Digital Commons Network^™

Controls On Plastic Debris Capture In Urban Stormwater Drains Of London, Canada: A Study Within The Great Lakes Watershed, Nina Kozikowski

Electronic Thesis and Dissertation Repository

Land-based sources are the greatest contributors of plastic pollution in aquatic environments. Prior to this investigation, there were no available studies concerning the number and types of plastic debris items between 1 mm and 5 mm captured in urban stormwater drains. The present study examined macroplastic (>5 mm) and large microplastic (1-5 mm) debris that accumulated in LittaTrap^TM devices at six drain sites over four seasonal periods in London, Ontario, Canada. Macroplastics (MaPs) and microplastics (MPs) were found in all 36 samples, and the totals ranged from 5-158 MaPs and 18-359 MPs per trap. Out of the 118 …

Revealing The Core Dynamics Of Vesta: Insights From Experimental Investigations Of Electrical Resistivity And Thermal Conductivity, Oluwasanmi A. Orole Mr

Electronic Thesis and Dissertation Repository

Insights from high pressure and temperature experiments involving in-situ measurements of the electrical resistivity of Fe-5wt%Ni at temperatures of up to 2000 K, under pressures of 2-5 GPa in a 1000-ton cubic-anvil press have been used to reveal Vesta’s core dynamics. The Wiedemann–Franz law was used to calculate the thermal conductivity from the measured electrical resistivity data. Comparing the findings of this study with prior investigations on both pure Fe and Fe-10wt%Ni indicates that an increase in Ni ranging from 0-10wt% has negligible effect on the electrical resistivity of Fe alloys. By comparing the range of estimated heat flux through …

Empirical Nonlinear Site Response Applicable To Greater Vancouver, British Columbia, Natalia Gomez Jaramillo

Electronic Thesis and Dissertation Repository

In Greater Vancouver, strong earthquake shaking has not been recorded to quantify expected nonlinear soil response. Earthquake horizontal to vertical spectral ratios (eHVSR) are evaluated at seismic stations located at the edges or deeper center of sedimentary basins in Mexico City, the Kanto basin and Anchorage with available weak-to-strong motion recordings that have similar linear site response to Greater Vancouver to constrain the expected nonlinear soil response for future large earthquakes affecting Greater Vancouver. The empirical results confirm that the very low fundamental frequency (f₀ < 0.6 Hz) at deep Fraser River delta sites will be less affected by strong shakings and suggest that for Fraser River delta edge sites the amplification at the predominant frequency (f₁) could increase up to 1.77 times with a strong event. This thesis’ …

Deformation And Evolution Of Achondrite Parent Bodies, Yaozhu Li

Electronic Thesis and Dissertation Repository

Minerals in planetary bodies record accumulated strain from deformation events such as hypervelocity impacts but potentially also parent body processes such as gravitational compaction. This work investigates olivine microstructural features that may distinguish between different impact levels versus parent body plastic deformation regimes. Achondritic meteorites from the ureilite parent body, the Moon, Mars as well as terrestrial basalt and mantle xenolith have been investigated using micro-XRD, EBSD, micro-XRF and other methods to study their parent body deformation history. A Matlab® method, unit segment length (USL), is herein developed to visualize the crystal boundary geometry and quantify the apparent subboundary density …

Short-Term Versus Long-Term Effects Of Nitrogen Addition And Warming On Ecosystem N Dynamics In A Grass-Dominated Temperate Old Field, Benjamin F. A. Souriol

Electronic Thesis and Dissertation Repository

Increased atmospheric nitrogen (N) deposition and climate warming are both anticipated to influence the ecosystem N dynamics of northern temperate ecosystems substantially over the next century. Nevertheless, in field experiments with N addition and warming treatments, temporal scale can play an important role in determining the extent of treatment effects on N dynamics, and it is unclear to what extent the results of short-term studies can be extrapolated to responses over longer time scales. I compared the short-term versus long-term effects of N addition and warming on net N mineralization, N leaching, and N retention in a grass-dominated old field. …

Thermal And Fluid Evolution Of The Clearwater West Impact-Generated Hydrothermal System, Quebec, And Associated Astrobiological Implications, Daliah R. Bibas

Electronic Thesis and Dissertation Repository

Impact-generated hydrothermal systems result from interactions between a permeable substrate, an impact-generated heat source, and fluids (e.g., H₂O). A comprehensive understanding of the evolution of these terrestrial features has significant implications in the search for habitable environments on Mars, a focus in the emerging field of astrobiology. This thesis presents a detailed case study of the impact-generated hydrothermal alteration of impactites at the Clearwater West impact structure, Quebec, focusing on hydrothermally precipitated quartz vugs in crater-fill impact melt rocks. Sample analysis included optical microscopy, electron microprobe analysis, mass spectrometry, and fluid inclusion microthermometry. Results show 3 main quartz …

Terrestrial Craters As Analogues For Degraded Craters On Titan, Taylor M. Duncan

Electronic Thesis and Dissertation Repository

Besides Earth, Titan is the only planetary body in our Solar System to currently have flowing liquid on its surface. Previous works note that dendritic and rectangular stream networks are present on a global scale on Titan, but do not map networks in the vicinity of Titan’s impact craters: Selk and Sinlap. The objective of this work is to understand how stream networks form adjacent to Titan’s impact craters. This information will inform future missions to Titan (i.e., Dragonfly) about the fluvial morphology of streams near their landing site. I conduct an analogue study with the stream networks at three …

Towards Automated Mineral Identification In Martian Rocks From X-Ray Diffraction Patterns, Luke Tambakis

Electronic Thesis and Dissertation Repository

The CheMin (Chemistry and Mineralogy) instrument on the Curiosity rover has provided a rich set of X-ray diffraction (XRD) patterns from Martian rocks and regolith. These XRD patterns have allowed geologists to make exciting new discoveries about the mineralogy and the geological history of Mars. These discoveries pave the way for further Martian exploration and provide a deeper understanding of Martian geology. The Curiosity rover is very slow by design, travelling at about 4 cm/s. New, faster rovers are being developed to increase scientific throughput and exploration. XRD is valuable for future missions as it can produce new discov- eries …

Petrophysical Properties Of The Hed Meteorites And The Bushveld Igneous Complex: Implications For Future Asteroid Prospecting Missions, Lukas Louwerse

Electronic Thesis and Dissertation Repository

In this work, I make a quantitative and mineralogical comparison of Howardite-EuctriteDiogenite (HED) meteorites with terrestrial samples from the Bushveld Igneous Complex (BIC) to assess how geophysical surveys of 4 Vesta or of V-type asteroids could detect BIClike ore deposits. Petrophysical methods in this work include bulk and grain density, derived porosity (using helium pycnometry, the Archimedean method, and X-ray micro-computed tomography), magnetic susceptibility, induced polarization and resistivity, and P-wave velocity. Mineralogical methods in this work include optical microscopy, micro X-ray diffraction, micro X-ray fluorescence element mapping, and electron beam methods. Howardite NWA 15199 was classified as part of this …

Topographic Effects Of Shallow Crustal Earthquakes In The Greater Vancouver Region, Alex Vanderhoeff

Electronic Thesis and Dissertation Repository

Vancouver has a high seismic risk due to the proximity of the city to the Cascadia subduction zone offshore, the soft sediments the metropolitan region overlies, and the mountainous topography nearby. The soft sediments and mountainous topography could cause an increase in shaking due to the sedimentary basin, topographic resonance and constructive/destructive interference, respectively. Numerical three-dimensional (3D) wave propagation simulations (WPS) were run using a finite difference scheme developed by Peterson and Sjogreen (2012), Seismic Waves, 4^th order, to perform simulations of large shallow crustal rupture scenario earthquakes using the 1994 M6.7 Northridge, California earthquake slip distribution. The …

Late Neoarchean To Middle Paleoproterozoic Geology Of Devon And Ellesmere Islands, Canadian Arctic, Joshua P. Laughton

Electronic Thesis and Dissertation Repository

The northernmost exposure of the Laurentian shield in Canada outcrops on Devon and Ellesmere islands within the Canadian Arctic Archipelago. Due to the remote location, the basement rocks of these islands have received little attention. From this study, zircon crystallization ages demonstrate that Devon Island is underlain by a late Neoarchean terrane comprising orthogneisses emplaced at ca. 2.55–2.51 Ga and an interleaved metasedimentary sequence deposited at ca. ≥2.47 Ga. On northern Devon Island, younger metasedimentary sequence(s) were deposited at ca. 2.2–1.9 Ga and intruded by ca. 2.01–1.95 Ga granitoids. Devon and Ellesmere islands experienced widespread metamorphic activity associated with the …

The Fate Of Carbonate Rocks During Hypervelocity Impacts: Case Studies From Three Impact Structures On Earth, Nicolas D. Garroni

Electronic Thesis and Dissertation Repository

Approximately 28% of all hypervelocity impact structures discovered on Earth exist in a carbonate-dominated target sequence. Despite decades of research, how carbonate rocks and minerals react to shock metamorphism is still poorly understood. In this contribution, three impact structures on Earth were studied to determine the effects of shock metamorphism on carbonate minerals: Chicxulub, Crooked Creek and Jebel Waqf as Suwwan.

At Chicxulub, carbonates from the impact-melt bearing breccia of drill core, M0077A were characterized petrographically and geochemically. Calcite was the only carbonate mineral present and is abundant throughout the impact breccia in five distinct varieties: limestone clasts …

Soil Organic Carbon Dynamics And The Effects Of Resident Vegetation In Pelee Island Soils, Colton Geil

Electronic Thesis and Dissertation Repository

Soil organic carbon (SOC) enhances nutrient retention, structural stability, porosity, aeration, water infiltration, and overall soil health. Understanding SOC turnover and its preservation in soils is paramount to managing carbon sequestration. On Pelee Island, we used δ¹³C, δ¹⁵N and C/N of SOC at various depths to identify the sources and evolution of SOC with time. At depths >150 cm, SOM was from a mixture of aquatic and terrestrially derived sources. We also analyzed the impact of permanent cover crops called ‘resident vegetation’ on the ability of soils to store carbon in different aggregate size fractions. SOC …

The Origin And Evolution Of Impact Crater Lakes: A Case Study Of The Ries Impact Structure, Germany, Matthew J. O. Svensson

Electronic Thesis and Dissertation Repository

Impact events are known to generate hydrothermal systems, which can subsequently vent into an overlying crater lake and potentially create ideal conditions for some microbial life-forms. Thus, early post-impact sedimentary deposits would be excellent targets for Mars sample return, and as such, the robust characterization of such deposits on Earth is critical. In this thesis, we establish an improved understanding of how the Ries crater lake formed, and how an active impact-generated hydrothermal system influenced its early evolution. The ~14.8 Ma Ries impact structure hosts the majority of its paleolake deposits within the structure's central basin with some deposits situated …

Approaches To Model Non-Uniqueness And Site Complexity For Non-Invasive Shear-Wave Depth Profiling, Christopher Boucher

Electronic Thesis and Dissertation Repository

Shear-wave velocity (VS) depth profiling and associated seismic site classifications were performed at 15 sites across Metro Vancouver, British Columbia using passive seismic and surface wave methods. Inversion model parameters are constrained at each site using nearby geodata in combination with developing regression models of shear-wave velocity with depth for three primary stratigraphic units. Statistical methods such as a Bayesian Information Criterion are applied post-inversion to evaluate models between and within varying parameterizations. Data evaluation metrics, including the use of microtremor horizontal-to-vertical spectral ratios (MHVSRs), are applied to identify two common deviations from the simple case of normally dispersive laterally …

Subsurface Correlation Of Lower Silurian Medina Group, Southwestern Ontario, Rhys H. Paterson

Electronic Thesis and Dissertation Repository

The Medina Group succession in southwestern Ontario includes, in ascending order: the Whirlpool, Manitoulin, Cabot Head, Power Glen, Devils Hole-Balls Falls, Grimsby, and Thorold formations. Subsurface mapping in central and eastern Lake Erie has resulted in the recognition of three stratigraphic packages within the Medina Group based upon the integration of sedimentologic, stratigraphic and geophysical borehole logs. The interplay between changing paleoenvironments, sediment provenance, and regional tectonics and associated sea level fluctuations has resulted in the accumulation of a complex mosaic of mixed siliciclastics and carbonates. Manitoulin Formation carbonates and Whirlpool Formation siliciclastics display consistent thicknesses across the study area. …

Geomechanical Modeling Of A Fault During Fluid Injection, Charles Kw Hulls

Electronic Thesis and Dissertation Repository

The injection of fluid into rock masses as a part of industrial processes, such as hydraulic fracturing, can lead to an increase in seismic activity. The movement of the injected fluid and resulting stresses can be simulated and analyzed. One aspect of this analysis is the predicted rate of seismic activity, obtained via the Dietrich rate-and-state law and the Coulomb Failure Stress. This work produces simulations for two fracturing scenarios in the Duvernay Shale region. Model parameters, such as layer permeability and timing of fault slip, are varied to determine their impact on the model results. The simulated results show …

Characterization Of Some Natural Copper Samples From The Keweenaw Peninsula Of Lake Superior Using Electron Microscopy And X-Ray Tomography Techniques, Emilie Mk Landry

Electronic Thesis and Dissertation Repository

Copper corrosion is of interest to Canada’s Nuclear Waste Management Organization as it relates to their multi-barrier system for nuclear waste disposal in deep geologic repositories. Spent fuel canisters coated with a thin copper layer must persist for up to one million years. Natural copper from the Keweenaw Peninsula in Michigan, USA, has persisted for over 1 billion years and is here characterized to understand copper corrosion over geological time. Copper samples representing three rock types were characterized using optical microscopy, scanning electron microscopy techniques (energy dispersive X-ray spectroscopy and electron backscatter diffraction), and micro-computed X-ray tomography (microCT) to establish …

Complex Unicellular Microfossils From The 1.9 Ga Gunflint Chert, Canada, Ana L. González Flores

Electronic Thesis and Dissertation Repository

The presence of eukaryotic life during the early Paleoproterozoic has been a matter of debate because well-preserved fossils older than 1.8 Ga rarely exhibit eukaryotic cellular microstructures. In this study, microfossils from the 1.9 Ga Gunflint Chert were studied using the extended-focal-depth imaging technique, combined with scanning electron microscopy, resulting in recognition of three types of large (10–35 μm diameter) complex unicellular bodies (CUBs) and one type of “multicellular body” (< 50 μm diameter). The CUBs show the following eukaryotic cyst-like structures: (1) radially arranged internal strands similar to those in some acritarchs and dinoflagellates; (2) regularly spaced long tubular processes, stubby pustules, and/or robust podia on the cell surface; (3) reticulate cell-wall sculpturing such as pits, ridges, and scale-like ornaments; and (4) internal bodies that may represent membrane-bounded organelles. These morphological features provide strong evidence for the presence of protists in the late Paleoproterozoic.

Among the three types of CUBs from the Gunflint microbiota, a new species, Germinosphaera gunflinta sp. nov., was recognized. This species has the diagnostic characteristics of Germinosphaera, such …

Oxygen Speciation In Potassium Silicate And Potassium Aluminosilicate Glasses: Insights From X-Ray Photoelectron Spectroscopy, Ryan Sawyer

Electronic Thesis and Dissertation Repository

In a geological context, glasses are useful analogues for silicate melts as they are more readily studied in the laboratory using a wide range of techniques that are impractical for molten liquids. Understanding the structure of binary silicate glasses can help us understand more about the magmatic processes that affect terrestrial planetary bodies.

Potassium silicate glasses ranging in composition from 10 mol% to 35 mol% K₂O were studied using X-ray Photoelectron Spectroscopy (XPS). From high resolution O 1s XPS spectra, Bridging Oxygen (BO) mole fractions were calculated and compared with those of previous ²⁹Si MAS NMR studies. …

Examining Κ, The High Frequency Spectral Decay Parameter, In Eastern Canada, Samantha M. Palmer

Electronic Thesis and Dissertation Repository

This thesis examines the ground motion modeling parameter kappa (κ) in the stable continental region of eastern Canada. Kappa characterizes the decay of spectral amplitudes at high frequencies due to near-surface material de-amplification and is important in seismic hazard assessments. Kappa has significant economic and seismic safety implications for critical infrastructure such as nuclear power plants and dams.

To examine kappa in eastern Canada, a database of ground motions to analyze near-source ground motion characteristics is developed. The database consists of ground motion records from 3357 earthquakes of moment magnitude (M) ≥1.5 recorded within 150 km of 25 …

White Micas As A Tool For Tracking Pegmatite Evolution And Its Use In Li Exploration. A Case Study Of Wekusko Lake, Manitoba, Canada., David N. Benn

Electronic Thesis and Dissertation Repository

The Wekusko Lake pegmatite field is part of the Green Bay Group of pegmatites located near Snow Lake, Manitoba, Canada. Within this field, there are at least 13 spodumene-bearing pegmatites of varying degrees of mineralization. The abundance of white micas and the chemical affinity to incorporate Li and other trace elements into its crystalline structure makes white micas an ideal indicator mineral. The evolution of a melt can be tracked using trace elements in white mica. The K/Rb ratio vs Cs is used to determine a link between increasing evolution and increased Li contents of both the white mica and …

Heat Flow In Terrestrial-Type Bodies From High P,T Electrical Resistivity Measurements Of Au, Fe-Si And Fe-Ni-Si Solid And Liquid Alloys, Meryem Berrada

Electronic Thesis and Dissertation Repository

The source of the fluid stirring mechanism that powers the dynamo of terrestrial-type bodies during their active magnetic field era is debated. Prior to the formation of a solid inner core, thermal convection may cause enough mechanical stirring of the core fluid to generate a magnetic field through dynamo action. After inner core formation, compositional convection in the liquid outer core becomes the main source of fluid stirring mechanism to power a dynamo. Constraints on the likelihood and duration of these convection mechanisms may be obtained by the experimental determination of the thermal properties of core materials. These cores consist …

Deformation Conditions Of Quartz-Rich Mylonites Of The Grenville Front Tectonic Zone And Application To The Crustal Strength, Xueke Chang

Electronic Thesis and Dissertation Repository

This thesis analyzes a suite of mylonites from the Grenville Front shear zone exposed southeast of Sudbury, Ontario. Lattice preferred orientations, titanium-in-quartz thermometer, and dynamically recrystallized grain size piezometer measurements were applied to obtain the deformation mechanisms, deformation temperatures (T), and differential stresses (σ), respectively. Results show that these mylonites were formed in the shear zone during the terminal stage of the Grenville Orogeny. The dominant deformation mechanism is by regime 2 dislocation creep. The deformation temperature is between 425-567 °C, and the differential stress is between 56-133 MPa. These results are discussed in the context of wet quartzite flow …

Modeling Of Fluid Injection-Related Processes In Hydrocarbon Reservoirs In Alberta, Canada, Negar Nazari

Electronic Thesis and Dissertation Repository

In the last decade, with the development of horizontal drilling and multistage hydraulic fracturing technology, extraction of unconventional resources has significantly increased in western Canada. These industrial activities have been associated with the rise in the seismicity rate. This thesis aimed to improve the quality of the available geomechanical models of the injection-induced seismicity in the Western Canada Sedimentary Basin, by incorporating detailed geoscience characterization for two unconventional reservoirs of the Duvernay Formation in the Fox Creek area and the Cardium Formation in West Pembina. Hydraulic fracturing has induced seismicity in the first area, but no induced seismicity has been …

Stable Carbon And Oxygen Isotopes Of Early Silurian Pentameride Brachiopods From Québec, Ontario, And Nunavut, And Paleoenvironmental Implications, Jordan N. Siewnarine

Electronic Thesis and Dissertation Repository

Analysis of low-Mg calcite brachiopod shells for δ¹⁸O and δ¹³C signatures provide quantitative independent geochemical data for paleoenvironmental interpretations. We analyzed 59 brachiopod shells from lower Silurian carbonate rocks of Anticosti Island, the Hudson Bay Lowlands and Niagara regions for spaciotemporal isotopic trends for the early Silurian. Screening tests using scanning electron microscopy, cathodoluminescence and trace element analysis demonstrate exceptional preservation, suggesting retention of primary isotopic values.

δ¹³C and δ¹⁸O values of shells range from 0.2‰ to 2.9‰ and -6.9‰ to -4.3‰ (VPDB), respectively. Temporally, increases in δ¹³C and δ …

Investigation Of Sulphide-Poor Gold Mineralization At The Deep A Zone, Kiena Complex, Québec, Stephanie A. Kobylinski

Electronic Thesis and Dissertation Repository

The Kiena Complex is located halfway between Malartic and Val d’Or in Québec, within the Abitibi Greenstone belt in the Superior Province. This study examined mineralization at the Kiena Complex using detailed core logging, geochemical analysis of wall rock, petrography, EPMA, and gold deportment studies. The analysis and interpretations indicate that the unique sulphide-poor gold-rich quartz veins of the Deep A Zone at the Kiena Complex contain 500 μm²) are located at the contact of quartz and corroded albite grains, and fine gold grains (5-500 μm²) are hosted within the corroded albite.

Early Solar System Chronology And Isotopic Linkage Of Non-Carbonaceous Chondrules, Clasts And Achondrites, Philip M. Reger

Electronic Thesis and Dissertation Repository

Chondrules are ubiquitous igneous spherules, the main constituents of ordinary chondrites, and are considered to be critical building blocks of planetesimals, yet their age and formation mechanism(s) remain debated. Differences between ages determined from the long-lived Pb-Pb and the short-lived ²⁶Al-²⁶Mg chronometers have been attributed to the heterogeneous distribution of ²⁶Al in the solar nebula, a radionuclide that was responsible for early differentiation of planetesimals.

To evaluate this hypothesis, the ²⁶Al-²⁶Mg and the ²⁰⁷Pb-²⁰⁶Pb isotopic compositions were both measured by multi-collector ICP-MS in individual chondrules and igneous clasts in unequilibrated …

Testing Aftershock Forecasts Using Bayesian Methods, Elisa Dong

Electronic Thesis and Dissertation Repository

The presence of strong aftershocks can increase the seismic hazard following a large earthquake and should be considered for operational earthquake forecasting and risk management. Aftershock forecasts are generated from seismicity models during the evolution of the aftershock sequence. This work compares quantitative test results of the forecasting abilities for three competing aftershock rate models - the modified Omori law, the Epidemic Type Aftershock Sequence model, and the compound Omori law - to identify the best performing model for forecasting the largest aftershock during the early aftershock sequence. Forecasts of large aftershock probabilities are generated by either the Extreme Value …

Intra-Population Variation Of Hair And Fingernail Stable Hydrogen, Oxygen, Carbon And Nitrogen Isotopes In London, Ontario, Canada Residents During The Covid-19 Pandemic, Sawyer C E Rowe

Electronic Thesis and Dissertation Repository

Lockdowns and travel restrictions during the COVID-19 pandemic forced a significant fraction of London, Ontario, Canada residents to remain in one location for long enough to reach isotopic equilibrium with their primary drinking water source(s). This situation created ideal natural conditions for measuring the isotopic fractionation between the stable hydrogen and oxygen isotopes of drinking water and hair or nail tissues, and for determining the magnitude of intra-population variation in tissue δ²H and δ¹⁸O. Hair and nail of participants who reported exclusively drinking London municipal tap water spanned much larger δ²H and δ^{18 …}