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Masters Theses

Chemical Engineering

<p>Polymer solutions -- Diffusion rate<br />Diffusion -- Mathematical models<br />Glucose</p>

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Molecular Diffusion In Polymer Solutions By A Microinterferometric Method, Surendra V. Desai Jan 1967

Molecular Diffusion In Polymer Solutions By A Microinterferometric Method, Surendra V. Desai

Masters Theses

"The object of this investigation of molecular diffusion in aqueous polymer solutions was to study the effect of solute concentration on the differential diffusion coefficient and also to study the effect of polymer concentration on the mean integral diffusion coefficient. For this purpose a microinterferometric method was used. Two non-ionic, water soluble polymers, Carboxymethylcellulose (CMC) and Carboxypolymethylene (Carbopol), were used in the study with D-Glucose as a solute.

The differential diffusion coefficient was found to increase with increases in solute concentration in all cases. For CMC, the integral diffusion coefficient at first decreased with increasing polymer concentration but became constant …


A Study Of Molecular Diffusion In Polymer Solutions By A Microinterferometric Method, Girish T. Dalal Jan 1966

A Study Of Molecular Diffusion In Polymer Solutions By A Microinterferometric Method, Girish T. Dalal

Masters Theses

"A microinterferometric method was used to study the effect of solute concentration on the diffusion coefficient in polymer solutions and also to determine the effect of polymer concentration on the diffusion coefficient. The polyacrylonitrile-dimethylformamide system was used as a means of determining the accuracy of the experimental apparatus and procedure. The non-ionic, water soluble polymer, hydroxyethyl cellulose (commercially known as Natrosol), was used to study this effect with urea and D-glucose as the solutes.

The results obtained for the polyacrylonitrile-dimethylformamide system were in close agreement with the results obtained by Secor, which meant that the experimental technique is accurate enough …