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Materials Characterization In The Development Of Combustion-Based Methods For Synthesis Of Niobium Silicides, Edgar Maguregui

Open Access Theses & Dissertations

The use of characterization techniques is essential for a better understanding of novel manufacturing processes and for investigating how the process parameters affect the products. Mechanically activated self-propagating high-temperature synthesis (MASHS) is an attractive method for the production of high-temperature structural materials. In the present work, it was used to fabricate Nb5Si3 compound and Nb5Si3/Nb composites. It has been shown that for mechanical activation of Nb/Si mixtures, a planetary ball mill is more effective than a shaker ball mill used in prior research on MASHS of Nb5Si3. The influence of mixture composition and experimental parameters, such as milling time and …

Low-Valent Synthons Of Titanium : Investigations On Structure-Reactivity Relationships, Rolando Aguilar

Open Access Theses & Dissertations

Strategies for the functionalization of abundant, small molecules into products with added value provide a powerful approach to address environmental sustainability issues. Dinitrogen (N2), and carbon oxides (CO, CO2), are examples of the ample, yet, underutilized atmospheric feedstock of nitrogen and carbon building blocks to produce a variety of chemicals. Although, potentially valuable, small molecules are inert under most conditions, and as such, their industrial activation often requires heterogeneous catalysts operated under high pressures (200 atm) and temperatures (450-600 ºC).

To this end, great efforts in synthetic inorganic chemistry have been devoted to the generation of well-defined and highly reactive …