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Integrated Data Fusion And Mining (Idfm) Technique For Monitoring Water Quality In Large And Small Lakes, Benjamin Vannah Jan 2013

Integrated Data Fusion And Mining (Idfm) Technique For Monitoring Water Quality In Large And Small Lakes, Benjamin Vannah

Electronic Theses and Dissertations

Monitoring water quality on a near-real-time basis to address water resources management and public health concerns in coupled natural systems and the built environment is by no means an easy task. Furthermore, this emerging societal challenge will continue to grow, due to the ever-increasing anthropogenic impacts upon surface waters. For example, urban growth and agricultural operations have led to an influx of nutrients into surface waters stimulating harmful algal bloom formation, and stormwater runoff from urban areas contributes to the accumulation of total organic carbon (TOC) in surface waters. TOC in surface waters is a known precursor of disinfection byproducts …


Evaluation Of The Biodegradability And Toxicity Of Pca And Mpca, Juan Rueda Jan 2013

Evaluation Of The Biodegradability And Toxicity Of Pca And Mpca, Juan Rueda

Electronic Theses and Dissertations

The main types of hypergolic propellants used at Kennedy Space Center (KSC) are hydrazine (HZ) and monomethylhydrazine (MMH). HZ and MMH are classified as hazardous materials and they are also known to be potentially carcinogenic to humans; therefore, handling these substances and their waste is strictly regulated. The wastes streams from HZ and MMH have been estimated to be the main hazardous wastes streams at KSC. Currently at KSC these wastes are first neutralized using citric acid and then they are transported on public roads for incineration as hazardous materials. A new method using alpha ketoglutaric acid (AKGA) was proposed …


Near-Road Dispersion Modeling Of Mobile Source Air Toxics (Msats) In Florida, Kurt Westerlund Jan 2013

Near-Road Dispersion Modeling Of Mobile Source Air Toxics (Msats) In Florida, Kurt Westerlund

Electronic Theses and Dissertations

There is a growing public concern that emissions of mobile source air toxics (MSATs) from motor vehicles may pose a threat to human health. At present, no state or federal agencies require dispersion modeling of these compounds, but many agencies are concerned about potential future requirements. Current air pollution professionals are familiar with Federal Highway Administration (FHWA) and U.S. Environmental Protection Agency (EPA) requirements for dispersion modeling to produce predicted concentrations for comparison with appropriate standards. This research examined a method in which the potential near-road concentrations of MSATs were calculated. It was believed that by assessing MSATs in much …


In-Plant And Distribution System Corrosion Control For Reverse Osmosis, Nanofiltration, And Anion Exchange Process Blends, Samantha Jeffery Jan 2013

In-Plant And Distribution System Corrosion Control For Reverse Osmosis, Nanofiltration, And Anion Exchange Process Blends, Samantha Jeffery

Electronic Theses and Dissertations

The integration of advanced technologies into existing water treatment facilities (WTFs) can improve and enhance water quality; however, these same modifications or improvements may adversely affect finished water provided to the consumer by public water systems (PWSs) that embrace these advanced technologies. Process modification or improvements may unintentionally impact compliance with the provisions of the United States Environmental Protection Agency’s (USEPA’s) Safe Drinking Water Act (SDWA). This is especially true with respect to corrosion control, since minor changes in water quality can affect metal release. Changes in metal release can have a direct impact on a water purveyor’s compliance with …


Study Of The Effect Of Surface Morphology On Mass Transfer And Fouling Behavior Of Reverse Osmosis And Nanofiltration Membrane Processes, Yuming Fang Jan 2013

Study Of The Effect Of Surface Morphology On Mass Transfer And Fouling Behavior Of Reverse Osmosis And Nanofiltration Membrane Processes, Yuming Fang

Electronic Theses and Dissertations

Reverse osmosis (RO) and nanofiltration (NF) membranes are pressure driven, diffusion controlled process. The influence of surface characteristics on membrane process performance is considered significant and is not well understood. Current mass transport models generally assume constant mass transfer coefficients (MTCs) based on a homogeneous surface. This work evaluated mass transfer processes by incorporating surface morphology into a diffusion-based model assuming MTCs are dependent on the thickness variation of the membrane’s active layer. To mathematically create such a surface layer, Gaussian random vectors embedded in a software system (MATLAB) were used to generate a three-dimensional ridge and valley active layer …


Chemophysical Characteristics And Application Of Biosorption Activated Media (Bam) For Copper And Nutrient Removal In Stormwater Management, Jamie Jones Jan 2013

Chemophysical Characteristics And Application Of Biosorption Activated Media (Bam) For Copper And Nutrient Removal In Stormwater Management, Jamie Jones

Electronic Theses and Dissertations

For high groundwater table areas, stormwater wet detention ponds are utilized as the preferred stormwater management throughout the state of Florida. Previous research has found that accumulations of nutrients, algae, heavy metals, pesticides, chlorophyll a, fecal coliform bacteria and low concentrations of dissolved oxygen (DO) are common characteristics of stormwater wet detention ponds. Although these pollutant levels are not regulated within the ponds, states are required to compute the pollutant load reductions through total maximum daily load (TMDL) programs to meet the water quality requirements addressed by the Clean Water Act (CWA). In this study, field sampling data of stormwater …


Ozone And Gac Treatment Of A Central Florida Groundwater For Sulfide And Disinfectant By-Product Control, Tara Lamoureux Jan 2013

Ozone And Gac Treatment Of A Central Florida Groundwater For Sulfide And Disinfectant By-Product Control, Tara Lamoureux

Electronic Theses and Dissertations

This study evaluated the combination of ozone and granular activated carbon (GAC) treatment for the removal of sulfide and disinfection byproduct (DBP) precursors in drinking water at the pilot-scale. The research conducted was performed at the Auxiliary (Aux) and Main Water Treatment Plants (WTPs) in Sanford, Florida. Both WTPs rely upon groundwater sources that contain total sulfide ranging from 0.02 to 2.35 mg/L and total organic carbon (TOC) ranging from 0.61 to 2.20 mg/L. The Aux WTP’s raw water contains, on average, 88% more sulfide and 24% more TOC than the Main WTP. Haloacetic acids (HAA5) and total trihalomethanes (TTHMs) …


Assessment, Optimization, And Enhancement Of Ultrafiltration (Uf) Membrane Processes In Potable Water Treatment, Christopher Boyd Jan 2013

Assessment, Optimization, And Enhancement Of Ultrafiltration (Uf) Membrane Processes In Potable Water Treatment, Christopher Boyd

Electronic Theses and Dissertations

This dissertation reports on research related to ultrafiltration (UF) membranes in drinking water applications. A pilot-scale investigation identified seasonal surface water quality impacts on UF performance and resulted in the development of a dynamic chemically enhanced backwash protocol for fouling management. Subsequent analysis of UF process data revealed limitations with the use of specific flux, transmembrane pressure (TMP), and other normalization techniques for assessing UF process fouling. A new TMP balance approach is presented that identifies the pressure contribution of membrane fouling and structural changes, enables direct process performance comparisons at different operating fluxes, and distinguishes between physically and chemically …


Development Of A Chemical Kinetic Model For A Fluidized-Bed Sewage Sludge Gasifier, Wyatt Champion Jan 2013

Development Of A Chemical Kinetic Model For A Fluidized-Bed Sewage Sludge Gasifier, Wyatt Champion

Electronic Theses and Dissertations

As the need for both sustainable energy production and waste minimization increases, the gasification of biomass becomes an increasingly important process. What would otherwise be considered waste can now be used as fuel, and the benefits of volume reduction through gasification are seen in the increased lifespan of landfills. Fluidized-bed gasification is a particularly robust technology, and allows for the conversion of most types of waste biomass. Within a fluidized-bed gasifier, thermal medium (sand) is heated to operating temperature (around 1350°F) and begins to fluidize due to the rapid expansion of air entering the bottom of the reactor. This fluidization …