Digital Commons Network^™

Fabrication Of Binder-Free Electrodes Based On Graphene Oxide With Cnt For Decrease Of Resistance, Di Zhang

Masters Theses

In electrode double layer capacitor (EDLC), electrodes usually contain binder materials to provide adhesion between electrode materials. However, binder materials usually bring unwanted resistances to the component due to their non-conductivity properties and the occupation of ion cavities. The purpose of this thesis is to demonstrate the feasibility of fabricating electrodes for EDLCs by using carbon nanotubes (CNTs) and graphene oxide (GO) without using any binding materials. At the same time, investigating the binder-free electrode’s electrochemical properties and make an assumption of its potential application in the future.

The slurry of binder-free electrodes was fabricated by ultrasonicating water suspended CNTs …

Investigation Of Shot1-Binding Atpases In Arabidopsis Thaliana, Sam Zelman

Masters Theses

Mitochondria play critical roles not only in primary metabolism as a central organelle for ATP generation, but also in responding to abiotic stresses. We identified a mutation in the MTERF18 (Mitochondrial Transcription Termination factor)/SHOT1 (Suppressor of hot1-4 1) gene in Arabidopsis thaliana that enables plants to better tolerate heat and oxidative stresses, presumably due to reduced oxidative damage, but the exact molecular mechanism of the heat tolerance is unknown. In order to reveal the stress tolerance mechanisms of mterf18/shot1 mutations, it is critical to understand the molecular defects of the mutant and to identify …

Real-Time Tddft-Based Filtered Spectroscopy, Ivan Williams

Masters Theses

We demonstrate the ability to simulate targeted excitation of atomistic systems using our real-time TDDFT-based simulation framework NESSIE. Traditional ap- proaches for extracting spectra through real-time TDDFT involves excitation of all frequencies via impulse requiring long simulation times and yielding poor resolution. By exciting the system with a modulated sinc pulse between the frequencies of inter- est we are able to obtain a spectral response with far more precision in a significantly shorter time frame than competing implementations.

Understanding Shame And Guilt In Chinese Culture, Se Min Suh

Masters Theses

Research on shame and guilt has mainly been conducted in individualistic Western cultures. Some qualitative research, however, examined shame and guilt experiences in Chinese culture. Bedford (2004) identified 7 terms that represent emotional experiences of “shame” and “guilt.” We report 3 studies examining Mandarin Chinese speakers’ recalled experiences of negative self-conscious emotions and their related appraisals and motivations. Results reveal that instead of categorizing negative self-conscious emotion terms into 2 superordinate categories of “shame” and “guilt,” 3 clusters are more suitable based on their correlations and associated characteristics. Implications for cross-cultural studies on self-conscious emotions are discussed.

Exploration Of The Association Between Muscle Volume And Bone Geometry Reveals Surprising Relationship At The Genetic Level, Prakrit Subba

Masters Theses

The evolution of jaws in cichlid fishes of the East African Great Lakes is a textbook example of adaptive radiation in vertebrates. Karl Liem postulated that this adaptive radiation has been possible due to the functional decoupling of two cichlid functional units – the pharyngeal jaw (PJ) and the oral jaw (OJ). This functional decoupling of the jaws has enabled the OJ to be relieved of its dual role of prey capturing and processing and has allowed the PJ to take on the role of prey processing. As a result, African cichlids have adapted the morphology of their functional units …

Grandmotherhood In Ukraine: Behavioral Variation And Evolutionary Implications, Sofiya Shreyer

Masters Theses

Grandmothers are known to increase the health and well-being of their grandchildren in many different populations. However, grandmothers may vary in their contributions based on their relatedness to their grandchildren. In some populations, maternal grandmothers decrease the risk of mortality and increase the health of their grandchildren more than paternal grandmothers. Grandmaternal influence also sometimes varies based on the gender of the grandchild. The behavioral mechanisms of grandmaternal investment are not well understood and have not been explored in the heavily intergenerational context of Eastern Europe. This study examines the behavioral variation of sixty-two Ukrainian grandmothers through interviews and a …

Optimal Mammography Schedule Estimates Under Varying Disease Burden, Infrastructure Availability, And Other Cause Mortality: A Comparative Analyses Of Six Low- And Middle- Income Countries, Shifali Shifali

Masters Theses

Low-and-middle-income countries (LMICs) have a higher mortality-to-incidence ratio for breast cancer compared to high-income countries (HICs) because of late-stage diagnosis. Mammography screening is recommended for early diagnosis, however, current screening guidelines are only generalized by economic disparities, and are based on extrapolation of data from randomized controlled trials in HICs, which have different disease burdens and all-cause mortality compared to LMICs. Moreover, the infrastructure capacity in LMICs is far below that needed for adopting current screening guidelines. This study analyzes the impact of disease burden, infrastructure availability, and other cause mortality on optimal mammography screening schedules for LMICs. Further, these …

Brutalism And The Public University: Integrating Conservation Into Comprehensive Campus Planning, Shelby Schrank

Masters Theses

The University of Massachusetts Amherst, the Commonwealth’s flagship campus, is home to several Brutalist buildings. Similar to other buildings of this genre, they have gone unrecognized for their importance to the campus and their prominent architectural significance. Additionally, due to the ravages of close to 50 years of exposure coupled with limited maintenance and, in some instances, neglect they are now at a point where restorative maintenance is critical in ensuring their future contribution to the campus.

This thesis addresses the importance of creating a comprehensive, long-term plan for these buildings, by first looking to the University’s most prominent, yet …

In-Vitro Propagation And Fish Assessments To Inform Restoration Of Dwarf Wedgemussel (Alasmidonta Heterodon), Jennifer Ryan

Masters Theses

The dwarf wedgemussel (Alasmidonta heterodon) is a federally endangered freshwater mussel that once ranged from New Brunswick to North Carolina, but now only exists in isolated populations throughout its diminished range. Laboratory propagation in conjunction with augmentation or reintroduction is considered a critical component of dwarf wedgemussel restoration. My thesis aimed to I) develop in-vitro propagation techniques including methods to minimize microbial contamination for two Alasmidonta species and II) compile and assess critical fish assemblage information at existing dwarf wedgemussel presence and absence locations to inform future restoration activities. For the first objective (Chapter 2) I assessed three …

How Can Employers Contribute To Reducing Commuter-Generated Carbon Emissions? Evaluating Employer-Provided Commuter Benefits In Cambridge, Ma, Mary Richards

Masters Theses

Encouraging a more sustainable commuter mode shift and improving urban transportation systems have the potential to reduce anthropogenic greenhouse gas emissions (GHGs), a major contributor to climate change. Replacing some single-occupancy vehicle (SOV) trips with alternative modes of transportation, such as public transit, walking, or bicycling, represents one approach to begin reducing transportation-related emissions. Collectively, these shifts in transportation patterns would help to reduce the negative social, economic, and environmental costs associated with high rates of personal vehicle use. Employer-provided benefits programs have the potential to influence commuter behavior by making sustainable, alternative commuting choices a more convenient and economically …

Effects Of Berberine On Development In Caenorhabditis Elegans, Zhuojia Qian

Masters Theses

Berberine is an isoquinoline alkaloid found in some plants and has many bioactivities including anti-microbial, lipid- and glucose-lowering, anti-cancer, anti-inflammatory, etc. However, there is limited knowledge about berberine’s effects on development and locomotive activity. Herein, in vivo studies were conducted to determine these effects of berberine using Caenorhabditis elegans as an in vivo model. Treatment of berberine at 50 μM starting at L1 stage significantly retarded the growth rate of nematodes, and reduced the length, width and moving speed of worms by 19%, 12% and 29%, respectively, compared to the control. In addition, triglycerides (TG) and protein content in worms …

Network Virtualization And Emulation Using Docker, Openvswitch And Mininet-Based Link Emulation, Narendra Prabhu

Masters Theses

With the advent of virtualization and artificial intelligence, research on networked systems has progressed substantially. As the technology progresses, we expect a boom in not only the systems research but also in the network of systems domain. It is paramount that we understand and develop methodologies to connect and communicate among the plethora of devices and systems that exist today. One such area is mobile ad-hoc and space communication, which further complicates the task of networking due to myriad of environmental and physical conditions. Developing and testing such systems is an important step considering the large investment required to build …

Mitigation Of Teratogenic Agents: Is There Promise In Ion Modulating Drugs?, Aastha Pokharel

Masters Theses

As reported by the CDC, birth defects remain a common occurrence in the United States, with malformations originating in many places in the developing organism. Furthermore, the etiology of many of these defects remain unknown, with some factors consisting of genetics, environmental pollutants and teratogens. In our study, we examined whether insults by teratogenic agents, ethanol in particular, can be mitigated by hyperpolarizing agents acting to restore the cell’s potential. We first evaluated whether three hyperpolarizing drugs (Lamotrigine, Gabapentin, and Ivermectin) induced teratogenic effects on CD-1 mice and found that Ivermectin induced craniofacial malformations, and exposure to Lamotrigine and Gabpentin …

Cumulative Grief, Xuan Pham

Masters Theses

A written thesis to accompany the M.F.A. Exhibition Cumulative Grief, in which the artist's personal and familial narrative explores the complexity and nuances of racial grief.

Assessing Stress Tolerance Of Organelle Small Heat Shock Protein Mutants In Arabidopsis Thaliana, Parth Patel

Masters Theses

Molecular chaperones are proteins found in virtually every organism and are essential to cell survival. When plants are heat stressed, they upregulate and downregulate multiple genes, many of which are associated with the heat shock response. Small heat shock proteins (sHSPs) are one class of molecular chaperones that are upregulated during heat shock. They are proposed to act as the first line of defense by binding to heat sensitive proteins and preventing their irreversible aggregation. However, many details of sHSP function remain to be discovered and exactly what proteins they protect is unresolved. In addition to cytosolic sHSPs found in …

From Intentional Awareness To Environmental Action: The Relationship Between Mindfulness And Pro-Environmental Behaviors, Nischal Neupane

Masters Theses

Mindfulness is defined as the ‘awareness that arises through paying attention to the present moment, on purpose, non-judgmentally’. Despite ample empirical evidence of its efficacy in inducing positive behavior change, almost no work has investigated the viability of using mindfulness-based interventions (MBIs) to promote pro-environmental behavior. Some recent studies have demonstrated consistent correlational relationships between mindfulness levels and pro-environmental attitudes (e.g., connectedness to nature), intentions, and some pro-environmental behaviors (e.g., recycling, “green” purchasing decisions), but no past work has explicitly examined mindfulness in the context of energy saving behaviors. Results from both quantitative and qualitative research conducted as part of …

Blue Eyes Crying In The Rain: Hindsight In 2020, Kenneth Murphy

Masters Theses

The paintings that comprise Blue Eyes Crying in the Rain: Hindsight in 2020 are the output of my research and artistic practice at the University of Massachusetts Amherst. These paintings make visible the complex experiences and misperceptions of men in contemporary society. My intent was to create paintings that bring light to some of the darker aspects of manhood and rework phobias about manhood and male homosexuality through self-deprecation. This reworking is accomplished through the integration of disparate ideas and images, including perception, location, and exteriority, into compositions wherein representation and portraiture (specifically self- portraiture) make visible particular psychological states …

Does Invasion Science Encompass The Invaded Range? A Comparison Of The Geographies Of Invasion Science Versus Management In The U.S., Lara Munro

Masters Theses

Biases in invasion science lead to a taxonomic focus on plants, particularly a subset of well-studied plants, and a geographic focus on invasions in Europe and North America. Geographic biases could also cause some branches of invasion science to focus on a subset of environmental conditions in the invaded range, potentially leading to an incomplete understanding of the ecology and management of plant invasions. While broader, country-level geographic biases are well known, it is unclear whether these biases extend to a finer scale and thus affect research within the invaded range. This study assessed whether research sites for ten well-studied …

The Shape Of U: Mapping Out Protective Elements In Mrna Escapees, Jacob Miles

Masters Theses

A crucial step of the viral life cycle of Kaposi’s Sarcoma Herpesvirus (KSHV) lytic infection is the triggering of a massive RNA decay event termed “Host Shutoff”. Host Shutoff is driven by the viral endonuclease SOX which leads to the destruction of over 70% of the total transcriptome. This process cripples cellular gene expression and allows for viral reprograming of the cell for the purpose of viral replication. Co-evolution has led to the host developing a multitude of antiviral defenses aimed at preserving certain cellular RNAs linked to antiviral responses. One such defense are RNA secondary structures located within the …

War Of The Moon, Bibiana Medkova

Masters Theses

Space, in the post-World War context, was the new frontier of ‘global’ dominion. Space Race of the 1950s was a competition to signal technological capability and military strength. The objective of War of the Moon is to unpack the motivation for Moon race in 1950s. What did countries have to gain politically, economically, socially and technologically by conquering space and landing on the moon. At what cost? Who financed it, and where did the labor, land, and raw materials sourced come from. And how it was used to accomplish said landing. Space security is a massive aspect of all current …

Effect Of Jackfruit-Derived Extract Consumption On Colitis-Associated Colon Tumorigenesis In Mice, Jingwen Lin

Masters Theses

Colorectal cancer is the third most common cancer and the fourth most common cause of cancer-related death in the world. The global burden of colorectal cancer is also expected to increase by 60%, to over 2.2 million new cases and 1.1 million annual deaths, by the year 2030. Jackfruit is known for its packed nutrition including many antioxidants: vitamin C, carotenoids and flavanones. It has also been used in traditional medicine due to its potential protection against many chronic diseases. However, there is limited research studying the potential effect of jackfruit on colorectal cancer. Here, we used a well-established AOM/DSS …

Metric Learning Via Linear Embeddings For Human Motion Recognition, Byoungdoo Kong

Masters Theses

We consider the application of Few-Shot Learning (FSL) and dimensionality reduction to the problem of human motion recognition (HMR). The structure of human motion has unique characteristics such as its dynamic and high-dimensional nature. Recent research on human motion recognition uses deep neural networks with multiple layers. Most importantly, large datasets will need to be collected to use such networks to analyze human motion. This process is both time-consuming and expensive since a large motion capture database must be collected and labeled. Despite significant progress having been made in human motion recognition, state-of-the-art algorithms still misclassify actions because of characteristics …

The Welfare States: Examining U.S. State-Level Benefits For Families With Children, 1987-2015, Anthony Huaqui

Masters Theses

Welfare state scholars have amassed competing theoretical explanations for the development of welfare policies. When considering the U.S. case, a discussion of federalism is central to these theoretical examinations. How power in policymaking is distributed amongst the varying levels of government is influential in the construction of the U.S. welfare state. Standard quantitative approaches to U.S. welfare research have offered a limited analysis of how theoretical explanations change after historical moments of welfare reform. In this study, I examine the institutional changes introduced to U.S. welfare in 1996 by way of the Personal Responsibility and Work Opportunity Reconciliation Act (PRWORA). …

Crustal Evolution Of The New England Appalachians: The Rise And Fall Of A Long-Lived Orogenic Plateau, Ian Hillenbrand

Masters Theses

The rise and demise of mountain belts, caused by growth, modification, or removal of the continental lithosphere are fundamental processes that influence almost all Earth systems. Understanding the nature, timing, and significance of active processes in the creation and evolution of modern mountain belts is challenged by a lack of middle crustal and lower crustal exposures. Analogues can be found in ancient orogens, whose deeply eroded roots offer a window into deeper processes, yet this record is complicated by overprinting events and complex deformational histories. Research presented herein constrains the tectonic history of multistage Appalachian Orogen, type locality of the …

Exodus, A Museum Of Between: Directing An Original Staging Of Object Journalism, Oral Testimony And Early Italian Opera, Gabriel Harrell

Masters Theses

This written thesis documents how I, accompanied by a team of talented colleagues, conceived of, planned, and began the process of staging Exodus, a museum of between. I begin with an introduction to the theory and influences that shaped the work in its earliest stages. I go on to discuss the major themes of the work, chiefly an excavation of the idea of belonging, and posit a model of theater making modeled on a kaleidoscope, a model that aims to serve as a device through which to see one of our oldest stories with new eyes. I discuss the three …

An Experimental Investigation Of How Peer Criticism And Praise Affect Urges For Self-Injury, Lauren Haliczer

Masters Theses

Nonsuicidal self-injury (NSSI) is prevalent among young adults, and is associated with increased suicide risk. The self-punishment hypothesis theorizes that individuals who are highly self-critical may engage in NSSI due to finding the experience of pain as ego-syntonic. Although evidence links self-critical views to NSSI, minimal research has examined how these views are influenced by more proximal social stressors, such as peer criticism, to trigger NSSI urges. The current study addresses the following questions: (1) Will the effects of recalled peer criticism (vs. praise and a neutral interaction) on pain endurance (a proxy measure for NSSI urges) and self-reported NSSI …

Validity Parameters For Step Counting Wearable Technologies During Treadmill Walking In Young People 6-20 Years Of Age, Zachary Gould

Masters Theses

Introduction: Wearable technologies play an important contemporary role in the measurement of physical activity (PA) and promotion of human health across the lifespan, including for young people (i.e., children, adolescents, and young adults). As new objective wearable technologies continue to develop, standardized approaches to documenting validation parameters (i.e., measures of accuracy, precision, and bias) are needed to ensure confidence and comparability in step-defined PA. Purpose: To produce validity parameters for step counting wearable technologies during treadmill walking in young people 6-20 years of age Methods: 120 participants completed 5-minute treadmill bouts from13.4 to 134.1 m·min^-1. Participants wore eight …

Magnetite Mineralization Of The Hammondville Pluton: Poly-Phase Kiruna Type Iocg Magnetite-Apatite Deposits In The Lyon Mountain Granite, Phillip Geer

Masters Theses

Recent mapping of the Eagle Lake Quadrangle, NY, coupled with whole-rock geochemistry and microscopy has offered insight into the petrogenesis of the magnetite-apatite deposits of the Hammondville mining district in the eastern Adirondack Mountains. This study provides insight into the magmatic history of the ca. 1060-1050 Ma Lyon Mountain Granite (Hammondville Pluton) which is intimately related to, and hosts the deposits in this area. Magnetite seams are commonly surrounded by well layered magnetite gneiss, which typically parallel the seams, although in some outcrops appear to be slightly truncated by them. Mineralization is generally concordant with the weak layering found throughout …

Nozzle Clogging Prevention And Analysis In Cold Spray, Alden Foelsche

Masters Theses

Cold spray is an additive manufacturing method in which powder particles are accelerated through a supersonic nozzle and impinged upon a nearby substrate, provided they reach their so-called critical velocity. True to its name, the cold spray process employs lower particle temperatures than other thermal spray processes while the particle velocities are comparably high. Because bonding occurs mostly in the solid state and at high speeds, cold spray deposits are distinguished for having low porosity and low residual stresses which nearly match those of the bulk material.

One complication with the cold spray process is the tendency for nozzles to …

Enforcing Higher Standards For Flood Hazard Mitigation In Vermont, Tamsin Flanders

Masters Theses

The state of Vermont faces increasing risk of costly damage from catastrophic flooding events as climate change increases the frequency of heavy rains and cumulative precipitation. In addition to increasing flood inundation risk, extreme precipitation events are leading to high rates damage from fluvial erosion—erosion caused by the force of floodwater and the materials it carries. As in all U.S. states, flood hazard governance in Vermont is shared by multiple levels of government and involves a complex compliance model that relies on local governments to regulate private property owners to achieve community, state, or federal goals.

To encourage municipalities to …