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Heat Flow In The Southern Margin Of Salar De Atacama: Deep Groundwater Temperature Distributions And The Implications For Subsurface Flow And Land Surface Energy Budgets, Graham Thomas

Masters Theses

Salar de Atacama (SdA) located in Northern Chile is home to one of the planet’s largest salar systems and lithium resources. Managing groundwater resources in salars is not obvious due to the lack of scientific understanding on the connectivity between the freshwater and brine systems. Using heat as a tracer in SdA provides a cost-effective method to further investigate groundwater flow in salars. This study employs 372 temperature-depth profiles from 90 boreholes between 2013-18 to understand the distinct thermal zones and flow between them in SdA. Three thermal zones exist within the southern margin of SdA’s thermal regime, at higher …

Architecture Of Extraction: Imagining New Modes Of Inhabitation And Reclamation In The Mining Lifecyle, Erica Dewitt

Masters Theses

Mining is the primary method through which modern society obtains the minerals needed to fuel the global economy, provide for modern energy requirements, and support the built environment. Presently, mining accounts for nearly 1% of the global ice-free land surface, with a dramatic increase anticipated in the coming decades. Mining permanently changes and often destroys the pre-existing topography, hydrology, and ecology of the ground, and efforts to reclaim mining landscapes—with the aim of encouraging reforestation and soil replenishment—are often unsuccessful, rendering the land of abandoned mines both unusable and uninhabitable.

This thesis addresses the current state of mining in the …

Modeling Spatial Distributions Of Tidal Marsh Blue Carbon Using Morphometric Parameters From Lidar, Bonnie Turek

Masters Theses

Tidal marshes serve as important “blue carbon” ecosystems that accrete large amounts of carbon with limited area. While much attention has been paid to the spatial variability of sedimentation within salt marshes, less work has been done to characterize spatial variability in marsh carbon density. Driven by tidal inundation, surface topography, and sediment supply, soil properties in marshes vary spatially with several parameters, including marsh platform elevation and proximity to the marsh edge and tidal creek network. We used lidar to extract these morphometric parameters from tidal marshes to map soil organic carbon (SOC) at the meter scale. Fixed volume …

Sedimentary Processes Influencing Divergent Wetland Evolution In The Hudson River Estuary, Kelly Mckeon

Masters Theses

Consistent shoreline development and urbanization have historically resulted in the loss of wetlands. However, some construction activities have inadvertently resulted in the emergence of new tidal wetlands, with prominent examples of such anthropogenic wetlands found within the Hudson River Estuary. Here, we utilize two of these human-induced tidal wetlands to explore the sedimentary and hydrologic conditions driving wetland development from a restoration perspective. Tivoli North Bay is an emergent freshwater tidal marsh, while Tivoli South Bay is an intertidal mudflat with vegetation restricted to the seasonal growth of aquatic vegetation during summer months. Using a combination of sediment traps, cores, …

Testing The Impact Of A Freshwater Wetland Restoration On Water Table Elevation And Soil Moisture Using A Parametric Groundwater Modeling Approach, Erika T. Ito

Masters Theses

Wetlands are now recognized for the many social, environmental, ecological, and economic benefits they provide. They improve water quality, support biodiversity, abate floods and storms, and provide local recreational areas. Historically, many wetlands have been drained or altered for residential, commercial, or agricultural use. Effective wetland restoration projects reestablish ecosystem services and mitigate legacy effects of land use change to create self-sustaining systems. However, a persisting lack of scientifically-vetted methodological and evaluation guidelines in the field of restoration ecology has caused many restoration efforts to fail to restore natural wetland hydrologic conditions. By definition, wetlands must be saturated, permanently or …

Benjamin Smith Lyman: Geologist At The Intersection Of Hokkaido, Japan, And The United States, Benjamin Ashby

Masters Theses

Benjamin Smith Lyman was a geologist from Northampton, Massachusetts, who was contracted by the Japanese government in 1872 to carry out coal surveys on the island of Hokkaidō 北海道. What started out as a standard geological survey, quickly evolved into a lifelong interest in Japan for Lyman. The large collection of letters, books, photographs, and other documents housed under the Benjamin Smith Lyman Collection at the University of Massachusetts Amherst, serve as a primary source on both early relations between the Japanese and the West and the beginnings of the large network of academic writings which today can be classified …

Coastal Groundwater Catchments Of The Gulf Of Alaska, Aeon Russo

Masters Theses

High latitude mountain environments are experiencing disproportionately adverse effects in a currently changing climate. The Gulf of Alaska (GoA) region is an exemplar of this. Dramatic shifts are occurring in the region’s freshwater reservoirs as glaciers retreat more with each passing year. Research in the region places much focus on observing and predicting climate driven shifts in glacier mass balance, surface discharge, and associated nutrient fluxes to the ocean. On the other hand, coastal groundwater discharge (CGD) is given very little attention. Global and near-global estimates of CGD indicate variable results spanning an order of magnitude. Focusing on regionally specific …

Crustal Evolution Of The New England Appalachians: The Rise And Fall Of A Long-Lived Orogenic Plateau, Ian Hillenbrand

Masters Theses

The rise and demise of mountain belts, caused by growth, modification, or removal of the continental lithosphere are fundamental processes that influence almost all Earth systems. Understanding the nature, timing, and significance of active processes in the creation and evolution of modern mountain belts is challenged by a lack of middle crustal and lower crustal exposures. Analogues can be found in ancient orogens, whose deeply eroded roots offer a window into deeper processes, yet this record is complicated by overprinting events and complex deformational histories. Research presented herein constrains the tectonic history of multistage Appalachian Orogen, type locality of the …

Magnetite Mineralization Of The Hammondville Pluton: Poly-Phase Kiruna Type Iocg Magnetite-Apatite Deposits In The Lyon Mountain Granite, Phillip Geer

Masters Theses

Recent mapping of the Eagle Lake Quadrangle, NY, coupled with whole-rock geochemistry and microscopy has offered insight into the petrogenesis of the magnetite-apatite deposits of the Hammondville mining district in the eastern Adirondack Mountains. This study provides insight into the magmatic history of the ca. 1060-1050 Ma Lyon Mountain Granite (Hammondville Pluton) which is intimately related to, and hosts the deposits in this area. Magnetite seams are commonly surrounded by well layered magnetite gneiss, which typically parallel the seams, although in some outcrops appear to be slightly truncated by them. Mineralization is generally concordant with the weak layering found throughout …

Plio-Pleistocene Paleoceonography Of The Ross Sea, Antarctica Based On Foraminifera From Iodp Sites U1523, U1522, And U1521, Julia Seidenstein

Masters Theses

The West Antarctic Ice Sheet (WAIS) is currently thinning and retreating because shifting oceanic currents are transporting warmer waters to the ice margin, which could lead to a collapse of the ice sheet and global sea level rise. International Ocean Discovery Program (IODP) Expedition 374 sailed to the Ross Sea in 2018 to study the history of the WAIS over the last 20 million years. Previous geologic drilling projects into Ross Sea sediments that record the history of the WAIS (DSDP Leg 28, RISP, MSSTS, Cape Roberts Drilling Project, ANDRILL), as well as modeling studies, show considerable variability of ice-sheet …

Seeing Through The Ottawan Overprint, Adirondack Mtns., Ny: Integrating Microstructural Analysis, Geothermobarometry, And In-Situ Monazite Petrochronology, Justin Mistikawy

Masters Theses

Integrating field observation with petrochronology is critical for understanding the tectonometamorphic evolution of the North American Grenville Province. Despite methodological advances in geothermobarometry and geochronology, incorporating these data into larger models of the Adirondack Mountains remains particularly challenging due to the presence of multiple generations of deformation, primarily related to the ca. 1190 – 1140 Ma Shawinigan and ca. 1090 – 1020 Ma Ottawan Orogenies (McLelland et al.,2013). The Rock and Bear Ponds area is a dome of tight-to-isoclinally folded metapelites in structural contact with orthogneiss. Fold generations are orthogonal and partitioned such that the northern area is dominated by …

Threshold Processes And Stream Temperature Distribution In A Small New England Headwater Stream Catchment., Mitchell Isaacson

Masters Theses

Rising air temperature and decreasing stream flow trends are predicted to result in corresponding increases in stream temperatures. As a result, the future of ectothermic stream fishes, which rely on seasonal and spatial distributions of stream temperature for growth and survival, could be in jeopardy. Fortunately, contradicting stream temperature trends in forested headwater catchments suggest that non-climatic variables, such as baseflow indices and catchment geologic structure, may have an important confounding influence on the future of stream temperature. Most significantly, the annual stability of groundwater temperature has long been recognized as an important buffer between air and stream temperature. The …

In-Situ Zircon And Monazite Geochronology From Compositionally Distinct Layers In A Single Migmatitic Paragneiss Sample Located In The Eastern Adirondack Mountains, Ny, Kaitlyn Suarez

Masters Theses

Migmatites are a common rock type in the Adirondack Mountains, NY. We analyzed a single sample of biotite-garnet-sillimanite paragneiss with foliation parallel leucosome along Route 22 south of Whitehall, NY in order to determine the timing of melting using both in-situ monazite and zircon U/Pb geochronology from the restite and leucosome layers of the same rock. Monazite was analyzed via in-situ EMPA on the Ultrachron microprobe at the University of Massachusetts. Zircon was analyzed via LA-ICP-MS (in-situ and mounted mineral separates) at the LaserChron Center. Monazite analyses from the restite yielded six compositionally distinct populations with dates of 1178 ± …

Legacy Sediment Controls On Post-Glacial Beaches Of Massachusetts, Alycia Ditroia

Masters Theses

Here we examine seasonal grain-size trends on 18 beaches in the Northeastern US and dispersed along the post-glacial coast of Massachusetts (USA) in order to explore the mechanisms influencing median grain size and slope. Over 800 grain size samples were collected along 200 summer and winter cross-shore beach elevation surveys. Obtained grain size and beach slope data are compared to coastal morphology, sediment source, wave height, and tidal magnitude in order to ascertain controls on beach characteristics. In general, median grain size increases with intertidal beach slope in the study region. However, grain sizes along post-glaciated beaches in the study …

The Oxidation State Of Hawaiian Magmas, Michael Vollinger

Masters Theses

In order to estimate the oxygen fugacity of Hawaiian lavas I have measured the ferric/ferrous ratios of samples from the 1984 eruption of Mauna Loa volcano and from the ongoing (1983-2017) Puu Oo eruption of Kilauea volcano. Fifteen samples were studied from the 21 day Mauna Loa eruption and 86 samples, erupted between 1983 and 2004, of the 34 year long Kilauea eruption. Both studies show that, in order to obtain reliable estimates of oxygen fugacity when, where, and how basaltic lava is sampled is of critical importance. Water-quenched lavas and spatter sampled at, or near vents, are less oxidized …

Exploring Long-Term Fault Evolution In Obliquely Loaded Systems Using Tabletop Experiments And Digital Image Correlation Techniques, Kevin Toeneboehn

Masters Theses

This thesis focuses on the use of scaled physical experiments to better understand the development and long-term evolution of fault systems that are otherwise impossible to observe directly. The document is divided into three chapters. The first chapter documents the implementation of an inexpensive stereo vision method for acquiring high resolution three-dimensional strain data for table-top experiments. The second chapter applies the stereo vision method to a tectonic problem—the development of slip partitioning in obliquely loaded crustal systems. Slip partitioned fault systems accommodate oblique convergence with different slip rake on two or more faults and are well documented in the …

Petrogenesis And Concentric Zonation Of The Belchertown Intrusive Complex, West-Central Massachusetts, Karen June Van Wagner

Masters Theses

The Belchertown Intrusive Complex is a ~164 km2 Devonian pluton that intruded Paleozoic metasedimentary and metavolcanic rocks in west-central Massachusetts. Intrusion of the pluton was synchronous with Acadian deformation (Ashwal, 1974). The complex is concentrically zoned, with a core of orthopyroxene-biotite monzodiorite, a middle zone of clinopyroxene-hornblende-biotite granodiorite, and an outermost zone of hornblende-biotite granodiorite. Zoning from a more to less hydrous mineral suite from the outside to the inside of the pluton led Ashwal (1974) to suggest that metamorphic hydration most strongly affected the outermost zones of the complex. Basaltic inclusions occur most commonly near the edges of …

Volatiles In Subglacially Erupted Basaltic Glasses And Their Use In Reconstructing Paleo-Ice Thicknesses, Carver Lee

Masters Theses

Volatile concentrations in basaltic tuyas, edifices that form during a subglacial eruption and remain once the ice sheet has retreated, have been used to calculate the thickness of the overlying ice sheet at the onset of the eruption (Tuffen, 2010). However, subglacial eruptions are complex events and this technique does not always provide a clear answer (Schopka et al., 2006; Edwards et al., 2009). The purpose of this research is to evaluate this technique and investigate constraints on the quality of data collected by attempting to calculate the minimum ice thickness under which Hlöðufell, a tuya in south-central Iceland, erupted. …

Fault Interaction Within Restraining Bend Fault Systems, Aviel Rachel Stern

Masters Theses

Numerical simulations of a 15° restraining bend analog claybox experiment include considering the fault geometry, rheology, and boundary conditions. The numerical models show that a growing fault from an analog experiment propagates at depth rather than at the surface and is exposed in later stages of the experiment, and that the wet kaolin clay from the analog experiment is partially decoupled from the steel plate. The numerical models provide the stresses to predict accurate fault growth from the analog experiment and provide the evolution of external work within the fault system. The external work from the numerical models decrease as …

Micropaleontology And Isotope Stratigraphy Of The Upper Aptian To Lower Cenomanian (~114-98 Ma) In Odp Site 763, Exmouth Plateau, Nw Australia, Ali Alibrahim

Masters Theses

The biostratigraphy and isotope stratigraphy of the upper Aptian to lower Cenomanian interval including oceanic anoxic events OAE1b, 1c and 1d are investigated in ODP Site 763, drilled on the Exmouth Plateau offshore northwest Australia. Benthic foraminifera suggest that Site 763 was situated in outer neritic to upper bathyal water depths (~150-600 m). OAEs of the Atlantic basin and Tethys are typically associated with organic carbon-rich black shales and δ¹³C excursions. However, OAEs at this high latitude site correlate with ocean acidification and/or pyrite formation under anoxic conditions rather than black shales. Ocean acidification maybe responsible for sporadic …

Oceanic Anoxia Event 2 (~94 Ma) In The U.S. Western Interior Sea: High Resolution Foraminiferal Record Of The Development Of Anoxia In A Shallow Epicontinental Sea, Amanda L. Parker

Masters Theses

The Upper Cretaceous Tropic Shale of southern Utah captures critical oceanographic changes that occurred during Oceanic Anoxic Event 2 (OAE 2) and the transgression of the Greenhorn Sea. We investigated the response of planktic and benthic foraminifera in a shallow (<100 >m) marine environment stressed by the onset of OAE 2 during the Cenomanian-Turonian boundary (CTB; 93.9 Ma) to determine the oceanographic mechanisms controlling the observed turnovers in the foraminiferal record. This study is based on high-resolution quantitative foraminifera counts and isotope paleoecology (d¹⁸O and d¹³C) from a 40-m outcrop. The OAE 2 interval is identified …

Sources Of Water And Solutes To The Salar De Atacama, Chile: A Coupled Hydrologic, Geochemical, And Groundwater Modeling Study, Lilly G. Corenthal

Masters Theses

Focused groundwater discharge in endorheic basins provides opportunities to investigate mechanisms for closing hydrologic budgets in arid regions. The Salar de Atacama (SdA), a closed basin in northern Chile, has accumulated over 1800 km³ of halite and a lithium-rich brine since the late Miocene primarily through evapotranspiration of groundwater. The hydrologic balance of SdA and sources of water and solutes required to explain this deposit are not well constrained. An adapted chloride mass balance method drawing on a database of over 200 water sample sites is applied to a remotely-sensed precipitation dataset to estimate spatially-distributed modern groundwater recharge. Comparing …

Dissolution, Ocean Acidification And Biotic Extinctions Prior To The Cretaceous/Paleogene (K/Pg) Boundary In The Tropical Pacific, Serena Dameron

Masters Theses

The several million years preceding the Cretaceous/Paleogene (K/Pg) boundary has been the focus of many studies. Changes in ocean circulation and sea level, extinctions, and major volcanic events have all been documented for this interval. Important research questions these changes raise include the climate dynamics during the warm, but not hot, time after the decay of the Late Cretaceous greenhouse interval and the stability of ecosystems prior to the mass extinctions at the end-Cretaceous.

I document several biotic perturbations as well as changes in ocean circulation during the Maastrichtian stage of the latest Cretaceous that question whether the biosphere was …

Hydrogeological Control On Spatial Patterns Of Groundwater Seepage In Peatlands, Danielle K. Hare

Masters Theses

Groundwater seepage to surface water is an important process to peatland ecosystems; however, the processes controlling seepage zone distribution and magnitude are not well understood. This lack of process-based understanding makes degraded peatland ecosystems difficult to restore and problematic for resource managers developing a sustainable design. Degraded peatlands, particularly abandoned cranberry farms, often have drainage ditches, applied surface sand, and decreased stream sinuosity to artificially lower the water table and support agriculture. These modifications disconnect the surface and groundwater continuum, which decreases thermal buffering of surface water significantly. The combination of a decreased influx of thermally buffered groundwater, a naturally …

The Timing Of Deformation In The Four Peaks Area, Central Arizona, And Relevance For The Mazatzal Orogeny, Calvin A. Mako

Masters Theses

The Mazatzal orogeny (1.66-1.60 Ga) is a key element of the tectonic evolution of the North American continent during the Proterozoic (Whitmeyer and Karlstrom, 2007). Recently, Mesoproterozoic detrital zircon grains (1.55-1.45 Ga) have been found in metasedimentary rocks that were thought to have been deformed during the Paleoproterozoic Mazatzal orogeny (Jones et al. 2011; Doe et al. 2012, 2013; Daniel et al. 2013). Some type examples Mazatzal deformation now seem to be too young to have been deformed in the accepted time of that orogeny (1.66-1.60 Ga) and may have been deformed in the younger, newly defined, Picuris orogeny. This …

Evolution Of Off-Fault Deformation Along Analog Strike-Slip Faults, Alexandra E. Hatem

Masters Theses

Strike-slip faults evolve to accommodate more fault slip, resulting in less off-fault deformation. In analog experiments, the measured fault slip to off-fault deformation ratios are similar to those measured in crustal strike-slip systems, such as the San Andreas fault system. Established planar faults have the largest fault slip to off-fault deformation ratio of ~0.98. In systems without a pre-existing fault surface, crustal thickness and basal detachment conditions affect shear zone width and roughness. However, once the applied plate displacement is 1-2 times the crustal thickness, partitioning of deformation between fault slip and off-fault distributed shear is >0.90, regardless of the …

From ~1.5 Ma To Today: Insights Into The Southern San Andreas Fault System From 3d Mechanical Models, Laura Fattaruso

Masters Theses

Three-dimensional mechanical simulations of the San Andreas fault (SAF) within the Coachella Valley in California produce deformation that match geologic observations and demonstrate the impact of fault geometry on uplift patterns. Most models that include the Coachella Valley segment of the SAF have assumed a vertical orientation, but recent studies suggest that this segment dips 60-70° northeast. We compare models with varied fault geometry and evaluate how well they reproduce observed uplift patterns. Our model with a dipping SAF matches geologic observations, while models containing a vertical fault do not. This suggests that the active Coachella Valley segment of the …