Digital Commons Network^™

Scalable And Continuous Fabrication Of Dendrimer Based Gene And Protein Delivery Systems, Joseph Johnston

Masters Theses

"Gene and protein therapeutics play critical roles in the drug market and represent the future of biopharmaceuticals. Polymeric nanoparticle-based gene/protein delivery systems are promising owing to their ability to protect the cargo from degradation, improving intracellular delivery and transfection efficiency as well as abundant sources and flexibility to be modified. Yet the successful industrialized production and clinical application of polymeric nanoparticle-based delivery systems have long been limited by unsatisfied delivery efficiency and the lack of reproducible and scalable methods for the preparation of uniform nanoparticles with good batch to batch consistency. To address the unsatisfied efficacy and difficulty in scale-up …

Comprehensive Evaluation Of Novel Medium-Temperature And High-Temperature Resistant Re-Crosslinkable Preformed Particle Gels For Conformance Control, Zhanmiao Zhai

Masters Theses

"Gel treatment has been widely used to control excessive water production and improve oil recovery in mature oilfields. In comparison to traditional preformed particle gel (PPG), re-cross linkable preformed particle gel (RPPG) has a significant advantage in treating abnormal features such as open fractures, fracture-like channels, and void space conduits (VSC). This research provides a comprehensive evaluation of two novel RPPG products developed in our lab: medium-temperature resistant RPPG (MT-RPPG) for a Middle East reservoir and a high-temperature resistant RPPG (HT-RPPG) for North Sea reservoirs (130 ^oC).

We assessed the effect of the monomer types and concentration, pH, salinity, …

Power Generation From Waste Heat During Oil Production, Subrahmanya Chandra Bhamidipati

Masters Theses

"The increase in the world population is causing a significant increase in the global demand for energy. This rise in demand is generally met with the use of fossil fuels. But there is considerable pressure to lessen the release of carbon through the combustion of fossil fuels. One way that the oil and gas industry can provide increased energy without carbon combustion is by extracting the latent heat energy contained in produced oil, gas and water from producing reservoirs, and from water which is cycled through depleted, end-of-life or abandoned reservoirs. Extracting this energy and using it to provide direct …

Analysis Of Refracturing Activities In The Major Shale Plays In The United States, Faisal Shammam

Masters Theses

"Refracturing of existing horizontal multistage wells has increased over the past decade in the oil industry. This work aims to investigate all the refracturing operations in the most active shale plays in the united states (Bakken, Niobrara, Marcellus, Permian, Eagle Ford, Barnett, and Haynesville) in terms of completion technique, candidate selection, treatment types, and refracturing production efficiency. To collect the data of the refractured wells, an advanced data analytics approach was applied to separate the refractured wells from 170,000 wells reported in FracFocus, a public chemical registry for hydraulic fracturing in the United States, and combine it with DrillingInfo database, …

Investigation Of Post-Acid Stimulation Impacts On Well Performance Using Fracture Modeling And Reservoir Simulation In A Jurassic Carbonate Reservoir, Muaath Alansari

Masters Theses

"Well stimulation (well fracturing) became an essential tool in the Oil and Gas industry to unlock the potential of unconventional reservoirs all over the world and especially in the Middle East. In Kuwait, well stimulation is obligatory when dealing with deep Jurassic carbonate reservoirs. Thus, the well fracture designing process plays a very critical role in determining the success of the stimulation job and the improvement of the recovery.

Several wells stimulated with 20% HCL have shown wide variations in both short and long term well production performance. The research aims to investigate and identify the possible reasons causing these …

Relationships Among Mineralogy, Geochemistry, And Oil And Gas Production In The Tuscaloosa Marine Shale, Hayley Roxana Beitel

Masters Theses

"The Tuscaloosa Marine Shale (TMS) is an unconventional shale reservoir located in southeast Louisiana and southwest Mississippi. Limited mineralogical and geochemical data for the TMS have been published. The data that do exist indicate that the formation is heterogeneous. Consequently, previous investigators and oil and gas companies have not managed to effectively link mineralogical and chemical changes to oil and gas production in the TMS. These linkages are critical to establish for future exploration efforts. In this study, we attempt to establish these relationships by gathering all existing mineralogical and chemical data in the TMS, including newly acquired data from …

Development Of Amine-Functionalized Mesoporous Alumina For Radioiodine Removal From Water, Mansour Mohammed Alsalbokh

Masters Theses

“Radioactive materials have spread due to careless disposal and nuclear disasters. Some radionuclides can exist in an aqueous media, like radioactive iodine. As a result, in this work amine-functionalized mesoporous alumina was developed to adsorb radioactive iodine from the liquid phase. Bismuth was incorporated, using a wet impregnation method, to test it as a possible silver replacement. Amine grafting was used to functionalize the surface of the mesoporous alumina. All materials prepared in this work were characterized by N₂ physisorption, FTIR and TGA to determine the textural properties, surface functionality, and amine loading. The synthesized materials were tested for …

Data Analytics Of Natural Gas Injection Enhanced Oil Recovery For Unconventional Reservoirs, Ali Waqar

Masters Theses

"Unconventional Enhanced Oil recovery, via the injection of natural gas has attracted great attention, as studies and projects have shown to be promising. An overview of pertinent studies has been carried out. Core Scale Laboratory Experiments, Core Scale Simulation, Field Scale simulation and pilot projects are analyzed. Data is collected for Core, Reservoir, Operational, and recovery information. Thereafter, Data analysis techniques are applied to identify data ranges, distributions, trends, relationships, and to eventually reach conclusions.

Huff and Puff injection is the preferred mode of injection, delivering most promising results for unconventional reservoirs. Across all the studies, with increase in amount …

Microgel Placement And Plugging Performance In Sand Filled Fracture For Conformance Control, Baihua Lin

Masters Theses

“Preformed particle gels (PPG) has been widely applied for conformance control in heterogeneous reservoirs with fractures and super-K channels. As a plugging agent, PPG could plug the fractures or high permeability streaks and divert the displacing fluid into low permeability matrix. Many studies have been conducted to investigate the potential of PPGs as a water cut reduction and improved oil recovery agent using homogeneous sandpacks or heterogeneous core samples with man-made open fractures. However, no research has been carried out to understand how PPG injection and plugging performance will be changed if the fractures are filled with sands. Herein, the …

Evaluation Of Eor Potential Of Low Salinity Polymer In Enhancing Heavy Oil Recovery On The Alaska North Slope, Shize Yin

Masters Theses

"Alaska's North Slope (ANS) contains vast amount of viscous oil resources that have not been extracted. This study focuses on the investigation over the potential shown by low-salinity polymer flooding in improving the recovery of ANS heavy oil through laboratory experiments.

At the beginning, coreflooding experiments were performed with silica sandpacks. The synergy between low-salinity water flooding and polymer flooding was proved, and the low-salinity polymer showed a better performance than the normal-salinity polymer. Further, the sandpacks prepared with formation sand from an oilfield on the ANS was then employed so as to simulate the reservoir condition. A series of …

Methane Dry Reforming Reaction On Cr, V, In, And Ga Supported Sapo-34 Zeolite, Ehigiator Festus Ojo

Masters Theses

”The CO₂ reforming of methane is a significant research area in mitigating and transforming two greenhouse gases for the production of syngas. The reaction has been investigated for four different promoted catalysts to determine their reactant's conversion, product’s selectivity, and their respective syngas ratios.

The catalytic test was investigated under atmospheric conditions at 600⁰C for 6.5h with a WHSV of 4800 ml g^-1 h^-1. The conversion and selectivity of catalysts 9Al 1V-inc SAPO-34, 9Al 1Cr-inc SAPO-34, 9Al 1Ga-inc SAPO-34, and 9Al 1In-inc SAPO-34 were analyzed. The CH₄ conversion for the different catalysts are, 9Al 1Cr-inc …

Asphaltene Stability In Crude Oil During Carbon Dioxide Injection And Its Impact On Oil Recovery: A Review, Data Analysis, And Experimental Study, Sherif M. Fakher

Masters Theses

"Crude oils are usually associated with many compounds, some of which are favorable and others, which are not. One of the most unfavorable components of crude oil that pose severe operational problems and decreases oil production significantly are asphaltenes. These compounds are solids that are homogenized in the crude oil at room temperature but tend to separate from solution when agitated. They can deposit in the reservoir pores, wellbore, and transportation pipelines thus causing severe operational problems and oil recovery reduction.

Even though researchers have been studying asphaltenes for more than 100 years, there is still an ambiguity concerning asphaltene …

Investigating The Use Of Class C Flyash-Based Geopolymer Cement As A Potential Alternative To Portland Cement To Seal Co₂ Storage Wells, Priyesh Parimal Jani

Masters Theses

"Capturing emitted carbon dioxide from the source of emission and storing it underground is one effective way to reduce the amount of CO₂ in the atmosphere and is called carbon capture and storage (CCS). For the successful CCS project, it is necessary to ensure long term storage of injected CO₂ inside these selected reservoirs. Portland cement used to cast wells in these reservoirs degrade in CO₂ environment and can create migration path for leakage of CO₂. The aim of this study was to provide a comprehensive review about the problem, to propose a new geopolymer …

Computational Fluid Dynamics Modeling Of Proppant Static Settling Velocity In High Viscosity Friction Reducers, Chen Yuan

Masters Theses

"In the current petroleum fracturing industry, it is necessary to understand the downhole migration and settling velocity of the proppant. If we can master this information well, it will be a great help to obtain effective propped fracture conductivity. In order to study the transport of proppants in the well, we used laboratory experiments and computer numerical simulations to compare the results to get a meaningful conclusion. We spent a lot of time building models on a powerful computer and comparing the experimental conclusions. We finally decided to use computational fluid dynamics (CFD) as the simulation platform, discrete phase method …

Gel Composition And Brine Concentration Effect On Hydrogel Dehydration Subjected To Uniaxial Compression, Xinrui Zhao

Masters Theses

"Gel treatment is a process that injects the gel into a reservoir to control the conformance and improve the sweep efficiency of injection fluids. At a certain pressure gradient, the gel dehydrates in a reservoir due to mechanical forces. This work evaluates the effects of the gel composition and brine concentration on gel dehydration under uniaxial compression. A sodium acrylate-co-acrylamide based gel cross-linked with N, N'-Methylenebisacrylamide (MBAA) was used for the study. The compression test is performed with a rheometer with a plate-plate geometry. The gel dehydration under pressure was measured to see how gel dehydration would be impacted by …

Breaker Evaluation And Formation Damage Remediation Of Re-Crosslinkable Preformed Particle Gel (Rppg), Enze Zhou

Masters Theses

"Re-crosslinkable preformed particle gel (RPPG) is a newly developed preformed particle gel for improving sweep efficiency and oil recovery by blocking or reducing the conductivity of fractures and fracture-like channels or conduits. However, RPPG has the potential to plug the facilities or damage the formation if a treatment is not properly conducted.

This work presents the performance of selected oxidizing breakers on the degradation of RPPG. The influence of a few factors on the degradation process was investigated, including breaker type, breaker concentration, temperature, gel concentration, gel aging time, and gel size. Results indicate that breaker type, concentration, and temperature …

Performance Investigation Of Surface Modified Ceramic Microfiltration Membranes And The Effects Of Ionic Strength, Choji Bitrus Daches

Masters Theses

"The performance of ceramic membranes surface coated with cysteic acid to improve efficiency and reduce fouling rate was studied under two transmembrane pressure (TMP) and constant crossflow velocity (CFV). The filtration process was done in crossflow mode to allow for extended operation of the membranes. the performance of the membranes were determined in terms of the measured fluxes and on content rejection. Cleaning-in-place (CIP) was done on the membranes to ensure flux recovery after each run. The results showed significant improvement on the performance of the membranes with respect to high permeate fluxes and high oil content rejection (> 99.5%). …

Developing A Model System Of Liquid Lubricants For Space Applications: Multiple Alkylated Cyclopentane In Alumina Enclosed Surface, Vidit Singh

Masters Theses

"Lubricants are substances used for reducing friction wear tear and energy losses between two moving bodies. For space applications, normal lubricants cannot be used as they cannot survive the harsh and demanding conditions of space. Multiple Alkylated Cyclopentanes (MACs) have been utilized as space lubricants in recent times with tremendous results. NASA uses the MACs for their missions in space, in particular 1,3,4- tri-(2-octyldodecyl) cyclopentane sold by Nye Lubricants under the name of Pennzane^TM.

In this research, an effort has been made to identify appropriate potential models for simulating Pennzane molecules and to develop MD simulation codes to …

Review And Data Analysis Of Low Salinity Water Effect Through Induced Fine Migration, Dawei Xu

Masters Theses

"Low salinity water flooding (LSWF) is well proved to be an effective EOR technology both in laboratory and field tests, however, the conditions for LSWF to work and EOR mechanism is still debatable. Up till now, many mechanisms have been proposed to explain the incremental oil recovery in sandstone by LSWF, for instance, fine migration, ionic exchange, wettability alteration and pH increase.

In this study, we only focus on low salinity water flooding effect through induced fine migration mechanism. The objective of this study is to conduct a comprehensive analysis using statistical analysis methods and explaining the mechanism of fine …

Modeling Overpressure Development During Shale Rock Compaction Coupling Poroelasticity And Permeability Evolution Above 3km Depth, Wenyu Zhao

Masters Theses

"The evolution of pore pressure including overpressure during sedimentation is an important process to consider when analyzing whether high pore pressure causes rock failure. High pore pressure is caused by under-compaction due to the rapid burial of low-permeability sediments, and as a result, porosity decreases less rapidly with depth than in normally compacted sediments where porosity decreases exponentially with depth. While under-compaction related pore pressure magnitudes have been determined empirically, in most numerical modeling approaches, the pore pressure is either applied as a static magnitude or coupled to a fluid flow simulator. This study simulates the pore pressure evolution during …

Diffusion Kinetics In Promising Adsorbents For Gas Capture Processes, Teresa Gelles

Masters Theses

"This reports the results of experimental studies aimed at characterizing the transport properties of promising adsorbents for various gas capture processes by the "zero length column" (ZLC) technique. ZLC was used to measure the intracrystalline diffusivities of single and binary components of ethane and ethylene in powder and pellet samples of paraffin-selective adsorbents Ni(bdc)(ted)_0.5 (Ni-BT) and ZIF-7 for the purpose of olefin/paraffin separation. Results show that binary gaseous systems result in intracrystalline diffusion time constants slightly lower than those in single component gaseous streams due to coadsorption effects. It was also found that ethylene diffusion was affected by surface …

Hydraulic Fracture Design Optimization For Nubian Sandstone Formation In Libya, Housameddin Mohamed Sherif

Masters Theses

There is growing interest in developing unconventional oil and gas reserves in Libya, such as the tight portions of the Nubian sandstone.

Well-X7 is a development well drilled to a TD of 13,005' penetrating the Upper Nubain Sandstone (UNSS) at 12,122'-12,207' and the Lower Nubain Sandstone (LNSS) at 12,524'-12,880' KB. Based on open hole logs, the UNSS has 71 ft of net pay and the LNSS was found to have 295 ft of net pay. Openhole logs also showed low permeabilities of 2.5 and 3 md for the UNSS and LNSS, respectively. The well was initially perforated in both zones …

Proppant Transport With Varying Injection Points And Its Impact On Proppant Development Inside A Fracture, Shail Janakbhai Soni

Masters Theses

"This study presents experimental work which examines the effect of perforation placement and density on proppant placement within a hydraulic fracture. The study also investigates the effect of proppant angularity.

Experiments were conducted with ceramic proppant injected in a fracture slot model consisting of three injection points at the bottom, middle and top of the fracture slot, and two outlets, at the bottom and top of the fracture model. The effect of single point injection height was investigated by injecting solely at the bottom, middle or top of the apparatus, for both bottom and top outlet conditions. Multiple injection points …

Monobore Completion Design: Classification, Applications, Benefits And Limitations, Anwar Khaled Al-Fadhli

Masters Theses

"A monobore completion is a simple completion design that uses the same internal diameter from the bottom of the well to surface. This may be accomplished by cementing a string of casing in a well, or by having tubing stabbed into a polished bore receptacle on a casing liner the same size as the tubing. Monobore completions have been applied extensively in oil and gas fields around the world, both onshore and offshore, from very low reservoir flow to extremely high production rates, since the late 1980s. They have proven beneficial due to their simplicity and cost savings. This study …

The Development Of A New Formulation Of Fly Ash Class C Based Geopolymer And Assessing Its Performance In Presence Of Drilling Fluid Contamination, Mohamed Saad Ahdaya

Masters Theses

"Cementing is one of the most critical steps in the drilling and completion of oil wells. Traditionally, Portland cement is used for oil cementing operations; however, geopolymer materials have recently attracted much attention because they are more cost-effective and have less environmental impacts.

An intensive laboratory work was conducted to obtain a new formulation of fly ash class C based geopolymer cement to be used as a potential alternative cementing material to Portland cement in oil and gas cementing. Twenty-four variations of fly ash class C based geopolymers were prepared, and by comparing several of their properties using API standard …

Carbon Black Production, Analyzing And Characterization, Shadha Khalid Jebur

Masters Theses

"Carbon black (CB) plays a significant function in the development of the electrical and mechanical properties of high performance for a tough elastic polymeric substance such as rubber materials. Thus, CB is widely used to manufacture a massive number of products such as reinforcing and pigment phase in automobile tires due to its high ability to increase tire life by reducing the thermal damage. This material is also used in belts, hoses, and other non-tire rubber goods. Before use in valuable materials. CB should first be analyzed and characterized by different instruments to obtain its mechanical properties. A new thermal …

Ceria Nanostructured Catalysts For Conversion Of Methanol And Carbon Dioxide To Dimethyl Carbonate, Jawad Hassan A Al Drwish

Masters Theses

"In this study, three different shapes of ceria (CeO₂) nanostructures (e.g., nanooctahedra, nanocubes and nanorods) were synthesized via the hydrothermal method and screened for carbonylation reaction. Of these three shapes of nanostructures, the nanorod was doped with metals such as Ca, Ni, Cu, and Co by wet impregnation method. All materials were characterized by XRD, NH₃/CO₂-TPD, XRF, FTIR and N₂ physorption to determine the crystal size and phases, acid-base properties, metal loading, and surface properties. The obtained materials were employed as catalysts for the activation of Carbon Dioxide (CO₂) and methanol …

Bifunctional Porous Polymeric Fiber As A Catalyst For N-Phenylglycine Synthesis And Carbonation Of Propylene Oxide To Propylene Carbonate, Ahmed Abdulghani Almuslem

Masters Theses

"In this study, development of a polymeric bi-functional porous catalyst that can be used in various applications such as batch, packed-bed, and continuous flow reactors and the formation of highly important chemicals that have many applications in the industry. With this material many homogenous reactions can be conducted in heterogeneous environment which is more efficient and profitable. The catalyst was formed by grafting hollow fiber with APS then immobilized with Br using 1,2-dibromoprobane (Br/APS/PAI-HFs). The formed catalyst was tested with BET and FTIR to confirm the immobilization of Br. A porous polymeric material Br/APS/PAI-HFs provides the ability for ring opining …

Data Analysis Of Low-Salinity Waterflooding To Enhance The Oil Recovery In Sandstone Reservoirs, Nadia Ariani

Masters Theses

"The lack of a single reasonable general mechanism to describe how low-salinity waterflooding can improve oil recovery in both laboratory and field pilot projects has increased the interests of many researchers and stakeholders. There has not been observed the relationship of formation brine salinity and injected brine salinity to see how much salinity is reduced to produce the maximum enhanced oil recovery by LSWF. There is no guidance in what EOR stage the LSWF is best implemented. This work collects data from various published literature to develop a comprehensive data set regarding low-salinity waterflooding in sandstone reservoirs. The LSWF mechanisms …

New Wellbore-Integrity Classification For Gas Migration Problems And New Cement Formulations Using Graphene Nano Platelets To Prevent Gas Migration Through Cement, Mohammed Mousa M. Alkhamis

Masters Theses

"Gas migration, one of the primary problems related to the integrity of oil wells, is caused by cement failures. Gas migration can result in costly well repairs and may endanger personal, equipment, and result in severe operational difficulties and environmental issues. The ultimate objectives of this research were to provide a comprehensive review of the problem and to provide a solution to the problem using Graphene Nano Platelets (GNPs).

An intensive review was performed to understand the cement failures. The reasons behind these failures were analyzed and classified with respect to their locations in the wellbore. Recommendations and potential solutions …