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2012

Aluminum

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Global Estimates Of Mineral Dust Aerosol Iron And Aluminum Solubility That Account For Particle Size Using Diffusion-Controlled And Surface-Area-Controlled Approximations, Qin Han, Charles S. Zender, J. Keith Moore, Clifton S. Buck, Ying Chen, Anne Johansen, Christopher I. Measures Jun 2012

Global Estimates Of Mineral Dust Aerosol Iron And Aluminum Solubility That Account For Particle Size Using Diffusion-Controlled And Surface-Area-Controlled Approximations, Qin Han, Charles S. Zender, J. Keith Moore, Clifton S. Buck, Ying Chen, Anne Johansen, Christopher I. Measures

All Faculty Scholarship for the College of the Sciences

Mineral aerosol deposition is recognized as the dominant source of iron to the open ocean and the solubility of iron in the dust aerosol is highly variable, with measurements ranging from 0.01–80%. Global models have difficulty capturing the observed variations in solubility, and have ignored the solubility dependence on aerosol size. We introduce two idealized physical models to estimate the size dependence of mineral aerosol solubility: a diffusion‐controlled model and a surface‐area‐controlled model. These models produce differing time‐ and space‐varying solubility maps for aerosol Fe and Al given the dust age at deposition, size‐resolved dust entrainment fields, and the aerosol …


Review Of Corrosion Aspects Of Compression Ignition Engine Parts Using Biodiesel Blends, B. Singh, John Korstad, Y. C. Sharma Jun 2012

Review Of Corrosion Aspects Of Compression Ignition Engine Parts Using Biodiesel Blends, B. Singh, John Korstad, Y. C. Sharma

College of Science and Engineering Faculty Research and Scholarship

This paper reviews the effects of corrosion on the engine parts that come in contact with a newly developed biodiesel fuel and its petrodiesel blend. Copper, aluminum, copper alloys (bronze), and elastomers caused significant levels of corrosiveness in biodiesel and biodiesel blend as opposed to low corrosion with petrodiesel. Specimens of stainless steel showed significant resistance to corrosion in biodiesel samples as compared to copper, aluminum, and copper alloys, but the level of corrosion was still higher than that in petrodiesel. Common methods adopted for measurement of corrosion include weight loss through static emersion tests, and electrochemical techniques by electrochemical …


Resonance Frequencies Of A Spherical Aluminum Shell Subject To Static Internal Pressure, Andrew A. Piacsek, Sami Abdul-Wahid, Robert Taylor May 2012

Resonance Frequencies Of A Spherical Aluminum Shell Subject To Static Internal Pressure, Andrew A. Piacsek, Sami Abdul-Wahid, Robert Taylor

All Faculty Scholarship for the College of the Sciences

Measurements of the vibrational response of a spherical aluminum shell subject to changes in the interior pressure clearly demonstrate that resonance frequencies shift higher as the pressure is increased. The frequency shift appears to be smaller for longitudinal modes than for bending wave modes. The magnitude of frequency shift is comparable to analytical predictions made for thin cylindrical shells. Changes in the amplitudes of resonance peaks are also observed. A possible application of this result is a method for noninvasively monitoring pressure changes inside sealed containers, including intracranial pressure in humans.


Aluminum In Food – The Nature And Contribution Of Food Additives, Robert A. Yokel Feb 2012

Aluminum In Food – The Nature And Contribution Of Food Additives, Robert A. Yokel

Pharmaceutical Sciences Faculty Publications

No abstract provided.


An Empirical Method For Correcting The Detector Spectral Response In Energy-Resolved Ct, Taly Gilat Schmidt Feb 2012

An Empirical Method For Correcting The Detector Spectral Response In Energy-Resolved Ct, Taly Gilat Schmidt

Biomedical Engineering Faculty Research and Publications

Energy-resolving photon-counting detectors have the potential for improved material decomposition compared to dual-kVp approaches. However, material decomposition accuracy is limited by the nonideal spectral response of the detectors. This work proposes an empirical method for correcting the nonideal spectral response, including spectrum-tailing effects. Unlike previous correction methods which relied on synchrotron measurements, the proposed method can be performed on the scanner. The proposed method estimates a spectral-response matrix by performing x-ray projection measurements through a range of known thicknesses of two or more calibration materials. Once estimated, the spectral-response matrix is incorporated into conventional material decomposition algorithms. A simulation study …


The Pharmacokinetics And Toxicology Of Aluminum In The Brain, Robert A. Yokel Jan 2012

The Pharmacokinetics And Toxicology Of Aluminum In The Brain, Robert A. Yokel

Pharmaceutical Sciences Faculty Publications

The chemical forms (species) of aluminum in blood plasma and brain extracellular fluid are considered, as they are the candidates for brain aluminum uptake and efflux. The blood-brain barrier is the primary site of brain aluminum uptake. The mechanism of brain uptake of aluminum transferrin, long thought to be mediated by transferrin-receptor mediated endocytosis, requires further investigation. Brain Al citrate uptake has been attributed to the sodium-independent Lglutamate/ L-cystine exchanger system, system Xc-. Reports have suggested aluminum can compromise blood-brain barrier integrity, however the studies were conducted with aluminum concentrations greatly exceeding those seen in human blood plasma. Aluminum appeared …


A Critical Review On Corrosion Of Compression Ignition (Ci) Engine Parts By Biodiesel And Biodiesel Blends And Its Inhibition, B. Singh, John Korstad, Y. C. Sharma Jan 2012

A Critical Review On Corrosion Of Compression Ignition (Ci) Engine Parts By Biodiesel And Biodiesel Blends And Its Inhibition, B. Singh, John Korstad, Y. C. Sharma

College of Science and Engineering Faculty Research and Scholarship

This paper reviews the effects of corrosion on the engine parts that come in contact with a newly developed biodiesel fuel and its petrodiesel blend. Copper, aluminum, copper alloys (bronze), and elastomers caused significant levels of corrosiveness in biodiesel and biodiesel blend as opposed to low corrosion with petrodiesel. Specimens of stainless steel showed significant resistance to corrosion in biodiesel samples as compared to copper, aluminum, and copper alloys, but the level of corrosion was still higher than that in petrodiesel. Common methods adopted for measurement of corrosion include weight loss through static emersion tests, and electrochemical techniques by electrochemical …


A Reaction Progress Variable Modeling Approach For Non-Ideal Multiphase Explosives, K. P. Ruggirello, P. E. Desjardin, M. R. Baer, M. J. Kaneshige, E. S. Hertel Jan 2012

A Reaction Progress Variable Modeling Approach For Non-Ideal Multiphase Explosives, K. P. Ruggirello, P. E. Desjardin, M. R. Baer, M. J. Kaneshige, E. S. Hertel

US Department of Energy Publications

This study concerns the development of a mixture fraction based reaction progress variable formulation for aluminized explosives. Highlights of the formulation include a fully compressible treatment of both the gas and solid phases (both aluminum and alumina), heterogenous and homogenous reactions, and effects of group combustion. Isolated particle simulations are validated against experimental data and DNS and show good agreement of burn times over a range of pressure and oxygen environments. The new models are implemented in the CTH shock physics code using a fractional step approach to allow for efficient computation of particle dynamics. Comparisons are made to experimental …


Identifying Smart Conducting Materials For Wi-Fi Electromagnetic Interference Shielding, Wham Al-Shabib, Daryoush Habibi, Zonghan Xie, Xiaoli Zhao Jan 2012

Identifying Smart Conducting Materials For Wi-Fi Electromagnetic Interference Shielding, Wham Al-Shabib, Daryoush Habibi, Zonghan Xie, Xiaoli Zhao

Research outputs 2012

The objective of this paper is to identify a suitable coating material in order to tune the microwave radiation and produce absorption losses for Wi-Fi devices. It is also desirable to obtain high absorption losses outside the Wi-Fi microwave frequency range of 2.4 GHz. Literature reviews of several types of material are described and compared for the use of the selected material in order to coat a Wi-Fi device for the desired absorption losses for that device. The selected material for the Wi-Fi device is usually a metal material or a combination of metals like Aluminium in polymer matrix with …


Rapid And Noncontaminating Sampling System For Trace Elements In Global Ocean Surveys, Gregory A. Cutter, Kenneth W. Bruland Jan 2012

Rapid And Noncontaminating Sampling System For Trace Elements In Global Ocean Surveys, Gregory A. Cutter, Kenneth W. Bruland

OES Faculty Publications

A system for the rapid and noncontaminating sampling of trace elements with volumes of up to 36 L per depth and including the dissolved and particulate phases has been developed for ocean sections that are a crucial part of programs such as International GEOTRACES. The system uses commercially available components, including an aluminum Seabird Carousel with all titanium pressure housings for electronics and sensors to eliminate zinc sacrificial anodes and holding twenty-four 12 L GO-FLO bottles, and a 7500 m, 14 mm Vectran conducting cable (passing over an A-frame with nonmetallic sheave) spooled onto a traction winch. The GO-FLO bottles …


Study Of Vacancy-Type Defects By Positron Annihilation In Ultrafine-Grained Aluminum Severely Deformed At Room And Cryogenic Temperatures, L H. Su, Cheng Lu, Lizi He, L C. Zhang, P Guagliardo, A K. Tieu, S N. Samarin, J F. Williams, H J. Li Jan 2012

Study Of Vacancy-Type Defects By Positron Annihilation In Ultrafine-Grained Aluminum Severely Deformed At Room And Cryogenic Temperatures, L H. Su, Cheng Lu, Lizi He, L C. Zhang, P Guagliardo, A K. Tieu, S N. Samarin, J F. Williams, H J. Li

Faculty of Engineering - Papers (Archive)

"Commercial-purity aluminum was processed by equal-channel angular pressing (ECAP) at room temperature (RT-ECAP) and cryogenic temperature (CT-ECAP) with liquid nitrogen cooling between two successive passes.It was found that the RT-ECAPed samples showed equiaxed microstructure after 4 and 8 ECAP passes, while the CT-ECAPed samples displayed slightly elongated microstructure and slightly smaller grain size.Moreover, the CT-ECAPed samples had higher hardness values than the RT-ECAPed samples subjected to the same amount of deformation.Positron annihilation lifetime spectroscopy (PALS) was used to investigate the evolution of vacancy-type defects during the ECAP deformation process.The results showed that three types of defects existed in the ECAPed …


Asymmetric Cryorolling For Fabrication Of Nanostructural Aluminum Sheets, Hailiang Yu, Cheng Lu, K. Tieu, Xianghua Liu, Yong Sun, Qingbo Yu, Charlie Kong Jan 2012

Asymmetric Cryorolling For Fabrication Of Nanostructural Aluminum Sheets, Hailiang Yu, Cheng Lu, K. Tieu, Xianghua Liu, Yong Sun, Qingbo Yu, Charlie Kong

Faculty of Engineering - Papers (Archive)

Nanostructural Al 1050 sheets were produced using a novel method of asymmetric cryorolling under ratios of upper and down rolling velocities (RUDV) of 1.1, 1.2, 1.3, and 1.4. Sheets were rolled to about 0.17 mm from 1.5 mm. Both the strength and ductility of Al 1050 sheets increase with RUDVs. Tensile strength of Al sheets with the RUDV 1.4 is larger 22.3% of that for RUDV 1.1, which is 196 MPa. The TEM observations show the grain size is 360 nm when the RUDV is 1.1, and 211 nm for RUDV 1.4.


Reinforcement With Graphene Nanosheets In Aluminum Matrix Composites, Jingyue Wang, Zhiqiang Li, Genlian Fan, H H Pang, Zhixin Chen, Di Zhang Jan 2012

Reinforcement With Graphene Nanosheets In Aluminum Matrix Composites, Jingyue Wang, Zhiqiang Li, Genlian Fan, H H Pang, Zhixin Chen, Di Zhang

Faculty of Engineering and Information Sciences - Papers: Part A

Graphene has a high fracture strength of 125 GPa, making it an ideal reinforcement for composite materials. Aluminum composites reinforced with graphene nanosheets (GNSs) were fabricated for the first time through a feasible methodology based on flake powder metallurgy. The tensile strength of 249 MPa was achieved in the Al composite reinforced with only 0.3 wt.% GNSs, which is 62% enhancement over the unreinforced Al matrix. The relevant strengthening mechanisms involved in the GNS/Al composites were discussed along with experimental procedure.


Controls On Dissolved Cobalt In Surface Waters Of The Sargasso Sea: Comparisons With Iron And Aluminum, R. U. Shelley, Peter N. Sedwick, T. S. Bibby, P. Cabedo-Sanz, T. M. Church, R. J. Johnson, A. I. Macey, C. M. Marsay, E. R. Sholkovitz, S. J. Ussher, P. J. Worsfold, M. C. Lohan Jan 2012

Controls On Dissolved Cobalt In Surface Waters Of The Sargasso Sea: Comparisons With Iron And Aluminum, R. U. Shelley, Peter N. Sedwick, T. S. Bibby, P. Cabedo-Sanz, T. M. Church, R. J. Johnson, A. I. Macey, C. M. Marsay, E. R. Sholkovitz, S. J. Ussher, P. J. Worsfold, M. C. Lohan

OES Faculty Publications

Dissolved cobalt (dCo), iron (dFe) and aluminum (dAl) were determined in water column samples along a meridional transect (∼31°N to 24°N) south of Bermuda in June 2008. A general north-to-south increase in surface concentrations of dFe (0.3-1.6 nM) and dAl (14-42 nM) was observed, suggesting that aerosol deposition is a significant source of dFe and dAl, whereas no clear trend was observed. for near-surface dCo concentrations. Shipboard aerosol samples indicate fractional solubility values of 8-100% for aerosol Co, which are significantly higher than corresponding estimates of the solubility of aerosol Fe (0.44-45%). Hydrographic observations and analysis of time series rain …


A Material System For Reliable Low Voltage Anodic Electrowetting, Mehdi Khodayari, Jose Carballo, Nathan B. Crane Jan 2012

A Material System For Reliable Low Voltage Anodic Electrowetting, Mehdi Khodayari, Jose Carballo, Nathan B. Crane

Faculty Publications

Electrowetting on dielectric is demonstrated with a thin spin-coated fluoropolymer over an aluminum electrode. Previous efforts to use thin spin-coated dielectric layers for electrowetting have shown limited success due to defects in the layers. However, when used with a citric acid electrolyte and anodic voltages, repeatable droplet actuation is achieved for 5000 cycles with an actuation of just 10 V. This offers the potential for low voltage electrowetting systems that can be manufactured with a simple low-cost process.