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Tetrakis(N-Ethyl-9-Oxo-4-Azonia-5-Aza-9h-Fluorene) Tetra-Μ3-Iodo-Hexa-Μ2-Iodo-Dodecaiodohexabismuthate, Meredith A. Tershany, Andrea M. Goforth, Mark D. Smith, Leroy Peterson Jr., Hans-Conrad Zur Loye
Tetrakis(N-Ethyl-9-Oxo-4-Azonia-5-Aza-9h-Fluorene) Tetra-Μ3-Iodo-Hexa-Μ2-Iodo-Dodecaiodohexabismuthate, Meredith A. Tershany, Andrea M. Goforth, Mark D. Smith, Leroy Peterson Jr., Hans-Conrad Zur Loye
Faculty Publications
The new iodobismuthate compound (C13H11N2O)4[Bi6I22] has been synthesized solvothermally by reacting BiI3, Zn(NO3)2·6H2O and 4,5-diazafluoren-9-one in a water/ethanol solvent mixture. The asymmetric unit of the compound contains two independent [N-ethyl-4,5-dafo]+ cations and one-half of a centrosymmetric [Bi6I22]4- anion. The average terminal Bi-I, Bi-2-I and Bi-3-I bond lengths in the anion are 2.8923 (2), 3.1403 (2) and 3.3022 (2) Å, respectively.
Tetrakis[2-(2-Pyridyl)Pyridinium] Tetra-Μ3-Iodo-Hexa-Μ2-Iodo-Dodecaiodohexabismuthate And Bis[Tris(2,2'-Bipyridine)Ruthenium(Ii)] Di-Μ4-Iodo-Octa-Μ2-Iodo-Dodecaiodohexabismuthate, Andrea M. Goforth, Meredith A. Tershansy, Mark D. Smith, Leroy Peterson Jr., Hans-Conrad Zur Loye
Tetrakis[2-(2-Pyridyl)Pyridinium] Tetra-Μ3-Iodo-Hexa-Μ2-Iodo-Dodecaiodohexabismuthate And Bis[Tris(2,2'-Bipyridine)Ruthenium(Ii)] Di-Μ4-Iodo-Octa-Μ2-Iodo-Dodecaiodohexabismuthate, Andrea M. Goforth, Meredith A. Tershansy, Mark D. Smith, Leroy Peterson Jr., Hans-Conrad Zur Loye
Faculty Publications
Crystals of the title compounds were grown solvothermally in an ethanol-water solvent mixture using ruthenium triiodide, 2,2'-bipyridine and bismuth triiodide as starting materials. Tetrakis[2-(2-pyridyl)pyridinium] tetra-3-iodo-hexa-2-iodo-dodecaiodohexabismuthate, (C10H9N2)4[Bi6I22], crystallizes in the triclinic space group P and is the major reaction product. The asymmetric unit of this compound consists of half a centrosymmetric [Bi6I22]4- anion and two independent 2,2'-bipyridinium cations. The minor product of the reaction is bis[tris(2,2'-bipyridine)ruthenium(II)] di-4-iodo-octa-2-iodo-dodecaiodohexabismuthate, [Ru(C10H8N2)3] …
Photoreductive Dissolution Of Ferrihydrite By Methanesulfinic Acid: Evidence Of A Direct Link Between Dimethylsulfide And Iron-Bioavailability, Anne M. Johansen, Jennifer M. Key
Photoreductive Dissolution Of Ferrihydrite By Methanesulfinic Acid: Evidence Of A Direct Link Between Dimethylsulfide And Iron-Bioavailability, Anne M. Johansen, Jennifer M. Key
All Faculty Scholarship for the College of the Sciences
Within open‐ocean regions where excess macronutrients are present, phytoplankton growth is limited by the bioavailability of iron supplied to these areas primarily within atmospheric aerosols of crustal origin. However, processes that control the abundance of biologically accessible iron in these aerosols are largely unknown. Here we show that dissolution of ferrihydrite, a surrogate iron(oxy)hydroxide phase found in atmospheric waters, is enhanced in the presence of methanesulfinic acid (MSIA, CH3SO2H, a dimethylsulfide (DMS) oxidation intermediate) in laboratory irradiation experiments with aqueous suspensions that simulate marine aerosol particles. The increased release of soluble Fe(II) is attributed to a …
Semiclassical Nonadiabatic Dynamics Based On Quantum Trajectories For The O(3P,1D)+H2 System, Sophya Garashchuk, Vitaly A. Rassolov, George C. Schatz
Semiclassical Nonadiabatic Dynamics Based On Quantum Trajectories For The O(3P,1D)+H2 System, Sophya Garashchuk, Vitaly A. Rassolov, George C. Schatz
Faculty Publications
The O(3P,1D)+H2→OH+H reaction is studied using trajectory dynamics within the approximate quantum potential approach. Calculations of the wave-packet reaction probabilities are performed for four coupled electronic states for total angular momentum J = 0 using a mixed coordinate/polar representation of the wave function. Semiclassical dynamics is based on a single set of trajectories evolving on an effective potential-energy surface and in the presence of the approximate quantum potential. Population functions associated with each trajectory are computed for each electronic state. The effective surface is a linear combination of the electronic states with the contributions …
Tuning Supported Catalyst Reactivity With Dendrimer-Templated Pt-Cu Nanoparticles, Natalie N. Hoover, Bethany J. Auten, Bert D. Chandler
Tuning Supported Catalyst Reactivity With Dendrimer-Templated Pt-Cu Nanoparticles, Natalie N. Hoover, Bethany J. Auten, Bert D. Chandler
Chemistry Faculty Research
The effects of particle composition on heterogeneous catalysis were studied using dendrimer-encapsulated nanoparticles (DENs) as precursors to supported Pt-Cu catalysts. Bimetallic Pt-Cu DENs with varying Pt/Cu ratios were prepared in an anaerobic aqueous solution and deposited onto a high-purity commercial alumina support. The dendrimer template was then thermally removed to yield supported nanoparticle catalysts, which were studied with toluene hydrogenation and CO oxidation catalysis as well as infrared spectroscopy of adsorbed CO. Incorporating Cu into Pt nanoparticles had opposite effects on the two test reactions. Cu acted as a mild promoter for CO oxidation catalysis, and the promoting effect was …
Implications Of Mass Education On Chemistry Higher Education, Christine O'Connor
Implications Of Mass Education On Chemistry Higher Education, Christine O'Connor
Conference Papers
The following paper discusses the implications of government policy on widening of participation at third level institutes. The increase in ‘non-traditional’ students has been widely recognised on an international scale; however some inequality issues still exist. The ‘struggles’ associated with widening of participation and creating a ‘new’ student type is discussed in particular reference to chemistry education. A change in mindset of staff on their pedagogical approach to cater for a diverse student body with a broad range of learner types is required. This must be supported from a departmental and institutional level. A look at the literature to investigate …
Solubilisation, Purification And Processing Of Single Walled Carbon Nanotubes Using Organic Molecules, Theresa Hedderman
Solubilisation, Purification And Processing Of Single Walled Carbon Nanotubes Using Organic Molecules, Theresa Hedderman
Doctoral
The aims of this research are seven fold; • To enhance the solubility of SWNTs in organic solvents. • To purify an untreated sample of SWNTs that contains many side products. • To gain a greater understanding of the interaction between the polycyclic aromatic hydrocarbons and SWNTs. • To debundle and disperse SWNTs. • To select SWNTs of a specific structure based on the structures of the polycyclic aromatic hydrocarbons used. • To observe and compare the interaction of polycyclic aromatic hydrocarbons with SWNTs produced by different methods. • To elucidate factors which contribute to different degrees of interaction between …