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Dimethyl (±)-(1s*,2r*,3s*)-[3-Phenyl-1-(N-Phenylcarbamoyloxy)-2, 3-Epoxypropyl]-Phosphonate, T. Boehlow, A. De La Cruz, N. Rath, C. Spilling
Dimethyl (±)-(1s*,2r*,3s*)-[3-Phenyl-1-(N-Phenylcarbamoyloxy)-2, 3-Epoxypropyl]-Phosphonate, T. Boehlow, A. De La Cruz, N. Rath, C. Spilling
Chemistry & Biochemistry Faculty Works
The crystal structure of the racemic title compound, C18H20NO6P, m.p. 428-431 K, has been determined by X-ray diffraction. The title compound consists of a tetrahedral P atom bonded to two methoxy groups, and an alkyl chain. The alkyl chain was substituted at position 1 with a carbamate and with an epoxide at positions 2 and 3. The relative configuration of the 1-carbamate and 2,3-epoxide substituents was confirmed as anti (1S,2R,3S). The crystal structure contains an enantiomeric pair with two intermolecular hydrogen bonds in a 14-membered ring. The hydrogen bonds are formed between the P=O of one enantiomer and the N-H …
Fragment Rotational Distributions From The Dissociation Of Nebr2: Experimental And Classical Trajectory Studies, Mehdi Nejad-Sattari , '95, Thomas Alex Stephenson
Fragment Rotational Distributions From The Dissociation Of Nebr2: Experimental And Classical Trajectory Studies, Mehdi Nejad-Sattari , '95, Thomas Alex Stephenson
Chemistry & Biochemistry Faculty Works
The Br-2 fragment rotational distributions that result from the vibrational predissociation of NeBr2 in the B electronic state have been measured for several initial vibrational levels. In each case, the rotational distributions extend to the effective energetic Limit determined by the amount of energy available (E(av1)) for disposal into the fragment rotational and translational degrees of freedom. Analysis of the data allows refinement of the NeBr2 dissociation energy; we find that D-0=70.0 +/- 1.1 cm(-1) for the X electronic state, v = 0. Both Delta v = - 1 and -2 dissociation events have been examined. For dissociation pathways with …