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Radiative Heat Transfer Analysis Of Railroad Bearings For Wayside Thermal Detector Optimization, James Alexandro Aranda

Theses and Dissertations

Wayside hot-box detectors (HBDs) are devices that are currently used to evaluate the health of railcar components including bearings, axles, and brakes by monitoring their temperatures. While HBDs have been instrumental in reducing some train derailments in the past few decades, the number of non-verified bearing removals has increased significantly. In general, HBDs tend to underestimate bearing temperatures in both field service and in laboratory testing, which is not surprising considering the simple two-point calibration method that is used to calibrate these devices. Because of this, different calibrations were compared and analyzed including two-point, three-point, and multi-point calibrations. Analysis of …

Synthesis And Design Of Metals Sulfide/Carbon Composite-Fibers Anodes For Lithium Ion Batteries, Jorge Lopez

Theses and Dissertations

In this study, Forcespinning is used to produce Titanium sulfide (TiS2)/carbon composite fibers for use as lithium-ion battery anodes. The high surface area to volume ratio of the composite fibers can have a high impact on the ionic and electronic conductivity of the active materials leading to improved electrochemical performance of the battery. TiS2 nanoparticles were chosen as the active materials to produce Metal-Li-alloys/C composite fibers due to their high theoretical capacity and low volume change during charge/discharge cycles. The use of a 2-D layered structure of TiS2 nanoparticles in the carbon fiber matrix can greatly accommodate more Li-ions between …

Boron Nitride Thin-Film Deposited By Rf Magnetron Sputtering, Jesus A. Valladares Gonzalez

Theses and Dissertations

Cubic Boron Nitride is considered a superhard material, its thermochemical stability makes it suitable for applications with corrosive environments and high temperatures. C-BN is grown by PDV on Si substrates. The plasma is energized via an RF source to sputter the target. The ion species in the plasma can be described by the classic electrodynamic expression . Plasma temperature is given by T = (6.2836*E/8*k). The sputter is given by the ratio of the heat transfer to the enthalpy of formation , of the target. The Hall Measurement is performed as recommended by NIST. The measurement was performed on a …

Local Delivery Of Mesenchymal Stem Cells Expressing Osteogenesis-Inducing Microrna For Bone Tissue Engineering Applications, Marco Antonio Arriaga

Theses and Dissertations

Bone is capable of regenerating autonomously when the injury is small (< 2.5 cm), however, large (> 2.5 cm) or insufficiently vascularized defects require intervention to repair. The overall goal of this project is to contribute towards the development of novel strategies to aid bone tissue regeneration by delivering mesenchymal stem cells expressing microRNAs that induce expression of the runt-related transcription factor 2 (RUNX2). It was determined that porous polycaprolactone (PCL) scaffolds fabricated to have a higher surface area to volume ratio (SVR) (> 80) compared to lower SVR (< 80) were hydrolyzed at a higher rate. Scaffolds fabricated with 80 vol. %/300–500 µm porogen were optimal for cell colonization as higher absorbance of metabolized MTT was detected compared to other scaffold types. From the subset of 5 miRNAs tested, miRNA-26a, miRNA-196 and miRNA-218 demonstrated higher upregulation of RUNX2 gene expression and calcium mineralization and thus, are promising candidates for bone tissue regeneration.

Improving Thermal-Hydraulic Performance Of Flat-Tube Louver-Fin Heat Exchangers By Eliminating Louver Gap Condensate Bridges, Alan L. Jones

Theses and Dissertations

The air side performance of heat exchangers is a well studied subject. Flat-tube louver-fin heat exchangers experience a decrease in performance when operating in dehumidifying conditions. As water vapor is pulled from the air, water condensate may create blockages between louvers. Flat-tube louver-fin heat exchanger may experience a drop in thermal-hydraulic performance by up to 50% due to blockages. The aim of this study is to make macro scale geometric changes to louver dimensions and eliminate louver condensate bridges. By eliminating louver condensate blockages, the heat exchanger should see an overall gain in thermal performance when compared to current fin …

Aligning Anatomical Knee Model With Kinematic Experimental Data To Investigate Squat Exercise, Jose Mario Salinas

Theses and Dissertations

A two-dimensional inverse dynamics anatomical model of the human knee was developed by aligning anatomical structures of the knee (taken from x-rays) with kinematic experimental data (collected from motion capture cameras). The mathematical model was used to study the forces related to the tibiofemoral and patellofemoral joints during the squat and knee extension exercises. Forces calculated by the model included: tibiofemoral contact force, patellofemoral contact force, forces generated by cruciate ligaments, quadriceps force, and patellar tendon force. Bone alignment consisted of superimposing the geometric center of the lateral femoral condyle (from x-rays) with the relative instantaneous center of rotation of …

Generalized &Thetas;-Parameter Peakon Solutions For A Cubic Camassa-Holm Model, Michael Rippe

Theses and Dissertations

In this paper we outline a method for obtaining generalized peakon solutions for a cubic Camassa-Holm model originally introduced by Fokas (1995) and recently shown to have a Lax pair representation and bi-Hamiltonian structure by Qiao et al (2012). By considering an amended signum function—denoted sgn &thetas;(x)—where sgn(0) = &thetas; for a constant &thetas;, we explore new generalized peakon solutions for this model. In this context, all previous peakon solutions are of the case &thetas; = 0. Further, we aim to analyze the algebraic quadratic equation resulting from a substitution of the single-peakon ansatz equipped with our amended …

A Systematic Approach To High Blood Pressure Risk Analysis And Healthcare Cost Reduction In Young Adults [Metodología Sistemática Para El Análisis De Riesgo Y Reducción De Costos De Servicios Médicos De Hipertensión En Adultos Jóvenes], Francisco Rafael Torres Diaz

Theses and Dissertations

The purpose of this research is to utilize publicly available data to estimate the current rate of occurrence of undiagnosed High Blood Pressure (HBP) in young adults (18 to 24 years old) and the out-of-pocket healthcare expenses associated with complications of HBP, to provide feasible alternatives to mitigate the effects on a region's economy. This has been done by building a Risk Factor Simulation Model that utilizes known HBP risk factors’ correlation to HBP, insurance coverage data, and rate of diagnosis to formulate the average Risk Factor Value for a region, which through an Annual Expected Cost Function estimates the …

Analysis Of Flash In Injection Molding Using Flow Simulation And Design Of Experiments, Claudia Lizette Lopez

Theses and Dissertations

This study presents a method of detecting flash by using flow simulation along with the mold processing conditions and the DOE analysis values from all input and output parameters that will be calculated. All of this would be completed in order to compare and verify the DOE and simulation results and find out if it can be applied to an actual live production molded part, in this case, the Leap char ribbon. This paper will also describe the scrap issue that is presently happening on this molded part, and what are the options that there is in order to find …

Forcespinning Of Metal Oxides And Metal Sulfides And Their Applications As Alternative Anode Materials For Lithium-Ion And Sodium-Ion Batteries, Alejandra Valdez

Theses and Dissertations

Molybdenum-Oxide/Carbon (MoO2/C) composite nanofibers were synthesized using Forcespinning method and subsequent heat treatment, for use as anode materials for lithium-ion batteries. Due to the layered structure of MoO2, the composite nanofibers are very promising for use as anode material for LIBs. The MoO2/C composite fiber anodes exhibit good electrochemical performance and cycling stability.

Design And Characterization Of An Affordable Laser Communication System, Andrea Tellez

Theses and Dissertations

Over the last decades, an exponential growth in communication demand has been observed. Radio Frequency (RF) band has been one of the most used bandwidths for data transmission in the world. Given the influence and the continuous growth of communication technology, the RF spectrum is overpopulated. More efficient systems are necessary to meet the communication needs of this generation. A change to optical bandwidth is the most practical alternative to deal with the congestion of radio frequency.

The aim of this thesis is to present the features of Free Space Optical links with off-the-shelf components. A description of how these …

Antimicrobial Properties And Characterization Of Polymer/Composite Nanofibers, David De La Garza

Theses and Dissertations

Pathogenic bacteria have been the cause of many illnesses worldwide due to their rapid growth and reproduction in food and water. Bacteria-resistant antibiotics and kidney complications due to overuse of antibiotics has remained a large public health concern. The goal of this research project was to find an alternative by producing nanofibers that inhibit microbial growth utilizing Forcespinning technology. The Forcespinning of poly(acrylic acid) (PAA) with Single Wall Carbon Nanotubes functionalized with OH (SWCNT-OH) and Ag + flakes were carried out on solutions with different concentrations. Scanning electron microscopy was used to view fiber morphology and investigate the average nanofiber …

Experimental And Computational Studies Of Rotation And Proton Tunneling In Organic Molecules And Molecular Dimers, Agapito Serrato Iii

Theses and Dissertations

An introduction to the relations of classical and quantum mechanics are presented in brief. As is an overview of the instrumentation and quantum chemical analysis performed to characterize the molecules presented in in this thesis. The pure rotational spectrum of 3,3,3-trifluoro-2(trifluoromethyl)propanoic acid, perfluorobutyric acid–formic acid dimer, and tropolone–formic acid dimer were measured using high-resolution microwave spectroscopy. The spectra have been observed using a cavity-based Fourier-transform microwave (FTMW) spectrometer and/or a chirped-pulse FTMW.

Multifunctional Carbon Systems (Interlaminated Carbon Nanofiber Mats/ Carbon Nanotubes Polymer Composites), Homero Gonzalez Guardiola

Theses and Dissertations

Carbon nanomaterials have been an attractive topic within diverse industrial sectors given their outstanding properties for decades. One of the properties that has been calling attention is it’s shielding effectiveness (SE) for electromagnetic interference (EMI), because of the constant race of improving portable electronic and wireless communication devices among other applications. The present study, analyzes the properties of interlaminated Carbon Nanofiber (CNF) mats/Carbon Nanotubes (CNT) polymer composites, emphasizing in its capability to shield EMI. The CNF mats were developed with Polyvinyl alcohol (PVA) as a precursor and by means of the Forcespinning® technology which uses centrifugal force to create fibers …

Approximate Set Union Via Approximate Randomization, Pengfei Gu

Theses and Dissertations

We develop an randomized approximation algorithm for the size of set union problem |A1 U A2 U...UAm|, which given a list of sets A1,...,Am with approximate set size m i for Ai with mi ∈ ((1–βL)|A i|,(1+βR)|Ai|), and biased random generators with Prob(x = RandomElement(Ai)) ∈ [1–a L/Ai, 1 +aR/Ai] for each input set Ai and element x ∈ Ai, where i = 1,2,...,m. The approximation |Ai | |Ai | ratio for |A1 U A2 U...UAm| is in the range [(1–ϵ)(1–aL)(1–βL),(1+ϵ)(1+β R)(1+βR)] for any ϵ ∈ (0,1), where α L,αR,βL,βR ∈ (0,1). The complexity of the algorithm …

Microwave-Assisted Ring-Opening Polymerization Of Poly(Ε-Caprolactone), Nancy Obregon

Theses and Dissertations

Poly(ϵ-caprolactone) (PCL) is a biodegradable polyester notorious by its promising properties and applications in the biomedical field. In this work, microwave-assisted ringopening polymerization (ROP) of ϵ-caprolactone (ϵ-CL) was performed. Stannous octoate [Sn(Oct)2] was used as catalyst with and without an alcohol initiator. The different initiators tested were glycerol, diethylene glycol (DEG) and poly(ethylene) glycol (PEG). Aiming to establish reaction parameters, the influence of different reaction times, temperatures, and monomer:initiator:catalyst ratios were examined. It was observed that the reaction was obtained and high molecular weight PCL was achieved successfully without an initiator. However, mixed results were obtained using an initiator. Products …

Magnetic Polymer Composite As A Thermosensitive Agent For Induced Hyperthermia, Nareg Ohannesian

Theses and Dissertations

Polyetheretherketone (PEEK) - magnetite (Fe3O4) blended compounds were produced by high speed vibration milling of PEEK-Fe 3O4 powders exposed to hexane and heated to the melting point (~350 °C) to form the homogeneous magnetic polymer composite, which provided a uniform dispersion of magnetite with low agglomerations in the polymer matrix. Polymer composite with 10 wt.% of magnetite displayed a magnetic saturation of 8 emu/g, tensile strength of 60 MPa and Young’s modulus of 4.4 GPa. Biotoxicity assessment was conducted via in vitro assay. The composite did not induce any adverse reactions, permitting use in medical applications. This study develops analytical …

Lead Doped Carbon Nanofibers In Li-Ion Batteries, Omar Torres

Theses and Dissertations

Lead acid batteries have been a very reliable rechargeable battery since its inception in the mid-1800s. Lithium-Ion batteries have been sought out for their light-weight and capacity of holding large amounts of energy in a small amount of space. Few studies have been conducted in the use of lead in lithium-ion batteries.

In this thesis, lead-doped carbon nanofibers were produced by using the Forcespinning® method and used as an anode on a lithium-ion battery. The morphology, material characterization and thermal properties of the anode material were analyzed using the Scanning Electron Microscopy (SEM), Energy Dispersive X-Ray Spectroscopy (EDS), Thermogravimetric Analysis …

Fibers For Skin Regeneration, Astrid Michelle Rodriguez Negron

Theses and Dissertations

This thesis presents the successful development of biocompatible Polyvinyl Butyral (PVB), PVB/Polylysine and PVB/Tannic Acid (TA)/Polylysine fibers from an ethanol solution, Polyhydroxybutyrate (PHB), PHB/Polylysine, PHB/TA/Polylysine fibers from a chloroform solution and Chitosan (CH)/Pullulan (PL)/TA and CH/PL/TA/Polylysine fibers from an aqueous solution. The fibers were mass produced utilizing the Forcespinning® (FS) technology. The morphology of the fibers was characterized using a scanning electron microscope (SEM) and the fibers average diameter was calculated. The thermal properties of the fibers were characterized using a thermogravimetric analyzer (TGA) and a differential scanning calorimeter (DSC). The antibacterial activity of the fibers was assessed using against …

Design Of A Multidirectional Wear Testing Device For Simulating Wear Of Biocompatible Materials Used In Joint Implants, Carlos A. Rodriguez Betancourth

Theses and Dissertations

In the present work, a novel multidirectional pin-on-disc wear testing device designated CNC-POD (computer-numerical-control pin-on-disc) capable of replicating the cross-shear motions experienced by a prosthesis in vivo was designed and developed in the UTRGV in order to evaluate the wear resistance of new biomaterials. The CNC-POD consists of six temperature-controlled pin-on-disc stations mounted on a two-axis CNC table (X-Y). Each pin-on-disc station is load-programmable up to 510 Newtons (115 pounds). The CNC table allows the machine to reproduce a wide range of 2D patterns in millimeter scale on the six stations under a specific load. Friction force is measured during …

Simplification Of Eeg Signal Extraction, Processing, And Classification Using A Consumer-Grade Headset To Facilitate Student Engagement In Bci Research, Jesus D. Rodriguez

Theses and Dissertations

Brain-computer interfaces (BCIs) are an emerging technology that leverage neurophysiological signals as input to computing systems. By circumventing the reliance on traditional input methods (e.g., mouse and keyboard), BCIs show a promising alternative interaction modality for people with disabilities. Advances in BCI research have further inspired a range of novel applications, such as the use of neurophysiological signals as passive input (e.g., to detect and reduce operator workload when managing multiple machines). BCIs have also emerged as a tool for student engagement due to the intrinsic interdisciplinarity of the technology, which spans the fields of computer science, electrical engineering, neuroscience, …

The Effect Of Heat Generation In The Railroad Bearing Thermoplastic Elastomer Suspension Element On The Thermal Behavior Of Railroad Bearing Assembly, Oscar Osvaldo Rodriguez

Theses and Dissertations

Understanding the internal heat generation of the railroad bearing elastomer suspension element during operation is essential to predict its dynamic response and structural integrity, as well as to predict the thermal behavior of the complete railroad bearing assembly including the bearing adapter. The latter is essential for sensor selection and placement within the adapter (e.g., typical temperature sensors have operating ranges of up to 125°C or 257°F). The internal heat generation is a function of the loss modulus, strain, and frequency. Based on experimental studies, estimations of internally generated heat within the thermoplastic elastomer pad were obtained. The calculations show …

The Use Of Mixed Organic/Ionic Liquid Electrolytes With Forcespun Metal Oxides/Carbon Microfiber Electrodes In Lithium Ion Batteries, Jahaziel Villarreal

Theses and Dissertations

Conventional Lithium-Ion Battery (LIB) electrolytes have serious safety concerns because of highly flammability. In order to mitigate this drawback, alternative electrolytes with low volatility and non-flammable need to be synthesis. Ionic liquids (ILs) and mixed organic ionic liquid electrolytes (MOILEs) are the most suitable replacement for the highly flammable commercial organic electrolytes. In this academic investigation, a new perspective on the electrochemical performance of the ionic liquid EMI-TFSI as an alternate non-flammable electrolyte. In parallel, the use of Forcespun nanofibers as binder-free anodes will be analyzed to further improve overall electrochemical performance.

Buffer Controlled Cache For Low Power Multicore Processors, Marven Calagos

Theses and Dissertations

This thesis proposes a buffered dual access mode cache to reduce power consumption in multicore caches for embedded systems. This cache is called Buffer Controlled Cache (BCC cache). The proposed scheme introduces a pre-cache buffer to determine how to access the cache. The proposed cache shows better prediction rates and lower power consumption than conventional caches, such as Phased cache and Way-prediction cache. For single core implementation, Simplescalar and Cacti simulators have been used for these simulations using SPEC2000 benchmark programs. The experimental results show that the proposed cache improves the power consumption by 37%-42% over the conventional caches. Multi2Sim …

Superharmonic Resonance Of Second Order For Electrostatically Actuated Mems Cantilevers, Martin Amador Botello

Theses and Dissertations

The nonlinear dynamics of electrostatically actuated micro-electro-mechanical system (MEMS) cantilever resonators are investigated. The applied Alternating Current (AC) voltage is in the realm of superharmonic resonance of the second order (near one-fourth of the natural frequency of the resonator) and hard excitations. Method of Multiple Scales (MMS) and Reduced Order Models (ROMs) are used to solve the dimensionless partial differential equation (PDE) of motion along with boundary and initial conditions. MMS transforms the PDE of motion into zero-order and first-order problems. ROMs uses mode shapes of vibration for undamped cantilever resonator as a basis of functions. ROM is …

Carbon Nanotube Yarn Based Dye Sensitized Solar Cells With Enhanced Electron/Hole Pair Recombination Prevention Characteristics, Glenn E. Grissom

Theses and Dissertations

Carbon nanotube yarn based solar cells (CNTYSCs) show promise in a variety of applications such as military and smart fabrics. We use a highly aligned and interwoven Carbon nanotube yarn (CNTY) for the working electrode (WE) and counter electrode (CE), to create a flexible super strong, conductive, and photo active surface for the support of a calcined TiO2 nano-solution and macro-solution deposition as a base for added functionalizations of a dye-sensitized solar cell (DSSC) that is able to maintain its flexibility and integrity. The CNT fiber based solar cells have power conversion ability that is independent of the direction of …