Digital Commons Network^™

Unbuilding: How Deconstruction Is Saving The Planet By Giving Building Materials A Second Life, Diana M. Ducroz

Capstones

In 2018, more than 600 million tons of construction and demolition (C&D) waste was generated in the United States, more than twice the volume of ordinary trash created by American households and businesses. Even though 80-95% of this concrete, asphalt, steel, wood, drywall, glass and brick can be reused, repurposed or recycled, a quarter of it – or 145 million tons in 2018 – ends up in landfills. Thirty million tons of wood alone – often sturdy, irreplaceable old-growth lumber – is being trashed every year.

Now, a budding ‘build reuse’ movement, made up of environmentalists, architects, historic preservationists, city …

Plastic Recycling Is Inefficient And Expensive, Clark S. Adomaitis

Capstones

Plastics production and incineration contributes more than 850 million metric tons to the emissions that are causing climate change. Emissions are growing at a moment when scientists and world leaders are in agreement that they need to dramatically decrease. Environmentalists say that plastic production makes up 4.5% of global greenhouse gas emissions. New plastic plants opening in the U.S. do not line up with emission reduction goals.

At the end of plastics’ lives, a lot of what we’re putting into our recycling bins isn’t getting recycled. In fact, only 18% of trash from New York City homes is actually recycled. …

Quantum Mechanics-Based Computational Chemistry Has Become A Powerful Partner In The Scientific Research Of Nitrogen-Rich Compounds, Paving The Way For Important Advances In Biochemical, Pharmacological And Other Related Fields, Dobrushe Denburg

Student Theses and Dissertations

The Computational Chemistry of Nitrogen-Rich Compounds; Insight into Pioneering Research

Nitrogen-rich functional groups have long been studied for their diversity; nitrogen can form single, double and triple bonds with itself, and will therefore exist in a very broad range of molecular arrangements. Poly-nitrogen compounds are highly energetic and electron rich, and many compounds display unique properties that allow participation in very specialized chemical reactions. Of import is their ubiquity in biological systems, and throughout the past century and currently, their biological relevance is deeply and widely explored in biochemistry and biomedicine, from their involvement in natural biological processes and complex …

Sorption Of Metals At The Barite (001)-Water Interface, Inva Braha

Student Theses

Abstract

Ion desorption processes control the retention of ions, such as Pb²⁺, at barite surfaces, whereas ion adsorption processes are a likely initial step in the incorporation of divalent cations, such as Sr²⁺ and Pb²⁺, into barite. Based on previous studies on samples dominated by flat terraces with relatively few defects, Sr²⁺ and Pb²⁺ adsorb and incorporate at the barite (001)-water interface (Bracco et al., 2019; Bracco et al., 2020). Here, I measured how susceptible lead (Pb) is to desorption and the role surface variability plays in its sorption behavior. First, I measured …

Logics Of Resource And Justification, Hirohiko Kushida

Dissertations, Theses, and Capstone Projects

It is a well-known result by G ̈odel in 1933 that the Intuitionistic Logic can be embedded into a system which is essentially equivalent to the modal logic S4. This can be considered to be an attempt to provide a provability semantics to the Intuitionistic Logic. This work had caused some problems: the exact arithmetical meaning of the Intuitionistic Logic and S4, the exact axiomatization of formal provability in formal arithmetic and the standard model of arithmetic. These days the arithmetical interpretation has been extended and generalized to epistemological interpretation for various modal logics, which resulted in various systems of …

Piecewise Linear Manifold Clustering, Artyom Diky

Dissertations, Theses, and Capstone Projects

This work studies the application of topological analysis to non-linear manifold clustering. A novel method, that exploits the data clustering structure, allows to generate a topological representation of the point dataset. An analysis of topological construction under different simulated conditions is performed to explore the capabilities and limitations of the method, and demonstrated statistically significant improvements in performance. Furthermore, we introduce a new information-theoretical validation measure for clustering, that exploits geometrical properties of clusters to estimate clustering compressibility, for evaluation of the clustering goodness-of-fit without any prior information about true class assignments. We show how the new validation measure, when …

A Geometric Model For Real And Complex Differential K-Theory, Matthew T. Cushman

Dissertations, Theses, and Capstone Projects

We construct a differential-geometric model for real and complex differential K-theory based on a smooth manifold model for the K-theory spectra defined by Behrens using spaces of Clifford module extensions. After writing representative differential forms for the universal Pontryagin and Chern characters we transgress these forms to all the spaces of the spectra and use them to define an abelian group structure on maps up to an equivalence relation that refines homotopy. Finally we define the differential K-theory functors and verify the axioms of Bunke-Schick for a differential cohomology theory.

Topological Classical Wave Systems With Modulations, Interactions, And Higher-Order Topological States, Mengyao Li

Dissertations, Theses, and Capstone Projects

Topological phases in classical wave systems, such as photonic and acoustic, have been actively investigated and applied for wave guiding, lasing, and numerous other novel phenomena and device applications Topological phase transitions enable robust boundary states, and the field has been broadening recently into a vast variety of systems with temporal modulations and interactions. Floquet modulation, for example, is the modulation applied periodically in time which may break symmetries and leads to novel topological phases.

Introducing non-Hermitian Floquet modulation enables more interesting phenomena including bandgap in imaginary part of the spectrum and gainy/lossy topological edge states with complex energy values. …

Solving Multiple Inference In Graphical Models, Cong Chen

Dissertations, Theses, and Capstone Projects

For inference problems in graphical models, much effort has been directed at algorithms for obtaining one single optimal prediction. In practice, the data is often noisy or incomplete, which makes one single optimal solution unreliable. To address this problem, multiple Inference is proposed to find several best solutions, M-Best, where multiple hypotheses are preferred for advanced reasoning. People use oracle accuracy as an evaluation criterion expecting one of the solutions has high accuracy with the ground truth. It has been shown that it is beneficial for the top solutions to be diverse. Approaches for solving diverse multiple inference are proposed …

Don't Sell Them Short, There's More To Bacterial Natural Products Than Antibiotics, Alison Clare Domzalski

Dissertations, Theses, and Capstone Projects

Recent genomic studies of microbiomes have revealed an overwhelming number of biosynthetic genes of unknown function. Most of these “cryptic” biosynthetic genes are not expressed in laboratory monocultures of individual microbes. Thus, there remains tremendous untapped potential for natural products discovery. Here we employ mixed microbial culture (MMC) as a simple yet powerful approach to awaken cryptic biosynthetic gene clusters. Our preliminary studies demonstrated that arrays of metabolites could be induced in MMCs upon environmental cues, such as surface adhesion. Using this system, we have screened, identified, and isolated bioactive bacterial metabolites, which were characterized structurally and biologically. Of the …

Tools And Strategies For The Patterning Of Bioactive Molecules And Macromolecules, Daniel J. Valles

Dissertations, Theses, and Capstone Projects

Hypersurface Photolithography (HP) is a printing method for fabricating structures and patterns composed of soft materials bound to solid surfaces and with ~1 micrometer resolution in the x, y, and z dimensions. This platform leverages benign, low intensity light to perform photochemical surface reactions with spatial and temporal control of irradiation, and, as a result, is particularly useful for patterning delicate organic and biological material. In particular, surface- initiated controlled radical polymerizations can be leveraged to create arbitrary polymer and block- copolymer brush patterns. Chapter 1 will review the advances in instrumentation architectures from our group that have made these …

Differentiability Of The Liouville Map Via Geodesic Currents, Xinlong Dong

Dissertations, Theses, and Capstone Projects

For a conformally hyperbolic Riemann surface, the Teichmüller space is the space of quasiconformal maps factored by an equivalence relation, and it is a complex Banach manifold. The space of geodesic currents endowed with the uniform weak* topology is a subset of a Fréchet space of Hölder distributions. We introduce an appropriate topology on the space of Hölder distributions and this new topology coincides with the uniform weak* topology on the space of geodesic currents. The Liouville map of the Teichmüller space becomes differentiable in the Fréchet sense. In particular, the derivative of Liouville currents exists and belongs to the …

Detecting Stance On Covid-19 Vaccine In A Polarized Media, Rodica Ceslov

Dissertations, Theses, and Capstone Projects

The growing polarization in the United States has been widely reported. Media coverage plays an important role in shaping public opinion and influences public debates on complex and unfamiliar topics. There are some benefits to individuals and society from political polarization and conflict between opposing viewpoints. However, recent research has primarily highlighted the negative consequences of polarization which reached an all-time high. One such topic is the Covid-19 vaccine which was developed in record time, and the public learned about its safety and possible risks through the media coverage.

In this capstone, we examine U.S. news media coverage on the …

A Unified Approach To M Dwarf Ages, Rocio Kiman

Dissertations, Theses, and Capstone Projects

Estimating ages of M dwarfs, the lowest mass stars in the Galaxy, is a current unresolved problem in Astrophysics. This dissertation focuses on developing a method to estimate ages for M dwarfs. This method consists of combining different age indicators in a Bayesian framework to achieve a precise age measurement. The age indicators I use are: 1) position in the color-magnitude diagram which is a proxy for effective temperature and luminosity, 2) movement of the stars in the Galaxy, or its 3D kinematics, 3) magnetic activity, measured by the Halpha emission line of the spectrum. In this dissertation I analyze …

Carbon And Nitrogen Dynamics Of A Lagoon Salt Marsh In Davenport, California, Mark D. Gormley

Dissertations, Theses, and Capstone Projects

Wetlands are complex environments that play a critical role in regulating the global biogeochemical cycle of carbon (C) and nitrogen (N). Wetlands are critical contributors to global climate change and atmospheric chemistry since they store as much as 33% of the world’s soil organic carbon (SOC), release more than 20% of the atmospheric methane (CH₄), and produce nitrous oxide (N₂O), an extremely potent greenhouse gas (GHG). Despite the enormous radiative forcing potential of carbon dioxide (CO₂), CH₄ and N₂O derived from wetlands, uncertainties over the rates of C sequestration and GHG …

Wave Excitation And Dynamics In Disordered Systems, Yiming Huang

Dissertations, Theses, and Capstone Projects

This thesis presents studies of the field and energy excited in disordered systems as well as the dynamics of scattering.

Dynamic and steady state aspects of wave propagation are deeply connected in lossless open systems in which the scattering matrix is unitary. There is then an equivalence among the energy excited within the medium through all channels, the Wigner time delay, which is the sum of dwell times in all channels coupled to the medium, and the density of states. But these equivalences fall away in the presence of material loss or gain. In this paper, we use microwave measurements, …

Adversarial Training For Skill Learning In A Mobile Robot, Todd W. Flyr

Dissertations, Theses, and Capstone Projects

Machine Learning in mobile robotics is sometimes hampered by the difficulties associated with the creation of a large corpus of labeled data that most neural network based learning algorithms demand. In recent years, advances in the field of machine learning have been facilitated via the creation of large collaboratively-created labeled training datasets that researchers can use as the basis for experiments to validate and improve their candidate neural network architectures. For the field of robotics, however, tasks are so disparate and the physical devices so varied that in most cases the creation of collaborative benchmark datasets are impractical. Obtaining data …

Synthesis, Characterization And Applications Of Europium Based Perovskite Oxide Nanoparticles, Nasim Farahmand

Dissertations, Theses, and Capstone Projects

The synthesis and characterization of nanocrystalline transition and rare-earth metal oxides have been studied widely over the past years. These materials possess unique physical, chemical, magnetic and dielectric properties which make them potential candidates for a wide range of applications such as electronics, energy storage and photocatalysis. There are a number of synthesis methods for preparing these materials, where most of them require stringent conditions such as high pressure and high temperature. However, in this study, a modified sol-gel synthesis has been used with a lower calcination temperature to make uniform nanocrystals of the transition/rare-earth metal oxide family. The focus …

Connecting Communities To Coastal Resilience: Enhancing Sustainability Through Public Participation In Salt Marsh Management And Restoration In Suffolk County, Ny, Jennifer L. Mcgivern

Dissertations, Theses, and Capstone Projects

Coastal resiliency is becoming significantly more critical to the livelihood of coastal communities as the frequency and intensity of storm events increases and is exacerbated by rising sea levels due to climate change. In October 2012 Superstorm Sandy impacted the New York-New Jersey area costing over $70 billion in storm damages and 147 lives lost, as storm surges surpassed record highs for the region. Protruding more than 100 miles into the Atlantic Ocean with over 1,000 miles of shoreline, Long Island is particularly vulnerable to the increasingly ferocious and numerous storms as well as the rising sea levels that climate …

Clifford Harmonics, Samuel L. Hosmer

Dissertations, Theses, and Capstone Projects

In 1980 Michelsohn defined a differential operator on sections of the complex Clifford bundle over a compact Kähler manifold M. This operator is a differential and its Laplacian agrees with the Laplacian of the Dolbeault operator on forms through a natural identification of differential forms with sections of the Clifford bundle. Relaxing the condition that M be Kähler, we introduce two differential operators on sections of the complex Clifford bundle over a compact almost Hermitian manifold which naturally generalize the one introduced by Michelsohn. We show surprising Kähler- like symmetries of the kernel of the Laplacians of these operators in …

Molecular Dynamics Simulations Of Self-Assemblies In Nature And Nanotechnology, Phu Khanh Tang

Dissertations, Theses, and Capstone Projects

Nature usually divides complex systems into smaller building blocks specializing in a few tasks since one entity cannot achieve everything. Therefore, self-assembly is a robust tool exploited by Nature to build hierarchical systems that accomplish unique functions. The cell membrane distinguishes itself as an example of Nature’s self-assembly, defining and protecting the cell. By mimicking Nature’s designs using synthetically designed self-assemblies, researchers with advanced nanotechnological comprehension can manipulate these synthetic self-assemblies to improve many aspects of modern medicine and materials science. Understanding the competing underlying molecular interactions in self-assembly is always of interest to the academic scientific community and industry. …

Monte Carlo, Molecular Dynamics And Network Analysis Of The Gramicidin Water Channel And Proton Transfer Pathways To Qb In Photosynthetic Reaction Centers, Yingying Zhang

Dissertations, Theses, and Capstone Projects

Water molecules play a key role in all biochemical processes. They help define the shape of proteins, and they are reactant or product in many reactions and are released as ligands are bound. They facilitate transfer of protons through transmembrane proton channel, pump and transporter proteins. Continuum electrostatics (CE) force fields such as used in MCCE (Multi-Conformation Continuum Electrostatics) capture electrostatic interactions in biomolecules with an implicit solvent, to give the averaged solvent water equilibrium properties. Hybrid CE methods can use explicit water molecules within the protein surrounded by implicit solvent. These hybrid methods permit the study of explicit hydrogen …

Diffraction-Based Studies Of Magneto- And Baro-Caloric Materials, Steven P. Vallone

Dissertations, Theses, and Capstone Projects

The field of calorics represents a class of materials that offer the potential for solid-state cooling and heating, and, given the global climate crisis, comprise a necessary and active area of research. A clear and thorough understanding of their internal structural interactions and their external response to the environment is necessary for overall progress in the field, as accurate theoretical modeling and efficient materials design for devices both depend on this information. Through analysis of x-ray and neutron diffraction, the atomic order and disorder that drives these interactions is revealed. This dissertation focuses on diffraction studies concerning representative samples from …

Automated Code Engine For Tensor Hypercontraction: Derivation, Optimization And Implementation Of Rank-Reduced Coupled Cluster Theories, Yao Zhao

Dissertations, Theses, and Capstone Projects

The ultimate goal of electronic structure theory is solving the electronic Schr¨odinger Equation. However, even accurate approximations of solving Schr¨odinger Equation, such as high order coupled cluster theories, require computational efforts that are too demanding to be applied on large chemical systems. This thesis tackles the problem of curse of dimensionality: how to reduce the time complexity of high-accuracy coupled cluster methods in order to accelerate computations of molecular energy. On one hand, we believe that low-rank approximation (i.e. Tensor HyperContraction) of high-order tensors appearing in coupled cluster theory is a promising way to achieve rank-reduced coupled cluster theory. On …

Making Space For Unquantifiable Data: Hand-Drawn Data Visualization, Eva Sibinga

Dissertations, Theses, and Capstone Projects

This project makes space for personal “data” around labor and care, prompting users to consider the concrete and abstract (quantifiable and unquantifiable) forms labor and care take in their lives. The interactive, subjective data visualization uses hand-drawn visual elements to foreground that data about care and human interaction will always be ambiguous and complex, that they may never be satisfactorily or universally quantified, and that they will always be out of reach of perfect categorization.

The project provides an alternative to prescriptive truth-telling with data. Instead of using a dataset to provide data-driven answers and insights to users, the interactive …

Enhanced Platinum (Ii) Drug Delivery For Anti-Cancer Therapy, Marek T. Wlodarczyk

Dissertations, Theses, and Capstone Projects

Over the years, anti-cancer therapies have improved the overall survival rate of patients. Nevertheless, the traditional free drug therapies still suffer from side effects and systemic toxicity, resulting in low drug dosages in the clinic. This often leads to suboptimal drug concentrations reaching cancer cells, contributing to treatment failure and drug resistance. Among available anti-cancer therapies, metallodrugs are of great interest. Platinum (II)-based agents are highly potent and are used to treat many cancers, including ovarian cancer (OC). Cisplatin (cis-diaminedichloroplatinum (II)) is the first Food and Drug Administration (FDA)-approved metallodrug for treatment of solid tumors, and its mechanism …

Developing Dynamical Probes Of Quantum Spin Liquids Inspired By Techniques From Spintronics, Joshua Aftergood

Dissertations, Theses, and Capstone Projects

We theoretically study low dimensional insulating spin systems using spin fluctuations as a probe of the spin dynamics. In some systems, low dimensionality in conjunction with other quantum fluctuation enhancing effects impedes spontaneous generation of long range magnetic ordering down to zero absolute temperature. In particular, we focus on exotic spin systems hosting mobile, fractionalized spin excitations above their ground state, and ultimately show that techniques already commonplace in spintronics can be utilized in the context of quantum magnetism to develop probes of exotic ground states.

We initially consider quantum spin chains (QSCs), and examine a system of two exchange-coupled …

Novel Hybrid Resampling Algorithms For Parallel/Distributed Particle Filters, Xudong Zhang

Dissertations, Theses, and Capstone Projects

Particle filters, also known as sequential Monte Carlo (SMC) methods, use the Bayesian inference and the stochastic sampling technique to estimate the states of dynamic systems from given observations. Parallel/Distributed particle filters were introduced to improve the performance of sequential particle filters by using multiple processing units (PUs). The classical resampling algorithm used in parallel/distributed particle filters is a centralized scheme, called centralized resampling, which needs a central unit (CU) to serve as a hub for data transfers. As a result, the centralized resampling procedures produce extra communication costs, which lowers the speedup factors in parallel computing. Even though some …

Evaluation Of The Potential Of Automated Sem-Eds Analysis For The Discrimination Of Inorganic Soil Particles, Anna S. Duggar

Dissertations, Theses, and Capstone Projects

Soil, that complex mixture of minerals, organic particles, chemicals, and anthropogenic materials, is ubiquitous and easily transferred, which gives it forensic relevance. Forensic soil analysis has traditionally included the identification and comparison of both organic and inorganic components, the inorganic portion being most commonly examined by light microscopy and other instrumental techniques. Predominantly, the inorganic materials in soil are naturally-occurring minerals, contributed as grains from the surrounding bedrock, which gives a soil its regional character. That parent material then undergoes physical, chemical, and anthropogenic changes producing wide geographic variation within a single region. This variation forms the basis for potential …

Representing The Derivative Of Trace Of Holonomy, Jeffrey Peter Kroll

Dissertations, Theses, and Capstone Projects

Trace of holonomy around a fixed loop defines a function on the space of unitary connections on a hermitian vector bundle over a Riemannian manifold. Using the derivative of trace of holonomy, the loop, and a flat unitary connection, a functional is defined on the vector space of twisted degree 1 cohomology classes with coefficients in skew-hermitian bundle endomorphisms. It is shown that this functional is obtained by pairing elements of cohomology with a degree 1 homology class built directly from the loop and equipped with a flat section obtained from the variation of holonomy around the loop. When the …