic
Arts & Sciences Articles
The title compound, [Cu2(C6H7N3S2)2(C2H3N)2](BF4)2, is a dimer with a central Cu2S2 core resulting from thiosemicarbazone sulfur bridging. Both Cu-TCT units (TCT is the thiophene-2-carboxaldehyde thiosemicarbazone anion) are roughly planar and are parallel to one another and perpendicular to the Cu2S2 plane.
Novel Derivatizing Agents For The Determination Of Methylmercury By Gas Chromatography Using Electron Capture Detection, Crystal Marie Irwin
Novel Derivatizing Agents For The Determination Of Methylmercury By Gas Chromatography Using Electron Capture Detection, Crystal Marie Irwin
Dissertations, Theses, and Masters Projects
No abstract provided.